Ultraviolet rays-absorbing composition and process for producing the same

• US 5,976,511 A
• Filed: 12/11/1997
• Issued: 11/02/1999
• Est. Priority Date: 04/25/1996
• Status: Expired due to Term

• Current Assignee: Sakai Chemical Industry Company Limited
• Original Assignee: Sakai Chemical Industry Company Limited
• Inventors: Sato, Noriaki, Ohtsu, Koichi
• Primary Examiner(s): Dodson, Shelley A.
• Application Number:
  US08/973,819
• Time in Patent Office: 691 Days
• Field of Search: 424/59, 424/60, 424/400, 424/401, 424/69, 423/554, 106/461, 106/471
• US Class Current: 424/59
• CPC Class Codes: A61K 2800/436 Interference pigments, e.g. Iridescent, Pearlescent
• CPC Class Codes: A61K 8/19 containing inorganic ingredients
• CPC Class Codes: A61K 8/27 Zinc; Compounds thereof
• CPC Class Codes: A61K 8/29 Titanium; Compounds thereof
• CPC Class Codes: A61Q 17/04 Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
• CPC Class Codes: C01P 2004/20 extending in two dimensions, e.g. plate-like
• CPC Class Codes: C01P 2004/84 one phase coated with the other
• CPC Class Codes: C09C 1/0015 Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings
• CPC Class Codes: C09K 15/326 containing only metals
• CPC Class Codes: C11D 3/0089 Pearlescent compositions; Opacifying agents

Abstract

The invention provides an ultraviolet rays-absorbing composition having a pearly luster which comprises plate barium sulfate particles having a surface coated with at least one of zinc oxide, cerium oxide and titanium oxide and a process for preparing the same. The composition has a pearly luster of stable quality, satisfactory translucence, and a satisfactory feel.

Claims

1. An ultraviolet rays-absorbing composition having a pearly luster which comprises plate barium sulfate particles having a surface coated with at least one of zinc oxide, cerium oxide and titanium oxide.

2. The ultraviolet rays-absorbing composition according to claim 1, wherein the plate barium sulfate particles have an average particle diameter of 3 to 70 μ

m and an average thickness of 0.05 to 2 μ

m.

3. The ultraviolet rays-absorbing composition according to claim 1, wherein at least one of the zinc oxide, cerium oxide and titanium oxide has a maximum particle size of not more than 0.2 μ

m and an average particle size of 10 to 150 nm.

4. A process for producing an ultraviolet rays-absorbing composition according to any one of claims 1, 2 and 3, which comprises:

suspending plate barium sulfate in water;

adding an aqueous solution of a zinc salt to the suspension;

adding at least one aqueous solution selected from the group consisting of aqueous ammonia, an aqueous solution of an alkali hydroxide, an aqueous solution of an alkali carbonate, an aqueous solution of ammonium carbonate and an aqueous solution of ammonium hydrogencarbonate;

obtaining plate barium sulfate particles having a surface coated with zinc oxide by filtration, washing with water, drying and calcining; and

preparing a composition using the plate barium sulfate having a surface coated with zinc oxide.

5. A process for producing an ultraviolet rays-absorbing composition according to any one of claims 1, 2 and 3, which comprises:

suspending plate barium sulfate in water;

adding an aqueous solution of a cerium salt to the suspension;

adding at least one aqueous solution selected from the group consisting of aqueous ammonia, an aqueous solution of an alkali hydroxide, an aqueous solution of an alkali carbonate, an aqueous solution of ammonium carbonate and an aqueous solution of ammonium hydrogencarbonate;

obtaining plate barium sulfate particles having a surface coated with cerium oxide by filtration, washing with water, drying and calcining; and

preparing a composition using the plate barium sulfate having a surface coated with cerium oxide.

6. A process for producing an ultraviolet rays-absorbing composition according to any one of claims 1, 2 and 3, which comprises:

suspending plate barium sulfate in water;

adding a titanyl sulfate aqueous solution or a titanium tetrachloride aqueous solution to the suspension;

subjecting the suspension to hydrolysis under heating or adding to the suspension at least one alkali solution selected from the group consisting of aqueous ammonia, an alkali hydroxide aqueous solution and a urea aqueous solution;

obtaining plate barium sulfate particles having a surface coated with zinc oxide by filtration, washing with water, drying and calcining; and

preparing a composition using the plate barium sulfate having a surface coated with titanium oxide.

7. A process for producing an ultraviolet rays-absorbing composition according to any one of claims 1, 2 and 3, which comprises:

(A) at least one set of procedures selected from the group consisting of i) and ii) as follows;

i) at least two routines selected from the group consisting of a), b) and c) as follows;

a) suspending plate barium sulfate in water;

adding an aqueous solution of a zinc salt to the suspension; and

adding at least one aqueous solution selected from the group consisting of aqueous ammonia, an aqueous solution of an alkali hydroxide, an aqueous solution of an alkali carbonate, an aqueous solution of ammonium carbonate, and an aqueous solution of ammonium hydrogencarbonate;

b) suspending plate barium sulfate in water;

adding an aqueous solution of a cerium salt to the suspension; and

adding at least one aqueous solution selected from the group consisting of aqueous ammonia, an aqueous solution of an alkali hydroxide, an aqueous solution of an alkali carbonate, an aqueous solution of ammonium carbonate, and an aqueous solution of ammonium hydrogencarbonate; and

c) suspending plate barium sulfate in water;

adding a titanyl sulfate aqueous solution or a titanium tetrachloride aqueous solution to the suspension; and

subjecting the suspension to hydrolysis under heating or adding to the suspension at least one alkali solution selected from the group consisting of aqueous ammonia, an alkali hydroxide aqueous solution and a urea aqueous solution; and

obtaining plate barium sulfate having a surface coated with at least two oxides selected from the group consisting of zinc oxide, cerium oxide and titanium oxide, by filtration, washing with water, drying and calcining; and

ii) suspending plate barium sulfate in water;

adding to the aqueous suspension at least two solutions selected from the group consisting of a zinc salt aqueous solution, a cerium salt aqueous solution and a titanyl sulfate aqueous solution or a titanium tetrachloride aqueous solution;

subjecting the suspension to hydrolysis under heating or adding to the suspension at least one alkali solution selected from the group consisting of aqueous ammonia, an alkali hydroxide aqueous solution and a urea aqueous solution; and

obtaining plate barium sulfate having a surface coated with at least two oxides selected from the group consisting of zinc oxide, cerium oxide and titanium oxide, by filtration, washing with water, drying and calcining; and

(B) preparing a composition using the plate barium sulfate particles of (A) having a surface coated with at least two oxides selected from the group consisting of zinc oxide, cerium oxide and titanium oxide.