Multi-layer topcoat for an optical member

• US 5,981,059 A
• Filed: 01/22/1998
• Issued: 11/09/1999
• Est. Priority Date: 04/03/1995
• Status: Expired due to Fees

• Current Assignee: Southwall Technologies, Inc. (Eastman Chemical Company)
• Original Assignee: Southwall Technologies, Inc. (Eastman Chemical Company)
• Inventors: Bright, Clark I., Kozak, Julius G.
• Primary Examiner(s): Le, Hoa T.
• Application Number:
  US09/012,150
• Time in Patent Office: 656 Days
• Field of Search: 428/421, 428/422, 428/428, 428/429, 428/446, 428/447, 428/448, 428/336
• US Class Current: 428/336
• CPC Class Codes: B29D 11/00 Producing optical elements, e.g. lenses or prisms grinding or polishing of optical elements B24B; constructional form of optical elements G02B; optical parts of spectacles G02C7/00
• CPC Class Codes: G02B 1/111 using layers comprising organic materials
• CPC Class Codes: Y10T 428/265 1 mil or less
• CPC Class Codes: Y10T 428/3154 Of fluorinated addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31544 Addition polymer is perhalogenated
• CPC Class Codes: Y10T 428/31612 As silicone, silane or siloxane
• CPC Class Codes: Y10T 428/31663 As siloxane, silicone or silane

Abstract

An optical arrangement includes a transmissive or reflective substrate having a first surface on which a multi-layer antireflection stack is formed. The antireflection stack is protected by a fluorocarbon lubricating layer that reduces the surface energy of the exposed surface to less than 40 dynes/cm, and preferably less than 20 dynes/cm. The fluorocarbon lubricating layer and a silane adhesion promotion layer form a durable topcoat having desired mechanical and optical characteristics. The preferred material for forming the lubricating layer is a fluoropolymer sold by 3M Company under the federally registered trademark FLUORAD.

Claims

1. An optical arrangement comprising:

an optical substrate having opposed first and second sides; and

a multi-layer topcoat on at least one of said first and second sides, said topcoat being substantially transparent, said topcoat including;

an adhesion promotion layer formed of a silane; and

a lubricating layer formed of at least one fluorocarbon material, said lubricating layer contacting a surface of said adhesion promotion layer opposite to said substrate.

2. The optical arrangement of claim 1 further comprising an intermediate layer between said substrate and said topcoat, said intermediate layer being formed of a material containing at least one of silicon and oxygen, said adhesion promotion layer being in contact with said intermediate layer.

3. The optical arrangement of claim 2 further comprising a multi-layer antireflection stack in which adjacent layers have refractive indices selected to retard reflection, said stack including said intermediate layer, said substrate being optically transparent.

4. The optical arrangement of claim 3 wherein other than said intermediate layer, layers in said antireflection stack have generally equal optical thicknesses, said topcoat and said intermediate layer having a combined optical thickness that is generally equal to said optical thicknesses of said other layers in said antireflection stack.

5. The optical arrangement of claim 1 wherein said substrate is a display screen of a monitor.

6. The optical arrangement of claim 1 wherein said lubricating layer is formed of a material sold by 3M Company under the federally registered trademark FLUORAD.

7. The optical arrangement of claim 1 wherein said lubricating layer is formed of a material sold by duPont de Nemours under the federally registered trademark TEFLON AF.

8. The optical arrangement of claim 1 wherein said adhesion promotion layer is formed from N-(2-amino ethyl)-3-amino-propyltrimethoxysilane.

9. The optical arrangement of claim 1 wherein said lubricating layer has a thickness of less than 200 angstroms and a surface energy of less than 40 dynes/centimeter.

10. A method of lubricating an optical arrangement comprising steps of:

providing a light transmissive member having an upper surface of a material containing at least one of oxygen and silicon; and

forming a topcoat on said upper surface, including selecting and applying a silane bonding agent and at least one fluorocarbon lubricant such that said topcoat is generally optically inactive and such that said silane bonding agent and said at least one fluorocarbon lubricant are in contact with each other.

11. The method of claim 10 wherein said step of forming said topcoat includes separately applying said silane bonding agent and said at least one fluorocarbon lubricant in separate layers to form a two-layer topcoat, said layer of silane bonding agent being applied to said upper surface of said light transmissive member.

12. The method of claim 10 wherein said step of forming said topcoat includes mixing said silane bonding agent and said at least one fluorocarbon prior to applying said topcoat to said upper surface.

13. The method of claim 10 wherein said step of providing said light transmissive member includes forming an antireflection stack of layers having alternating refractive indices, said surface on which said topcoat is formed being a layer of said antireflection stack.

14. The method of claim 10 further comprising a step of applying said light transmissive member to a cathode ray tube (CRT).

15. The method of claim 10 wherein said step of selecting said at least one fluorocarbon comprises selecting one of FLUORAD and TEFLON AF.

16. A lamination on a display screen comprising:

an antireflection coating having a plurality of layers, including an outermost layer of a material having at least one of silicon and oxygen;

a silane adhesion promotion layer on said outermost layer; and

a fluorocarbon lubricating layer on said silane adhesion promotion layer, said adhesion promotion and lubricating layers forming an optically passive topcoat.

17. The lamination of claim 16 further comprising a substrate on a side of said antireflection coating opposite to said topcoat, said substrate being fixed to said display screen using one of a pressure-sensitive adhesive, a curable adhesive or electrostatic force.

18. The lamination of claim 16 wherein said fluorocarbon lubricating layer is formed of FLUORAD.

19. The lamination of claim 16 wherein a combined thickness of said outermost layer and said topcoat is generally equal to a thickness of each layer in said antireflection coating other than said outermost layer.

20. The lamination of claim 16 wherein a combined thickness of said outermost layer and said topcoat is generally equal to approximately a quarterwave optical thickness at visible wavelengths.