Toner for developing electrostatic image, process-cartridge and image forming method

• US 5,972,553 A
• Filed: 10/25/1996
• Issued: 10/26/1999
• Est. Priority Date: 10/30/1995
• Status: Expired due to Term

• Current Assignee: Canon Kabushiki Kaisha (Canon Inc.)
• Original Assignee: Canon Kabushiki Kaisha (Canon Inc.)
• Inventors: Kasuya, Takashige, Kobori, Takakuni, Katada, Masaichiro
• Primary Examiner(s): Rodee, Christopher D.
• Application Number:
  US08/736,937
• Time in Patent Office: 1,096 Days
• Field of Search: 430/110, 430/109, 430/97, 430/124, 430/125
• US Class Current: 430/108.23
• CPC Class Codes: G03G 9/08711 with esters of acrylic or methacrylic acid
• CPC Class Codes: G03G 9/08782 Waxes
• CPC Class Codes: G03G 9/08795 characterised by their chemical properties, e.g. acidity, molecular weight, sensitivity to reactants
• CPC Class Codes: G03G 9/08797 characterised by their physical properties, e.g. viscosity, solubility, melting temperature, softening temperature, glass transition temperature
• CPC Class Codes: G03G 9/091 Azo dyes
• CPC Class Codes: G03G 9/09783 Organo-metallic compounds

Abstract

A toner for developing an electrostatic image is composed from a composition including: polymer components, a colorant, a wax and a charge-controlling agent. The polymer components are characterized by (a) containing substantially no THF (tetrahydrofuran)-insoluble content; (b) containing a THF-soluble content giving a GPC (gel permeation chromatography) chromatogram showing a main peak in a molecular weight region of 3×10³ -3×10⁴, and a sub-peak or shoulder in a molecular weight region of 1×10⁵ -3×10⁶, and (c) including a low-molecular weight polymer component having molecular weights of below 5×10⁴ on the GPC chromatogram and an acid value A_VL, and a high-molecular weight polymer component having molecular weights of at least 5×10⁴ and an acid value A_VH satisfying A_VL >A_VH. The wax has an acid value A_VWax satisfying A_VL >A_VWax and A_VWax >0 (mgKOH/g). The toner is characterized by a good combination of low-temperature fixability and anti-offset characteristic, a stable chargeability, and freeness from sleeve ghost phenomenon.

Claims

1. A toner for developing an electrostatic image, comprising a composition including:

polymer components, a colorant, a wax terminally modified with at least one of maleic acid, maleic acid half ester or maleic anhydride and a charge-controlling agent, wherein the polymer components are characterized by

(a) containing substantially no THF (tetrahydrofuran)-insoluble content;

(b) containing a THF-soluble content giving a GPC (gel permeation chromatography) chromatogram showing a main peak in a molecular weight region of 3×

10³ -3×

10⁴, and a sub-peak or shoulder in a molecular weight region of 1×

10⁵ -3×

10⁶, and

(c) including a low-molecular weight polymer component having molecular weights of below 5×

10⁴ on the GPC chromatogram and an acid value A_VL, and a high-molecular weight polymer component having molecular weights of at least 5×

10⁴ and an acid value A_VH, satisfying A_VL >

A_VH ; and

the wax has an acid value A_VWAX satisfying

space="preserve" listing-type="equation">0.5×

A.sub.VL >

A.sub.VWAX >

0.05×

A.sub.VL,

space="preserve" listing-type="equation">1.5 mgKOH/g≦

A.sub.VWAX ≦

13.0 mgKOH/g.

2. The toner according to claim 1, wherein the wax comprises polypropylene wax terminally modified with at least one species of acidic monomer selected from the group consisting of maleic acid, maleic acid half ester and maleic anhydride.

3. The toner according to claim 1, wherein the wax and the low-molecular weight polymer component respectively contain an acidic component which has originated from at least one species of acid monomer selected from the group consisting of maleic acid, maleic acid half ester and maleic anhydride.

4. The toner according to claim 1, wherein the low molecular weight polymer component has an acid value (A_VL) of 21-35 mgKOH/g, and the high-molecular weight polymer component has an acid value (A_VH) of 0.5-11 mgKOH/g.

5. The toner according to claim 1, wherein the low molecular weight polymer component has an acid value (A_VL) of 21-35 mgKOH/g, and the high-molecular weight polymer component has an acid value (A_VH) of 0.5-11 mgKOH/g, giving a difference therebetween (A_VL -A_VH) satisfying:

space="preserve" listing-type="equation">10≦

(A.sub.VL -A.sub.HL)≦

27.

6. The toner according to claim 1, wherein the polymer components contain a THF-soluble content giving a GPC chromatogram showing a minimum in a molecular weight region of from 3×

10⁴ to below 1×

10⁵.

7. The toner according to claim 1, wherein the composition has a glass transition temperature (Tg) of 50-70°

C., and the low- and high-molecular weight polymer components have glass transition temperatures Tg_L and Tg_H, respectively, satisfying;

space="preserve" listing-type="equation">Tg.sub.L ≧

Tg.sub.H -5.

8. The toner according to claim 7, wherein Tg is 55-65°

C., and Tg_L ≧

Tg_H.

9. The toner according to claim 1, wherein the low- and high-molecular weight polymer components are contained at W_L wt. % and W_H wt. %, respectively, in the polymer components of the composition so as to satisfy the following conditions in relation to their acid values A_VL (mgKOH/g) and A_VH (mgKOH/g), respectively:

space="preserve" listing-type="equation">W.sub.L ;

W.sub.H =50;

50 to 90;

10,

space="preserve" listing-type="equation">A.sub.VL ×

W.sub.L /(W.sub.L +W.sub.H)≧

A.sub.VH ×

W.sub.H ×

4/(W.sub.L +W.sub.H),

and

space="preserve" listing-type="equation">11≦

(A.sub.VL W.sub.L +A.sub.VH W.sub.H)/(W.sub.L +W.sub.H)≦

30.

10. The toner according to claim 1, wherein the low- and high-molecular weight polymer components respectively contain at least 65 wt. % of polymerized styrene units.

11. The toner according to claim 1, wherein the high-molecular weight polymer component comprises a polymer polymerized by using a polyfunctional polymerization initiator.

12. The toner according to claim 1, wherein the high-molecular weight polymer component comprises a polymer polymerized by using a polyfunctional polymerization initiator and a monofunctional polymerization initiator in combination.

13. The toner according to claim 1, wherein the polymer components provide a GPC chromatogram showing an areal percentage of at most 10% in a molecular weight region of at least 10⁶.

14. The toner according to claim 1, wherein the charge-controlling agent comprises a metal-containing organic compound represented by the following formula I:

##STR11## wherein M denotes a coordination center metal having a coordination number of 6, selected from the group consisting of Cr, Co, Ni, Mn and Fe;

Ar denotes an aryl group selected from the group consisting of phenyl and naphthyl, capable of having a substituent selected from the group consisting of nitro, halogen, carboxyl, anilide, and alkyl and alkoxy having 1-8 carbon atoms;

X, X'"'"', Y and Y'"'"' independently denote --O--, --CO--, --NH--, or --NR-- (wherein R denotes an alkyl having 1-4 carbon atoms); and

C.sup.⊕

denotes hydrogen, sodium, potassium, ammonium or aliphatic ammonium.

15. The toner according to claim 14, wherein said metal-containing organic compound is a compound represented by the following formula:

##STR12## wherein X₁ and X₂ independently denote hydrogen, lower alkyl, lower alkoxy, nitro or halogen;

m and m'"'"' independently denote an integer of 1-3;

Y₁ and Y₃ independently denote hydrogen, C₁ -C₁₈ alkyl, C₂ -C₁₈ alkenyl, sulfonamide, mesyl, sulfonic acid, carboxy ester, hydroxy, C₁ -C₁₈ alkoxy, acetylamino, benzoyl, amino or halogen;

n and n'"'"' independently denote an integer of 1-3;

Y₂ and Y₄ independently denote hydrogen or nitro; and

A.sup.⊕

denotes H⁺, Na⁺, K⁺, NH₄⁺ or a mixture of these ions.

16. The toner according to claim 14, wherein said metal-containing organic compound is a compound represented by the following formula:

##STR13## wherein A.sup.⊕

denotes H⁺, Na⁺, K⁺, NH₄⁺ or a mixture of these ions.

17. The toner according to claim 1, wherein the charge-controlling agent comprises a metal-containing organic compound represented by the following formula II:

##STR14## wherein M denotes a coordination center metal having a coordination number of 6, selected from the group consisting of Cr, Co, Ni, Mn and Fe;

A denotes an arylene selected from the group consisting of ##STR15## (capable of having an alkyl substitutent), ##STR16## (X denotes hydrogen alkyl, halogen, or (nitro), ##STR17## (R denotes hydrogen, C₁ -C₁₈ alkyl or C₁ -C₁₈ alkenyl);

Y.sup.⊕

denotes a counter ion selected from the group consisting of hydrogen, sodium, potassium, ammonium and aliphatic ammonium; and

Z denotes --O-- or --CO.O--.

18. The toner according to claim 1, wherein the toner is in the form of particles having a particle size distribution including a weight-average particle size (D₄) of X μ

m and Y % by number of toner particles having a particle size of at most 3.17 μ

m satisfying the following conditions (1) and (2);

space="preserve" listing-type="equation">-5X+35≦

Y≦

-25X+180 (1)

space="preserve" listing-type="equation">3.5≦

X≦

6.5 (2).

19.

19. The toner according to claim 1, wherein the wax comprises both a polyolefin (A) terminally modified with said at least one of maleic acid, maleic acid half ester, or maleic anhydride and a polyolefin (B);

the modified polyolefin (A) has a weight-average molecular weight (Mw_WaxA) of 8.0×

10³ -1.4×

10⁴, and the polyolefin (B) has a weight-average molecular weight (MW_WaxB) of 1.0×

10⁴ -4.0×

10⁴.

20. The toner according to claim 19, wherein the weight-average molecular weight (Mw_WaxB) of the polyolefin (B) is 1.5×

10⁴ -2.5×

10⁴.

21. The toner according to claim 19, wherein the modified polyolefin (A) comprises polypropylene wax terminally modified with at least one species of acidic monomer selected from the group consisting of maleic acid, maleic acid half ester and maleic anhydride.

22. The toner according to claim 19, wherein the polyolefin (B) comprises polypropylene wax.

23. The toner according to claim 19, wherein the modified polyolefin (A) and the low-molecular weight polymer component respectively contain an acid component which has originated from at least one species of acidic monomer selected from the group consisting of maleic acid, maleic acid half ester and maleic anhydride.

24. The toner according to claim 19, wherein the low molecular weight polymer component has an acid value (A_VL) of 21-35 mgKOH/g, and the high-molecular weight polymer component has an acid value (A_VH) of 0.5-11 mgKOH/g.

25. The toner according to claim 24, wherein the low molecular weight polymer component has an acid value (A_VL) of 21-35 mgKOH/g, and the high-molecular weight polymer component has an acid value (A_VH) of 0.5-11 mgKOH/g, giving a difference therebetween (A_VL -A_VH) satisfying:

space="preserve" listing-type="equation">10≦

(A.sub.VL -A.sub.HL)≦

27.

26. The toner according to claim 19, wherein the polymer components contain a THF-soluble content giving a GPC chromatogram showing a minimum in a molecular weight region of from 3×

10⁴ to below 1×

10⁵.

27. The toner according to claim 19, wherein the composition has a glass transition temperature (Tg) of 50-70°

C., and the low- and high-molecular weight polymer components have glass transition temperatures Tg_L and Tg_H, respectively, satisfying;

space="preserve" listing-type="equation">Tg.sub.L ≧

Tg.sub.H -5.

28. The toner according to claim 27, wherein Tg is 55-65°

C., and Tg_L ≧

Tg_H.

29. The toner according to claim 19, wherein the low- and high-molecular weight polymer components are contained at W_L wt. % and W_H wt. %, respectively, in the polymer components of the composition so as to satisfy the following conditions in relation to their acid values A_VL (mgKOH/g) and A_VH (mgKOH/g), respectively:

space="preserve" listing-type="equation">W.sub.L ;

W.sub.H =50;

50 to 90;

10,

space="preserve" listing-type="equation">A.sub.VL ×

W.sub.L /(W.sub.L +W.sub.H)≧

A.sub.VH ×

W.sub.H ×

4/(W.sub.L +W.sub.H),

and

space="preserve" listing-type="equation">11≦

(A.sub.VL W.sub.L +A.sub.VH W.sub.H)/(W.sub.L +W.sub.H)≦

30.

30. The toner according to claim 19, wherein the low- and high-molecular weight polymer components respectively contain at least 65 wt. % of polymerized styrene units.

31. The toner according to claim 19, wherein the high-molecular weight polymer component comprises a polymer polymerized by using a polyfunctional polymerization initiator.

32. The toner according to claim 19, wherein the high-molecular weight polymer component comprises a polymer polymerized by using a polyfunctional polymerization initiator and a monofunctional polymerization initiator in combination.

33. The toner according to claim 19, wherein the polymer components provide a GPC chromatogram showing an areal percentage of at most 10% in a molecular weight region of at least 10⁶.

34. An image forming method, comprising:

forming an electrostatic image on an electrostatic image-bearing member, and developing the electrostatic image with a toner contained in developing means to form a toner image;

wherein the toner is a toner according to any one of claims 5-23 or 26-33.

35. The toner according to claim 1, wherein the wax comprises polyolefin wax modified to have an acid value of 3.5 to 13.0 mgKOH/g.

36. An image forming method, comprising:

forming an electrostatic image on an electrostatic image-bearing member, and developing the electrostatic image with a toner contained in developing means to form a toner image;

wherein the toner comprises polymer components, a colorant, a wax terminally modified with at least one of maleic acid, maleic acid half ester or maleic anhydride and a charge-controlling agent;

the polymer components are characterized by

(a) containing substantially no THF (tetrahydrofuran)-insoluble content;

(b) containing a THF-soluble content giving a GPC (gel permeation chromatography) chromatogram showing a main peak in a molecular weight region of 3×

10³ -3×

10⁴, and a sub-peak or shoulder in a molecular weight region of 1×

10⁵ -3×

10⁶, and

(c) including a low-molecular weight polymer component having molecular weights of below 5×

10⁴ on the GPC chromatogram and an acid value A_VL, and a high-molecular weight polymer component having molecular weights of at least 5×

10⁴ and an acid value A_VH satisfying A_VH ≦

A_VH ; and

the wax has an acid value A_VWAX satisfying

space="preserve" listing-type="equation">0.5×

A.sub.VL >

A.sub.VWAX >

0.05×

A.sub.VL

and

space="preserve" listing-type="equation">1.5 mgKOH/g≦

A.sub.VWAX ≦

13.0 mg/KOH/g.

37.

37. The method according to claim 36, wherein the toner image is transferred to a transfer-receiving member via or without via an intermediate transfer member, and then the toner image is fixed onto the transfer receiving member under application of heat and pressure by fixing means.

38. The method according to claim 37, wherein the toner image is transferred onto the transfer-receiving member by contact means supplied with a bias voltage.

39. The method according to claim 37, wherein the electrostatic image-bearing member surface is cleaned by cleaning means after the toner image is transferred therefrom.

40. The method according to claim 36, wherein said electrostatic image-bearing member is charged by charging means and then exposed to light to form the electrostatic image thereon.

41. The method according to claim 40, wherein the electrostatic image-bearing member is charged by contact charging means.