Method for making multilayer optical films having thin optical layers

• US 5,976,424 A
• Filed: 07/31/1997
• Issued: 11/02/1999
• Est. Priority Date: 07/31/1996
• Status: Expired due to Term

• Current Assignee: Minnesota Mining and Manufacturing Co (3M Company)
• Original Assignee: Minnesota Mining and Manufacturing Co (3M Company)
• Inventors: Weber, Michael F., Ouderkirk, Andrew J., Stover, Carl A., Merrill, William W.
• Primary Examiner(s): Vargot, Mathieu D.
• Application Number:
  US08/904,325
• Time in Patent Office: 824 Days
• Field of Search: 264/1.6, 264/1.7, 264/1.9, 264/173.12, 264/173.15, 264/173.16, 264/216, 264/290.2
• US Class Current: 264/1.6
• CPC Class Codes: B29C 48/08 flexible, e.g. films
• CPC Class Codes: B29C 48/21 the layers being joined at their surfaces
• CPC Class Codes: B29C 48/307 specially adapted for bringing together components, e.g. melts within the die
• CPC Class Codes: B29K 2067/00 Use of polyesters or derivatives thereof, as moulding material
• CPC Class Codes: B32B 27/36 comprising polyesters
• CPC Class Codes: G02B 1/10 Optical coatings produced by application to, or surface treatment of, optical elements G02B1/08 takes precedence
• CPC Class Codes: G02B 5/287 comprising at least one layer of organic material

Abstract

A method for making multilayer optical films is provided in which the degradation of the optical extinction of the thinnest optical layers is avoided by casting these layers close to the casting wheel.

Claims

1. A method for making a multilayer optical film, comprising the steps of:

providing a first and second resin;

extruding the first and second resins into a resin stream comprising a plurality of layers and having first and second major surfaces, wherein at least some of the plurality of layers comprise the first resin and at least some of the plurality of layers comprise the second resin, wherein the number of layers having a layer thickness of less than k microns and disposed within 400 microns of the first surface is greater than the number of layers having a layer thickness of less than k microns and disposed within 400 microns of the second surface, and wherein k≦

10; and

casting the resin stream against a casting surface such that the first major surface is in contact with the casting surface.

2. The method of claim 1, wherein k=10.

3. The method of claim 1, wherein k=2.

4. The method of claim 1, wherein k=0.5.

5. The method of claim 1, wherein the first resin comprises a polymer derived from at least one monomer selected from the group consisting of aromatic dicarboxylic acids and esters thereof.

6. The method of claim 5, wherein the monomer is naphthalene dicarboxylic acid.

7. The method of claim 1, wherein the second resin comprises a polymer derived from at least one monomer selected from the group consisting of naphthalene dicarboxylic acid, isophthalic acid, terephthalic acid, and the esters thereof.

8. The method of claim 7, wherein the monomer is a copolymer of naphthalene dicarboxylic acid and isophthalic acid.

9. The method of claim 1, wherein the resin stream is cast such that one surface of the resin stream is against the casting surface and the other surface is exposed to air.

10. The method of claim 1, wherein the casting wheel is cooled to less than the ambient temperature.

11. The method of claim 1, wherein the resin stream has a symmetric square wave index profile.

12. The method of claim 1, wherein the resin stream comprises a plurality of layer packets separated from each other by at least one boundary layer, and wherein the thicknesses of the layers in each layer packet change essentially monotonically in the direction of the layer thicknesses.

13. The method of claim 1, wherein the optical layers within the resin stream exhibit an essentially monotonically increasing layer thickness profile from the first surface to the second surface.

14. The method of claim 1, wherein the resin stream is heated to at least about 270°

C. and wherein the casting wheel is cooled with a coolant having a temperature of less than about 20°

C.

15. The method of claim 1, further comprising the step of:

stretching the cast resin stream.

16. The method of claim 1, wherein the casting surface is a casting wheel.

17. A method for making a multilayer optical film, comprising the steps of:

providing first and second resins;

extruding the first and second resins into a resin stream having a plurality of layers and having first and second major surfaces, wherein at least some of the plurality of layers comprise the first resin and at least some of the plurality of layers comprise the second resin, wherein at least some of the plurality of layers are of a first layer type having a layer thickness of less than k microns, where k≦

10, and wherein at least some of the layers of the first layer type are disposed within 400 microns of the first surface and at least some of the layers of the first layer type are disposed within 400 microns of the second surface; and

casting the resin stream such that the first major surface of the resin stream is in contact with a first casting surface and the second major surface is in contact with a second casting surface.

18. The method of claim 17, wherein k=10.

19. The method of claim 17, wherein k=2.

20. The method of claim 17, wherein k=0.5.

21. The method of claim 17, wherein the first and second casting surfaces are opposing surfaces.

22. A method for making a multilayer optical film, comprising the steps of:

providing first and second resins;

extruding the first and second resins into a resin stream having a plurality of layers and having first and second major surfaces, wherein at least some of the plurality of layers comprise a first resin and at least some of the plurality of layers comprise a second resin, wherein a first set having at least one member and consisting of the layers having layer thicknesses of less than k microns and disposed within 400 microns of the first surface has at least as many members as a second set consisting of the layers having layer thicknesses of less than k microns and disposed within 400 microns of the second surface, wherein k≦

10, and wherein the median layer thickness of the first set is not greater than the median layer thickness of the second set; and

casting the resin stream against a casting surface such that the first surface is in contact with the casting surface.

23. The method of claim 22, wherein k=10.

24. The method of claim 22, wherein k=2.

25. The method of claim 22, wherein k=0.5.

26. A method for making a multilayer optical film, comprising the steps of:

providing a first and second resin;

extruding the first and second resin into a resin stream having first and second major surfaces and comprising a plurality of layers, wherein at least some of said plurality of layers are of a first layer type having a layer thickness of less than k microns, wherein k≦

10, and wherein substantially all of said of layers of said first layer type are disposed within 400 microns of the first surface; and

casting the first major surface of the resin stream against a casting surface.

27. The method of claim 26, wherein k=10.

28. The method of claim 26, wherein k=2.

29. The method of claim 26, wherein k=0.5.

30. A method for making a multilayer optical film, comprising the steps of:

providing a first and second resin;

extruding the first and second resins into a resin stream comprising a plurality of layers and having first and second major surfaces, wherein at least some of the plurality of layers comprise the first resin and at least some of the plurality of layers comprise the second resin, and wherein at least some of the plurality of layers are of a first layer type having a layer thickness of less than k microns, wherein k≦

10; and

bringing the resin stream into contact with at least one casting surface, such that substantially all of the layers of the first layer type are disposed within about 400 microns of at least one casting surface.

31. The method of claim 30, wherein substantially all of the layers of the first layer type are disposed within about 400 microns of the first major surface.

32. The method of claim 31, wherein k=1.

33. The method of claim 31, wherein k=0.5.

34. A method for making a multilayer optical film, comprising the steps of:

providing a first and second resin;

extruding the first and second resin into a resin stream comprising a plurality of layers and having first and second major surfaces, wherein at least some of the plurality of layers comprise the first resin and at least some of the plurality of layers comprise the second resin, wherein at least some of the plurality of layers are of a first layer type having a layer thickness of less than 1 micron, and wherein the portion of the resin stream within 400 microns of the second major surface is substantially devoid of layers of the first layer type; and

casting the resin stream such that the first major surface of the resin stream is in contact with a casting surface.