Coated sheet material

• US 5,981,011 A
• Filed: 01/05/1995
• Issued: 11/09/1999
• Est. Priority Date: 01/22/1992
• Status: Expired due to Fees

• Current Assignee: Mirropak CT LLC
• Original Assignee: A*Ware Technologies, L.C.
• Inventors: Elsenbaumer, Ronald L., Overcash, Derric T.
• Primary Examiner(s): Chen, Vivian
• Application Number:
  US08/369,135
• Time in Patent Office: 1,769 Days
• Field of Search: 428/34.2, 428/35.7, 428/36.6, 428/36.7, 428/352, 428/507, 428/508, 428/511, 428/514, 428/40.9, 428/41.8, 428/425.1, 428/452, 428/479.6, 428/481, 525/56, 525/61, 525/62
• US Class Current: 428/40.9
• CPC Class Codes: D21H 19/08 applied as vapour, e.g. in vacuum
• CPC Class Codes: D21H 19/12 applied as a solution using water as the only solvent, e.g. in the presence of acid or alkaline compounds
• CPC Class Codes: D21H 19/16 comprising curable or polymerisable compounds D21H19/24 takes precedence
• CPC Class Codes: D21H 19/20 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
• CPC Class Codes: D21H 19/58 Polymers or oligomers of diolefins, aromatic vinyl monomers or unsaturated acids or derivatives thereof
• CPC Class Codes: D21H 19/82 superposed D21H19/84 takes precedence
• CPC Class Codes: D21H 19/824 two superposed coatings, both being non-pigmented
• CPC Class Codes: D21H 19/826 two superposed coatings, the first applied being pigmented and the second applied being non-pigmented
• CPC Class Codes: D21H 19/84 on both sides of the substrate
• CPC Class Codes: D21H 27/001 Release paper
• CPC Class Codes: G03H 1/0272 Substrate bearing the hologram
• CPC Class Codes: G03H 2270/12 Fibrous, e.g. paper, textile
• CPC Class Codes: Y02P 20/582 Recycling of unreacted starting or intermediate materials
• CPC Class Codes: Y10T 428/1303 Paper containing [e.g., paperboard, cardboard, fiberboard, etc.]
• CPC Class Codes: Y10T 428/1379 Contains vapor or gas barrier, polymer derived from vinyl chloride or vinylidene chloride, or polymer containing a vinyl alcohol unit
• CPC Class Codes: Y10T 428/1383 Vapor or gas barrier, polymer derived from vinyl chloride or vinylidene chloride, or polymer containing a vinyl alcohol unit is sandwiched between layers [continuous layer]
• CPC Class Codes: Y10T 428/1438 Metal containing
• CPC Class Codes: Y10T 428/1476 Release layer
• CPC Class Codes: Y10T 428/24802 Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
• CPC Class Codes: Y10T 428/31507 Of polycarbonate
• CPC Class Codes: Y10T 428/3154 : Of fluorinated addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31551 : Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
• CPC Class Codes: Y10T 428/31591 : Next to cellulosic
• CPC Class Codes: Y10T 428/31663 : As siloxane, silicone or silane
• CPC Class Codes: Y10T 428/31725 : Of polyamide
• CPC Class Codes: Y10T 428/31779 : Next to cellulosic
• CPC Class Codes: Y10T 428/31783 : Paper or wood
• CPC Class Codes: Y10T 428/31786 : Of polyester [e.g., alkyd, etc.]
• CPC Class Codes: Y10T 428/3179 : Next to cellulosic
• CPC Class Codes: Y10T 428/31855 : Of addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/3188 : Next to cellulosic
• CPC Class Codes: Y10T 428/31895 : Paper or wood
• CPC Class Codes: Y10T 428/31906 : Ester, halide or nitrile of addition polymer
• CPC Class Codes: Y10T 428/31931 : Polyene monomer-containing
• CPC Class Codes: Y10T 428/31935 : Ester, halide or nitrile of addition polymer
• CPC Class Codes: Y10T 428/31949 : Next to cellulosic

Abstract

A coated sheet material made by : (a) coating a porous substrate sheet material with a barrier coating composition comprising (i) a cross-linkable polymer resistant to penetration by water moisture, and (ii) a water-dispersible film-forming polymer that is resistant to penetration by grease and oil, said barrier coating composition forming a barrier layer on said substrate sheet material; and (b) coating said barrier layer with a release coating composition wherein the cross-linkable polymer and the water-dispersible film-forming polymer are different. The coated sheet material is useful in forming articles and food wrappers for use in conventional or microwave ovens.

Claims

1. A coated sheet material comprised of:

a porous substrate sheet material having at least two oppositely disposed surfaces; and

a barrier coating on at least one surface of said substrate sheet material wherein said barrier coating is formed from a dispersion comprised of a mixture of;

(i) a cross-linkable first polymer that is resistant to penetration by water moisture when cured, and (ii) a water-dispersible, film-forming second polymer that is resistant to penetration by grease and oil when cured, wherein said first and second polymers are different.

2. The coat sheet material as recited in claim 1, wherein said substrate sheet material comprises cellulose.

3. The coated sheet material as recited in claim 1, wherein said water-dispersible, film-forming polymer is selected from the group consisting of:

poly(butylene alcohol), poly(propylene alcohol), poly(vinyl alcohol), poly(hydroxyethyl acrylate), and polyvinyl acetate, and copolymers derived from any of the foregoing.

4. The coated sheet material as recited in claim 1, wherein the cross-linkable polymer and the water dispersible polymer are selected from the group consisting of poly(vinyl alcohol)s, poly(butylene alcohol)s, poly(propylene alcohol)s, poly(1-(hydroxylmethyl) ethylene), poly(1-hydroxylethyl) ethylene), and copolymers derived therefrom.

5. The coated sheet material as recited in claim 1, wherein said cross-linkable polymer has an average molecular weight before curing of greater than 5,000 and is selected from the group consisting of:

poly(dienes), poly(methacrylics), poly(acrylamides), poly(methacrylic acids), poly(vinyl ethers), poly(vinyl halides), poly(vinyl esters) and hydrolyzed or partially hydrolyzed derivatives thereof, poly(styrenes), poly(oxides), poly(carbonates), poly(esters), poly(anhydrides), poly(urethanes), poly(siloxanes), poly(sulfones), poly(sulfonamides), poly(amides), poly(imines), poly(benzimidazoles), carbohydrates, poly(vinyl alcohol), poly(propyl alcohol), poly(butyl alcohol), poly(1-(hydroxylmethyl) ethylene), poly(1-hydroxyethyl) ethylene, styrene butadiene, hydroxylated polymers, and copolymers derived from any of the foregoing.

6. The coated sheet material as recited in claim 5, wherein said water-dispersible, film-forming polymer is selected from the group consisting of:

poly(butylene alcohol), poly(propylene alcohol), poly(vinyl alcohol), poly(hydroxyethyl acrylate), and polyvinyl acetate, and copolymers derived from any of the foregoing.

7. The coated sheet material as recited in claim 6, wherein said cross-linkable polymer is crosslinked by a crosslinking agent selected from the group consisting of:

maleic anyhdride, polymers comprising maleic anhydride, copolymers comprising maleic anhydride, glyoxals, anhydrides, ethyl oxylate, epichlorohydrin, polymers comprising epichlorohydrin, copolymers comprising epichlorohydrin, metal ions, fatty acid complexes of metal ions, exposure to heat, high energy radiation, gamma radiation, x-rays, ultraviolet radiation, visible radiation, electron beams, corona discharges, and combinations thereof.

8. The coated sheet material of claim 1, wherein the barrier layer coating additionally comprises any combination of fillers, dyes, pigments, colorants, metallized layers, printing, gloss, and texture.

9. The coated sheet material of claim 1 further comprising a release coating on said barrier coating.

10. The coated sheet material as recited in claim 9, wherein said release coating is comprised of a fatty acid compound.

11. The coated sheet material as recited in claim 10, wherein said fatty acid compound is a metal complex of a fatty acid.

12. The coated sheet material as recited in claim 10, wherein said fatty acid compound is a chrome complex of a fatty acid.

13. The coated sheet material as recited in claim 9, wherein said release coating comprises a metal complex of a fatty acid compound.

14. The coated sheet material as recited in claim 13, wherein said substrate sheet material comprises cellulose.

15. The coated sheet material as recited in claim 14, wherein said sheet material has a basis weight of between about 20 pounds per 1000 square feet of sheet material and about 40 pounds per 1000 square feet of sheet material.

16. The coated sheet material as recited in claim 15, wherein said sheet material is a corrugated sheet material, and is ovenable in a conventional oven at temperatures of about 400°

F.

17. The coated sheet material as recited in claim 16, wherein said coated sheet material is dual-ovenable.

18. The coated sheet material of claim 17, wherein said substrate material comprises cellulose;

said barrier coating is comprised of a polyvinyl alcohol; and

said release coating is comprised of a fatty acid complex of chromium.

19. The coated sheet material of claim 1 wherein the first polymer is crosslinked polyvinyl alcohol and the second polymer is uncrosslinked polyvinyl alcohol.

20. An article comprised of:

a porous substrate material having at least two oppositely disposed surfaces; and

a barrier coating on at least one surface of said substrate material wherein said barrier coating is formed from a dispersion comprised of a mixture of;

(i) a cross-linkable first polymer that is resistant to penetration by water moisture when cured, and (ii) a water-dispersible, film-forming second polymer that is resistant to penetration by grease and oil when cured wherein said first and second polymers are different.

21. The article as recited in claim 20, wherein said cross-linkable polymer has an average molecular weight before curing of greater than 5,000 and is selected from the group consisting of:

poly(dienes),poly(methacrylics), poly(acrylamides), poly(methacrylic acids), poly(vinyl ethers), poly(vinyl halides), poly(vinyl esters) and hydrolyzed or partially hydrolyzed derivatives thereof, poly(styrenes), poly(oxides), poly(carbonates), poly(esters), poly(anhydrides), poly(urethanes), poly(siloxanes), poly(sulfones), poly(sulfonamides), poly(amides), poly(imines), poly(benzimidazoles), carbohydrates, poly(vinyl alcohol), poly(propyl alcohol), poly(butyl alcohol),poly(1-(hydroxylmethyl) ethylene), poly(1-hydroxyethyl) ethylene, styrene butadiene, hydroxylated polymers, and copolymers derived from any of the foregoing.

22. The coated sheet material as recited in claim 21, wherein said water-dispersible, film-forming polymer is selected from the group consisting of:

poly(butylene alcohol), poly(propylene alcohol), poly(vinyl alcohol), poly(hydroxyethyl acrylate), and polyvinyl acetate, and copolymers derived from any of the foregoing.

23. The coated sheet material as recited in claim 22, wherein the crosslinkable polymer and the water dispersible polymer are selected from the group consisting of poly(vinyl alcohol)s, poly(butylene alcohol)s, poly(propylene alcohol)s, poly(1-(hydroxylmethyl) ethylene), poly(1-hydroxylethyl) ethylene), and copolymers derived therefrom.

24. The coated sheet material as recited in claim 21, wherein said cross-linkable polymer is crosslinked by a crosslinking agent selected from the group consisting of:

maleic anyhdride, polymers comprising maleic anhydride, copolymers comprising maleic anhydride, glyoxals, anhydrides, ethyl oxylate, epichlorohydrin, polymers comprising epichlorohydrin, copolymers comprising epichlorohydrin, metal ions, fatty acid complexes of metal ions, exposure to heat, high energy radiation, gamma radiation, x-rays, ultraviolet radiation, visible radiation, electron beams, corona discharges, and combinations thereof.

25. The article as recited in claim 20, wherein said cross-linkable polymer is a polyvinyl alcohol.

26. The article as recited in claim 20, wherein said water-dispersible, film-forming polymer is a polyvinyl alcohol.

27. The article as recited in claim 20, wherein said release coating is comprised of a metal complex of a fatty acid.

28. The article of claim 20 further comprising a release coating on said barrier coating.

29. The coated sheet material of claim 20 wherein the first polymer is crosslinked polyvinyl alcohol and the second polymer is uncrosslinked polyvinyl alcohol.

30. A coated sheet material comprised of:

a porous substrate sheet material having at least two oppositely disposed surfaces;

a barrier coating on at least one surface of said substrate sheet material wherein said barrier coating is formed from a dispersion comprised of a mixture of;

(i) a cross-linkable first polymer that is resistant to penetration by water moisture when cured, and (ii) a water-dispersible, film-forming second polymer that is resistant to penetration by grease and oil when cured, wherein said first and said second polymers are different; and

a release coating on said barrier coating.

31. The coated sheet material of claim 30 wherein the first polymer is crosslinked polyvinyl alcohol and the second polymer is uncrosslinked polyvinyl alcohol.

32. An article comprised of:

a porous substrate material having at least two oppositely disposed surfaces;

a barrier coating on at least one surface of said substrate material wherein said barrier coating is formed from a dispersion comprised of a mixture of;

(i) a cross-linkable first polymer that is resistant to penetration by water moisture when cured, and (ii) a water-dispersible, film-forming second polymer that is resistant to penetration by grease and oil when cured, wherein said first and second polymers are different; and

a release coating on said barrier coating.

33. The coated sheet material of claim 32 wherein the first polymer is crosslinked polyvinyl alcohol and the second polymer is uncrosslinked polyvinyl alcohol.