Thermoelectric catalytic power generator with preheat

• US 5,968,456 A
• Filed: 09/19/1997
• Issued: 10/19/1999
• Est. Priority Date: 05/09/1997
• Status: Expired due to Fees

• Current Assignee: Ronald J. Parise
• Original Assignee: Ronald J. Parise
• Inventors: Parise, Ronald J.
• Primary Examiner(s): TRAN, HIEN THI
• Application Number:
  US08/933,663
• Time in Patent Office: 760 Days
• Field of Search: 422/171, 422/177, 422/172, 422/176, 422/173, 422/174, 422/198, 422/110, 422/199, 422/202, 422/109, 60/298, 60/320, 60/300, 136/201, 136/205, 136/242, 136/211, 136/212
• US Class Current: 422/174
• CPC Class Codes: B01F 2101/2305 Mixers of the two-component package type, i.e. where at least two components are separately stored, and are mixed in the moment of application
• CPC Class Codes: B01F 25/4314 with helical baffles
• CPC Class Codes: B01F 33/5011 portable during use, e.g. hand-held
• CPC Class Codes: B29C 2948/92104 Flow or feed rate
• CPC Class Codes: B29C 2948/926 Flow or feed rate
• CPC Class Codes: B29C 2948/92704 Temperature
• CPC Class Codes: B29C 48/03 characterised by the shape of the extruded material at extrusion
• CPC Class Codes: B29C 48/33 with parts rotatable relative to each other
• CPC Class Codes: B29C 48/92 Measuring, controlling or regulating
• CPC Class Codes: F01N 3/20 specially adapted for catalytic conversion F01N3/22 takes precedence; Methods of operation or control of catalytic converters
• CPC Class Codes: F01N 3/2006 Periodically heating or cooling catalytic reactors, e.g. at cold starting or overheating by electrically controlling the supply of combustible mixture or its constituents only F02D41/0235
• CPC Class Codes: F01N 3/2013 using electric or magnetic heating means
• CPC Class Codes: F01N 3/2046 Periodically cooling catalytic reactors
• CPC Class Codes: H01M 10/443 in response to temperature
• CPC Class Codes: H01M 8/04007 related to heat exchange
• CPC Class Codes: H02J 7/34 Parallel operation in networks using both storage and other dc sources, e.g. providing buffering H02J7/14 takes precedence
• CPC Class Codes: H10N 10/00 Thermoelectric devices comprising a junction of dissimilar materials, i.e. devices exhibiting Seebeck or Peltier effects integrated devices or assemblies of multiple devices H10N19/00
• CPC Class Codes: H10N 10/13 characterised by the heat-exchanging means at the junction
• CPC Class Codes: Y02A 50/20 Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02E 60/50 : Fuel cells
• CPC Class Codes: Y02T 10/12 : Improving ICE efficiencies

Abstract

An automobile catalytic converter that utilizes the energy of the exothermic reactions that take place in the catalysis substrate to produce electrical energy with a thermoelectric generator. On vehicle cold start, the thermoelectric generator is used as a heat pump to heat the catalyst substrate to reduce the time to catalyst light-off. In this way, the catalytic converter comes up to operating temperature more rapidly, reducing the amount of pollutant emissions at vehicle start-up.

Claims

1. A preheat system for reducing emissions in a vehicle having an internal combustion engine, a fluid cooling system containing a coolant, an electrical power source, an electrical load, and an exhaust passage having exhaust gases flowing in a flow direction therein, comprising:

a catalytic converter disposed in the exhaust passage, said converter enclosing a catalytic monolith in fluid communication with the exhaust gases, said converter having a light-off temperature;

a coolant jacket disposed in an outer portion of the catalytic converter, said jacket having a coolant inlet and a coolant outlet in fluid communication with the fluid cooling system to maintain the outer portion of the catalytic converter at a predetermined temperature;

a plurality of thermoelectric generators disposed in heat exchange relationship with the catalytic monolith;

a temperature sensor disposed in the catalytic converter capable of determining a perceived temperature of the catalytic converter and further capable of sending a signal corresponding to the perceived temperature;

a preheat controller capable of receiving the signal and comparing the perceived temperature with the light-off temperature;

the preheat controller in electric communication with the electrical power source and the thermoelectric generators and operable to control the thermoelectric generators such that heat is transferred from the thermoelectric generators to the catalytic monolith when the perceived temperature is less than the light-off temperature; and

the preheat controller further capable of extracting electrical energy from the thermoelectric generators when the perceived temperature is greater than the light-off temperature and heat is transferred from the catalytic monolith to the thermoelectric generators.

2. The preheat system as set forth in claim 1 wherein:

the catalytic monolith is disposed within a casing;

a layer comprised of insulation is disposed around the casing;

a compression shell is disposed around the insulation layer;

a plurality of fins are arranged about the casing and in heat exchange relationship with the catalytic monolith and the compression shell;

a spring support shell is mounted concentrically between the compression shell and the coolant jacket such that a gap is formed therebetween; and

the thermoelectric generators are fixedly mounted to a plurality of springs disposed within the gap such that the springs bias the thermoelectric generators against the compression shell in heat exchange relationship with the fins.

3. The preheat system as set forth in claim 1 wherein:

the catalytic monolith is disposed within a casing;

a layer comprised of insulation is disposed around the casing;

a compression shell is disposed around the insulation layer;

a plurality of fins are arranged about the casing and in heat exchange relationship with the catalytic monolith and the compression shell;

a spring support shell is mounted concentrically between the compression shell and the coolant jacket such that a gap is formed therebetween;

a spring having a sinuous shape is disposed within the gap producing a biasing force between the compression shell and the spring support shell; and

the thermoelectric generators are fixedly mounted to the sinuous spring and disposed between the spring and the compression shell such that the spring biases the thermoelectric generators against the compression shell in heat exchange relationship with the fins.

4. A preheat system for reducing emissions in a vehicle having an internal combustion engine, a fluid cooling system containing a coolant, an electrical power source, an electrical load, and an exhaust passage having exhaust gases flowing in a flow direction therein, comprising:

a catalytic converter disposed in the exhaust passage, said converter enclosing a catalytic monolith in fluid communication with the exhaust gases, said converter having a light-off temperature;

a coolant jacket disposed in an outer portion of the catalytic converter, said jacket having a coolant inlet and a coolant outlet in fluid communication with the fluid cooling system to maintain the outer portion of the catalytic converter at a predetermined temperature;

a plurality of thermoelectric generators disposed in heat exchange relationship with the catalytic monolith;

a temperature sensor disposed in the catalytic converter capable of determining a perceived temperature of the catalytic converter and further capable of sending a signal corresponding to the perceived temperature;

a valve disposed in the exhaust passage having a closed position and an open position, capable of restricting the volume of exhaust gases through the monolith in the closed position; and

a preheat controller capable of receiving the signal and comparing the perceived temperature with the light-off temperature;

the preheat controller in electric communication with the electrical power source and the thermoelectric generators and operable to control the thermoelectric generators such that heat is transferred from the thermoelectric generators to the catalytic monolith when the perceived temperature is less than the light-off temperature;

the preheat controller in electric communication with the valve and operable to position the valve in the closed position when the perceived temperature of the catalytic converter is below the light-off temperature and operable to position the valve in the open position when the perceived temperature of the catalytic converter is above the light-off temperature; and

the preheat controller further capable of extracting electrical energy from the thermoelectric generators when the perceived temperature is greater than the light-off temperature and heat is transferred from the catalytic monolith to the thermoelectric generators.

5. The preheat system as set forth in claim 4 wherein the valve comprises:

a butterfly plate having at least one by-pass orifice disposed therein;

the butterfly plate disposed within and substantially filling a cross sectional area of the exhaust gas passage in the closed position restricting the exhaust gas flow to the at least one by-pass orifice.

6. The preheat system as set forth in claim 4 wherein the valve comprises:

a ball having at least one by-pass orifice disposed therein; and

the ball disposed within and substantially filling a cross sectional area of the exhaust gas passage in the closed position restricting the exhaust gas flow to the at least one by-pass orifice.

7. The preheat system as set forth in claim 4 wherein the catalytic converter has an upstream end and a down stream end and the valve is disposed in the exhaust passage proximate the downstream end of the catalytic converter.

8. The preheat system as set forth in claim 4 wherein the catalytic converter has an upstream end and a down stream end and the valve is disposed in the exhaust passage proximate the upstream end of the catalytic converter.

9. The preheat system as set forth in claim 4 wherein:

the catalytic monolith is disposed within a casing;

a layer comprised of insulation is disposed around the casing;

a compression shell is disposed around the insulation layer;

a plurality of fins are arranged about the casing and in heat exchange relationship with the catalytic monolith and the compression shell;

a spring support shell is mounted concentrically between the compression shell and the coolant jacket such that a gap is formed therebetween; and

the thermoelectric generators are fixedly mounted to a plurality of springs disposed within the gap such that the springs bias the thermoelectric generators against the compression shell in heat exchange relationship with fins.

10. The preheat system as set forth in claim 4 wherein:

the catalytic monolith is disposed within a casing;

a layer comprised of insulation is disposed around the casing;

a compression shell is disposed around the insulation layer;

a plurality of fins are arranged about the casing and in heat exchange relationship with the catalytic monolith and the compression shell;

a spring support shell is mounted concentrically between the compression shell and the coolant jacket such that a gap is formed therebetween;

a spring having a sinuous shape is disposed within the gap producing a biasing force between the compression shell and the spring support shell;

the thermoelectric generators are fixedly mounted to the sinuous spring and disposed between the spring and the compression shell such that the spring biases the thermoelectric generators against the compression shell in heat exchange relationship with the fins.

11. A catalytic system for producing electricity in a vehicle having an internal combustion engine, a cooling system containing a coolant, an electrical load, and an exhaust passage having exhaust gases flowing in a flow direction therein, comprising:

a catalytic converter disposed in the exhaust passage, with a catalytic monolith in fluid communication with the exhaust gases, said converter having a light-off temperature,

a coolant jacket disposed in an outer portion of the catalytic converter, said jacket having a coolant inlet and a coolant outlet in fluid communication with the cooling system to maintain the outer portion of the catalytic converter at a predetermined temperature;

a plurality of thermoelectric generators disposed in physical contact with the catalytic converter and in heat exchange relationship with the catalytic monolith and capable of producing electrical energy when heat is transferred from the catalytic monolith to the thermoelectric generators;

a controller in electrical communication with the thermoelectric generators and the electrical load and capable of extracting electrical energy from the thermoelectric generators and delivering the electrical energy to the electrical load;

wherein

the catalytic monolith is disposed within a casing;

a layer comprised of insulation is disposed around the casing;

a compression shell is disposed around the insulation layer;

a plurality of fins are arranged about the casing and in heat exchange relationship with the catalytic monolith and the compression shell;

a spring support shell is mounted concentrically between the compression shell and the coolant jacket such that a gap is formed therebetween; and

the thermoelectric generators are fixedly mounted to a plurality of springs disposed within the gap such that the springs bias the thermoelectric generators against the compression shell in heat exchange relationship with the fins.

12. The catalytic system as set forth in claim 11 wherein:

the catalytic monolith is disposed within a casing;

a layer comprised of insulation is disposed around the casing;

a compression shell is disposed around the insulation layer;

a plurality of fins are arranged about the casing and in heat exchange relationship with the catalytic monolith and the compression shell;

a spring support shell is mounted concentrically between the compression shell and the coolant jacket such that a gap is formed therebetween;

a spring having a sinuous shape is disposed within the gap producing a biasing force between the compression shell and the spring support shell; and

the thermoelectric generators are fixedly mounted to the sinuous spring and disposed between the spring and the compression shell such that the spring biases the thermoelectric generators against the compression shell in heat exchange relationship with the fins.