Patterned polymer electroluminescent devices based on microlithographic processes

• US 5,965,280 A
• Filed: 03/03/1997
• Issued: 10/12/1999
• Est. Priority Date: 03/03/1997
• Status: Expired due to Term

• Current Assignee: InnoLux Corporation
• Original Assignee: Hewlett-Packard Company (HP Inc.)
• Inventors: Roitman, Daniel B., Sheats, James R., Bazan, Guillermo, Renak, Michelle Lee
• Primary Examiner(s): COONEY, JOHN M
• Application Number:
  US08/813,962
• Time in Patent Office: 953 Days
• Field of Search: 428/690, 428/917, 313/504, 313/506
• US Class Current: 428/690
• CPC Class Codes: H10K 2102/351 Thickness
• CPC Class Codes: H10K 50/11 characterised by the electroluminescent [EL] layers
• CPC Class Codes: H10K 59/17 Passive-matrix OLED displays
• CPC Class Codes: H10K 59/221 Static displays, e.g. displaying permanent logos
• CPC Class Codes: H10K 71/12 using liquid deposition, e.g. spin coating
• CPC Class Codes: H10K 71/211 by selective transformation of an existing layer
• CPC Class Codes: H10K 71/60 Forming conductive regions or layers, e.g. electrodes
• CPC Class Codes: H10K 85/114 Poly-phenylenevinylene; Derivatives thereof
• CPC Class Codes: Y10S 428/917 Electroluminescent

Abstract

A PPV based electroluminescent device and method for constructing the same. The electroluminescent device is constructed on a substrate by depositing a layer of material having a PPV precursor and photoacid generator on the substrate. The substrate typically includes the anode for the device. The PPV precursor is converted to PPV in the presence of an acid. The photoacid generator produces an acid when exposed to electromagnetic radiation. Those portions of the layer that are not to contain electroluminescent elements are masked. The unmasked portion is then illuminated with electromagnetic radiation; and any unreacted PPV precursor is removed to provide a plurality of isolated PPV regions on the substrate. An electron transport layer is then deposited over the PPV regions and the cathode is deposited on top of the electron transport layer. By properly choosing the thickness of the electron transport layer, the electron transport layer also provides electrical isolation between the anode and cathode in the regions of the device that do not include PPV elements.

Claims

1. A method for constructing an electroluminescent device on a substrate, said method comprising the steps of:

depositing a layer of material comprising a PPV (poly(p-phenylenevinylene)) precursor and photoacid generator, said PPV precursor being converted to PPV in the presence of an acid, said photoacid generator producing an acid when exposed to electromagnetic radiation;

masking a portion of said layer leaving a portion of said layer unmasked;

illuminating said unmasked portion of said layer with electromagnetic radiation; and

removing any unreacted PPV precursor to provide a plurality of isolated PPV regions on said substrate.

2. The method of claim 1 wherein said PPV precursor comprises poly(9-hydroxy-[2.2]-paracylophan-1-ene)_x -block-poly(norbornene)_y (poly1_x -block-polyNBE_y.

3. The method of claim 1 wherein said photoacid generator comprises triphenylsulfonium trifuoromethanesulfonate.

4. The method of claim 1 further comprising the step of depositing an electron transport layer on said isolated PPV regions, said electron transport layer covering said PPV regions and filling any space between said PPV regions, said electron transport layer comprising a material that preferentially transports electrons over holes.

5. The method of claim 4 wherein said electron transport layer comprises polystyrene and 2-(4-biphenylyl)-1,3,4oxadiazole.

6. An electroluminescent display comprising:

an anode;

a plurality of isolated PPV regions in contact with said anode;

an electron transport layer covering said PPV regions and filling the spaces between said PPV regions; and

a cathode comprising a layer deposited on said electron transport layer, said electron transport layer isolating said cathode from said anode.

7. The display of claim 6 wherein said electron transport layer is deposited such that the minimum distance between skid anode and cathode in regions in which said cathode overlies said anode is greater than a predetermined distance that depends on the distance between anode and cathode in those regions in which said cathode overlies said PPV regions and on the materials from which said anode, cathode, and electron transport layer are constructed.

8. The display of claim 6 wherein said electron transport layer comprises polystyrene and 2-(4-biphenylyl)-1,3,4oxadiazole.

9. An electroluminescent display comprising:

a cathode;

a plurality of isolated PPV regions in contact with said cathode;

a hole transport layer covering said PPV regions and filling the spaces between said PPV regions; and

an anode comprising a layer deposited on said hole transport layer, said hole transport layer isolating said cathode from said anode.

10. The display of claim 9 wherein said hole transport layer is deposited such that the minimum distance between said anode and cathode in regions in which said anode overlies said cathode is greater than a predetermined distance that depends on the distance between anode and cathode in those regions in which said anode overlies said PPV regions and on the materials from which said anode, cathode, and hole transport layer are constructed.