Modified emulsion aggregation processes

• US 5,977,210 A
• Filed: 01/30/1995
• Issued: 11/02/1999
• Est. Priority Date: 01/30/1995
• Status: Expired due to Term

• Current Assignee: Xerox Corporation (Xerox Holdings Corp.)
• Original Assignee: Xerox Corporation (Xerox Holdings Corp.)
• Inventors: Kmiecik-Lawrynowicz, Grazyna E., Breton, Marcel P., Ong, Beng S., Patel, Raj D., Hopper, Michael A.
• Primary Examiner(s): McCamish, Marion
• Assistant Examiner(s): Guarriello, John J.
• Application Number:
  US08/380,550
• Time in Patent Office: 1,737 Days
• Field of Search: 523/161, 524/458, 524/495, 524/496, 430/137
• US Class Current: 523/161
• CPC Class Codes: C08F 2/26 anionic
• CPC Class Codes: C09D 11/30 Inkjet printing inks
• CPC Class Codes: Y10S 977/902 Specified use of nanostructure

Abstract

A process for the preparation of ink compositions comprising the emulsion polymerization of monomer, water, surfactant, and initiator with stirring and heating to provide a latex; mixing therewith a pigment dispersion of pigment particles, water, and cationic surfactant; blending the mixture; thereafter stirring the mixture; and subsequently adding additional anionic surfactant to stabilize the aggregate particles.

Claims

1. A process for the preparation of ink compositions consisting essentially of in the following order the emulsion polymerization of monomer, water, surfactant, and initiator with stirring and heating to provide a latex;

mixing therewith a pigment dispersion of pigment particles, water, and cationic surfactant;

blending the mixture;

thereafter stirring the mixture; and

subsequently adding anionic surfactant to stabilize the aggregate particles, and wherein said cationic surfactant is selected in an amount of from about 0.1 weight percent to about 0.75 weight percent, and wherein said ink compositions contain a polymer formed by the emulsion polymerization of said monomer and pigment.

2. A process in accordance with claim 1 wherein in the emulsion polymerization of monomer, water and surfactant, said surfactant is an ionic surfactant, and wherein said ionic surfactant stabilizes said ink compositions.

3. A process in accordance with claim 1 wherein the formed particles are of a size diameter of from about 0.005 to about 1 micron.

4. A process in accordance with claim 1 wherein the cationic surfactant is present in an amount of 0.5 weight percent.

5. A process in accordance with claim 1 wherein the surfactant utilized in preparing the pigment dispersion is a cationic surfactant, and the surfactant present in the latex mixture is an anionic surfactant.

6. A process in accordance with claim 1 wherein the surfactant utilized in preparing the pigment dispersion is an anionic surfactant, and the surfactant present in the latex mixture is a cationic surfactant.

7. A process in accordance with claim 1 wherein the dispersion is accomplished by homogenizing at from about 1,000 revolutions per minute to about 10,000 revolutions per minute, at a temperature of from about 20°

C. to about 35°

C., and for a duration of from about 1 minute to about 120 minutes.

8. A process in accordance with claim 1 wherein the dispersion is accomplished by an ultrasonic probe at from about 300 watts to about 900 watts of energy, at from about 5 to about 50 megahertz of amplitude, at a temperature of from about 25°

C. to about 55°

C., and for a duration of from about 1 minute to about 120 minutes.

9. A process in accordance with claim 1 wherein the dispersion is accomplished by microfluidization in a microfluidizer, or in nanojet for a duration of from about 1 minute to about 120 minutes.

10. A process in accordance with claim 1 wherein the blending is accomplished by homogenizing at from about 1,000 revolutions per minute to about 10,000 revolutions per minute for a duration of from about 1 minute to about 120 minutes.

11. A process in accordance with claim 1 wherein the polymer formed from said monomer is selected from the group consisting of poly(styrene-butadiene), poly(para-methyl styrene-butadiene), poly(meta-methylstyrene-butadiene), poly(alpha-methylstyrene-butadiene), poly(methylmethacrylate-butadiene), poly(ethylmethacrylate-butadiene), poly(propylmethacrylate-butadiene), poly(butylmethacrylate-butadiene), poly(methylacrylate-butadiene), poly(ethylacrylate-butadiene), poly(propylacrylate-butadiene), poly(butylacrylate-butadiene), poly(styrene-isoprene), poly(para-methyl styrene-isoprene), poly(meta-methylstyrene-isoprene), poly(alpha-methylstyrene-isoprene), poly(methylmethacrylate-isoprene), poly(ethylmethacrylate-isoprene), poly(propylmethacrylate-isoprene), poly(butylmethacrylate-isoprene), poly(methylacrylate-isoprene), poly(ethylacrylate-isoprene), poly(propylacrylate-isoprene), and poly(butylacrylate-isoprene).

12. A process in accordance with claim 1 wherein the polymer formed from said monomer is styrene/butylacrylate/acrylic acid.

13. A process in accordance with claim 1 wherein the polymer formed from said monomer is styrene/butylacrylate/acrylic acid.

14. A process in accordance with claim 1 wherein the polymer formed from said monomer is styrene/butylacrylate/acrylic acid 82:

18;

2.

15. A process in accordance with claim 1 wherein the polymer formed from said monomer is styrene/butylacrylate/acrylic acid 82:

18;

2.

16. A process in accordance with claim 1 wherein in the emulsion polymerization of monomer, water, surfactant, and initiator, said surfactant is a nonionic surfactant selected from the group consisting of polyvinyl alcohol, methalose, methyl cellulose, ethyl cellulose, propyl cellulose, hydroxy ethyl cellulose, carboxy methyl cellulose, polyoxyethylons cetyl ether, polyoxyethylens lauryl ether, polyoxyethylene octyl ether, polyoxyethylene octylphenyl ether, polyoxyethylene oleyl ether, polyoxyethylene sorbitan monolaurate, polyoxyethylene stearyl ether, polyoxyethylene nonylphenyl ether, and dialkylphenoxy poly(ethyleneoxy)ethanol.

17. A process in accordance with claim 1 wherein the anionic surfactant is selected from the group consisting of sodium dodecyl sulfate, sodium dodecylbenzene sulfate, and sodium dodecyinaphthalene sulfate.

18. A process in accordance with claim 1 wherein the cationic surfactant is a quaternary ammonium salt.

19. A process in accordance with claim 1 wherein the pigment is carbon black, cyan, yellow, magenta, or mixtures thereof.

20. A process in accordance with claim 1 wherein the surfactant for said emulsion polymerization is a nonionic surfactant concentration is from about 0.1 to about 5 weight percent;

the anionic surfactant concentration is about 0.1 to about 5 weight percent; and

the cationic surfactant concentration is about 0.4 to about 0.6 weight.

21. A process in accordance with claim 1 wherein the latex in an amount of from about 10 to about 25 weight percent is mixed with the pigment dispersion of pigment particles, and which dispersion is selected in an amount of from about 1 to about 10 weight percent, water, and cationic surfactant in the range of 0.1 to 0.75 weight percent;

blending the mixture resulting for a period of 1 to 30 minutes;

thereafter stirring the mixture at a speed in the range of 100 to 300 rpm for a period of 5 to 30 minutes; and

subsequently adding said additional anionic surfactant in the range of 2 to 10 percent to stabilize the aggregate particles.

22. A process in accordance with claim 1 further comprising adding to the formed ink a humectant in the amount of from about 2 to about 50 percent by weight, or a biocide present in the amount of from about 0.02 to about 0.1 percent by weight.

23. A printing process which comprises (1) incorporating into an ink jet printing apparatus the ink composition obtained by the process of claim 1, and (2) causing droplets of the ink to be ejected in an imagewise pattern onto a substrate, thereby generating images on the substrate.

24. A printing process in accordance with claim 23 wherein the ink jet printing apparatus employs a thermal ink jet printing process.

25. A printing process in accordance with claim 23 wherein there are provided prints on paper with solid area coverage having an optical density of from about 0.001 to about 0.05, and a waterfastness of from about 80 percent to about 99 percent.

26. A process in accordance with claim 23 wherein said mixture upon jetting is heated above or at the polymer glass transition, which heating enables the evaporation of water and thereby increases said additional anionic surfactant concentration, thereby enabling the further aggregation of the ink particles on the substrate and enhancing the optical density of the image.

27. A process in accordance with claim 1 wherein the emulsion polymerization surfactant and the cationic surfactant are comprised of similar components.

28. A process in accordance with claim 1 wherein the mixture resulting said additional anionic surfactant is heated above or at the polymer glass transition temperature.

29. A process in accordance with claim 1 wherein the ink particles formed are submicron in size.

30. A process for the preparation of ink compositions consisting of accomplishing in the following order the emulsion polymerization of monomer, water, surfactant, and initiator with stirring and heating to provide a latex;

mixing therewith a pigment dispersion of pigment particles, water, and cationic surfactant, blending the mixture;

thereafter stirring the mixture; and

subsequently adding anionic surfactant to stabilize the aggregate particles, and wherein the molar ratio of cationic surfactant to anionic surfactant is from 0.5 to 1.5, and wherein the latex in an amount of from about 10 to about 25 weight percent is mixed with the pigment dispersion of pigment particles, and which dispersion is selected in an amount of from about 1 to about 10 weight percent, water, and cationic surfactant;

blending the mixture resulting for a period of 1 to 30 minutes;

thereafter stirring the mixture at a speed in the range of 100 to 300 rpm for a period of 5 to 30 minutes; and

subsequently adding extra anionic surfactant in the range of 2 to 10 percent to stabilize the aggregate particles.

31. A process in accordance with claim 30 wherein the amount of cationic surfactant is equal to about 0.5 mol to the mol ratio of the anionic surfactant.

32. A process for the preparation of ink compositions consisting essentially of accomplishing in the following order the emulsion polymerization of monomer, water, surfactant, and initiator with stirring and heating to provide a latex;

mixing therewith a pigment dispersion of pigment particles, water, and cationic surfactant;

blending the mixture;

thereafter stirring the mixture; and

subsequently adding anionic surfactant to stabilize the aggregate particles, and wherein the molar ratio of cationic to anionic surfactant is from 0.5 to 1.5, and wherein said ink compositions contain a polymer and pigment.

33. A process for the preparation of ink compositions consisting of in the following order the emulsion polymerization of monomer, water, surfactant, and initiator with stirring and heating to provide a latex;

mixing therewith a pigment dispersion of pigment particles, water, and cationic surfactant;

blending the mixture;

thereafter stirring the mixture; and

subsequently adding additional anionic surfactant to stabilize the aggregate particles, and wherein said cationic surfactant is selected in an amount of from about 0.1 weight percent to about 0.75 weight percent, and wherein said ink compositions contain a polymer and pigment.