Process for producing .alpha.,.beta.-unsaturated nitrile

• US 5,965,765 A
• Filed: 07/02/1998
• Issued: 10/12/1999
• Est. Priority Date: 01/05/1996
• Status: Expired due to Fees

• Current Assignee: Asahi Kasei Kogyo Kabushiki Kaisha (Asahi Kasei Corporation)
• Original Assignee: Asahi Kasei Kogyo Kabushiki Kaisha (Asahi Kasei Corporation)
• Inventors: Sakamoto, Akihiko, Kurihara, Shigeru, Muroya, Hiroaki
• Primary Examiner(s): Richter, Johann
• Assistant Examiner(s): MURRAY, JOSEPH H
• Application Number:
  US09/101,321
• Time in Patent Office: 467 Days
• Field of Search: 558/320
• US Class Current: 558/320
• CPC Class Codes: B01J 2208/00132 Tubes
• CPC Class Codes: B01J 2208/00141 Coils
• CPC Class Codes: B01J 8/1827 the fluidising gas being a reactant
• CPC Class Codes: B01J 8/34 with stationary packing material in the fluidised bed, e.g. bricks, wire rings, baffles
• CPC Class Codes: C07C 253/26 containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
• CPC Class Codes: C07C 255/08 Acrylonitrile; Methacrylonitrile
• CPC Class Codes: Y02P 20/52 using catalysts, e.g. selective catalysts

Abstract

A process for producing an α,β-unsaturated nitrile from propylene, isobutylene or tert-butyl alcohol in an industrial fluidized reactor with the step of feeding methanol and an oxygen-containing gas in the course of the whole contact time of the reactor and reacting unreacted ammonia with the methanol and the oxygen-containing gas, which can reduce the amount of unreacted ammonia without lowering the yield of the nitrile; and an industrial process of conducting the above production in an industrial fluidized reactor having an inner diameter of 3 m or above and filled with a molybdenum-bismuth catalyst supported on silica, which can prevent the feed opening of a dispersing nozzle for the methanol from clogging with molybdenum oxides to attain constant reduction in the amount of unreacted ammonia. The former is a process of catalytically reacting propylene, isobutylene or tert-butyl alcohol with ammonia and an oxygen-containing gas at high temperature in a gas phase by the use of a fluidized bed catalyst to form an α,β-unsaturated nitrile having the same number of carbon atoms as that of the starting propylene, isobutylene or tert-butyl alcohol, wherein methanol and an oxygen-containing gas are fed into the fluidized reactor at the positions corresponding to one-half to nine-tenths of the whole contact time from the point of feeding the starting materials through gas dispersing nozzles; and the latter is a process of producing an α,β-unsaturated nitrile as described above, wherein the methanol is fed together with steam through the same gas dispersing nozzle to thereby inhibit the catalyst from adhering to the dispersing nozzle and remove the catalyst adherent thereto.

Claims

1. A process for producing an α

,β

-unsaturated nitrile which comprises catalytically reacting propylene, isobutylene, or tert-butyl alcohol with ammonia and an oxygen-containing gas at a high temperature in a gas phase by the use of a fluidized bed catalyst to produce an α

,β

-unsaturated nitrile having the same number of carbon atoms as propylene, isobutylene, or tert-butyl alcohol, wherein the reaction is conducted in a fluidized-bed reactor to which methanol and an oxygen-containing gas are fed through respective gas dispersing pipes at positions corresponding to from one half to nine tenths the whole contact time from the a point of starting-material feeding, and which has one or more perforated structures having open area ratio of at least 60% disposed below and/or above the gas dispersing pipes.

2. The process for producing an α

,β

-unsaturated nitrile of claim 1, characterized in that the open area ratio is at least 80%.

3. The process for producing an α

,β

-unsaturated nitrile of claim 1 or 2, characterized in that the perforated structures each is a net or comb-like structure.

4. The process for producing an α

,β

-unsaturated nitrile of claim 1 or 2, characterized in that the distance between each of the gas discharging pipes and the nearest perforated structure is from 10 to 100 cm or the interval between the perforated structures is from 10 to 100 cm.

5. The process for producing an α

,β

-unsaturated nitrile of claim 1, characterized in that the methanol is fed together with steam through the same gas dispersing pipe to thereby prevent the catalyst from adhering to the dispersing pipe or remove the catalyst adherent thereto.

6. The process for producing an α

,β

-unsaturated nitrile of claim 5, characterized in that a gas dispersing pipe having nozzles is used for each of the methanol and the oxygen-containing gas, wherein the nozzles of one of the pipes coincide in axis with those of the other pipe and the distance between the methanol feed openings and the oxygen-containing gas feed openings is from 10 to 200 mm so that the methanol and the oxygen-containing gas are jetted face-to-face in the vertical direction and come into contact with each other.

7. The process for producing an α

,β

-unsaturated nitrile of claim 5 or 6, characterized in that the methanol and the steam are mixed in a steam/methanol ratio of from 5 to 80 wt % and fed through the same gas dispersing pipe.