Toner particles of controlled shape and method of preparation

• US 5,968,702 A
• Filed: 11/24/1997
• Issued: 10/19/1999
• Est. Priority Date: 11/24/1997
• Status: Expired due to Term

• Current Assignee: Eastman Kodak Company
• Original Assignee: Eastman Kodak Company
• Inventors: Ezenyilimba, Matthew C., Sweeney, Mark A.
• Primary Examiner(s): GOODROW, JOHN L
• Application Number:
  US08/977,263
• Time in Patent Office: 694 Days
• Field of Search: 430/106, 430/110, 430/111, 430/137
• US Class Current: 430/110.3
• CPC Class Codes: G03G 9/0804 whereby the components are brought together in a liquid dispersing medium

Abstract

A method is described for the preparation of electrophotographic toner particles which includes the use of SOLSPERSE®. The method involves dissolving in ethyl acetate a hyperdispersant selected from SOLSPERSE® 24000 and SOLSPERSE® 20000, thereby forming a solution; mixing the solution with a polymer material to form an organic phase; dispersing the organic phase in an aqueous phase containing a particulate stabilizer and homogenizing the resultant dispersion; evaporating the solvent; and washing and drying the resultant product.

Claims

1. A method for the preparation of electrostatographic toner comprising the steps of:

a) dissolving in ethyl acetate a hyperdispersant selected from SOLSPERSE®

24000 and SOLSPERSE®

20000, thereby forming a solution;

b) mixing the solution with a polymer material to form an organic phase;

c) dispersing the organic phase in an aqueous phase comprising a particulate stabilizer and homogenizing the resultant dispersion;

d) evaporating the solvent; and

e) washing and drying the resultant product.

2. The method of claim 1 wherein a charge control agent is added in step b).

3. The method of claim 1 wherein a pigment is added in step b).

4. The method of claim 1 wherein a promotor is added in step b).

5. The method of claim 1 wherein the solvent is selected from chloromethane, dichloromethane, ethyl acetate, n-propyl acetate, iso-propyl acetate, vinyl chloride, methyl ethyl ketone, trichloromethane, carbon tetrachloride, ethylene chloride, trichloroethane, toluene, xylene, cyclohexanone and 2-nitropropane.

6. The method of claim 1 wherein the solvent is ethyl acetate.

7. The method of claim 1 wherein the pigment to SOLSPERSE®

ratio ranges from 1;

0.5 to 1.0;

0.06.

8. The method of claim 1 wherein the particulate stabilizer is selected from the group consisting of highly cross-linked latex polymeric material, and SiO₂.

9. The method of claim 1 wherein the amount of particulate stabilizer is between 1 to 15 parts based on 100 parts of total solids in the toner.

10. The method of claim 1 wherein the relationship between the aqueous phase and the organic phase, by volume, ranges from 1:

1 to 9;

1.

11. The method of claim 1 wherein the organic phase contains lubricants.

12. The method of claim 1 wherein the organic phase contains waxes.

13. The method of claim 1 wherein the polymer material is selected from, olefin homopolymers and copolymers, such as, polyethylene, polypropylene, polyisobutylene and polyisopentylene;

polytrifluoroolefins, such as polytetrafluoroethylene and polytrifluorochloroethylene;

polyamides, such as polyhexamethylene adipamide, polyhexamethylene sebacamide, and polycaprolactam;

acrylic resins, such as polymethylmethacrylate, polymethylacrylate, polyethylmethacrylate and styrene-methylmethacrylate;

ethylene-methylacrylate copolymers, ethylene-ethyl acrylate copolymers, ethylene-ethyl methacrylate copolymers, polystyrene and copolymers of styrene with unsaturated monomers, cellulose derivatives, polyesters, polyvinyl resins and ethylene-allyl alcohol copolymers.

14. The method of claim 1 wherein the polymer is polyester.

15. The method of claim 1 wherein the polymer is butyl acrylate-styrene copolymer.

16. The method of claim 1 wherein the pigment employed comprises from 1.0 to 40.0%, by weight, based upon the weight of the total solids present in the toner.

17. The method of claim 1 wherein the pigment employed comprises from 4.0 to 20.0%, by weight, based upon the weight of total solids present in the toner.

18. The method of claim 1 wherein the pigment is selected from TiO2;

carbon black such as channel black, furnace black, acetylene black, thermal black, lamp black and aniline black;

phthalocyanine pigments such as copper phthalocyanine, mono-chlor copper phthalocyanine, and hexadecachlor copper phthalocyanine;

organic pigments such as anthraquinone vat pigments such as vat yellow 6GLCL1127, quinone yellow 18-1, indanthrone CL1106, pyranthrone CL1096, brominated pyranthrones such as dibromopyranthrone, vat brilliant orange RK, anthramide brown CL1151, dibenzanthrone green CL1101, flavanthrone yellow CL1118;

azo pigments such as toluidine red C169 and hansa yellow; and

metallized pigments such as azo yellow and permanent red.

19. The method of claim 1 wherein the pigment is selected from bridged aluminum phthalocyanine and carbon black.

20. In a method for preparing electrostatographic toner by dispersing an organic phase in an aqueous phase to yield a layer of particulate stabilizer on the surface of a polymer, the improvement which comprises adding SOLSPERSE®

in a solvent to a polymer material, a pigment and optionally a charge control agent to form an organic phase for dispersing in the aqueous phase.

21. The method of claim 20 wherein the solvent is ethyl acetate.

22. The method of claim 20 wherein the polymer is selected from butyl acrylate-styrene copolymer and polyester.

23. Electrostatographic toner prepared in accordance with the method of claim 20.

24. Electrostatographic toner in accordance with claims 20 or 21 comprising carbon black and being nonspherical in shape.