Automatic dishwashing compositions containing water soluble cationic or amphoteric polymers

• US 5,981,456 A
• Filed: 07/23/1997
• Issued: 11/09/1999
• Est. Priority Date: 07/23/1997
• Status: Expired due to Fees

• Current Assignee: Lever Brothers Company, Division Of Conopco, Inc.
• Original Assignee: Lever Brothers Company (Unilever PLC)
• Inventors: Carnali, Joseph Oreste, Tartakovsky, Alla, Gary, Richard Gerald
• Primary Examiner(s): Gupta, Yogendra
• Assistant Examiner(s): BOYER, CHARLES I
• Application Number:
  US08/898,758
• Time in Patent Office: 839 Days
• Field of Search: 510/220, 510/223, 510/230, 510/232, 510/233, 510/302, 510/401, 510/434, 510/436, 510/467, 510/475, 510/480, 510/485, 510/509, 510/510, 510/511, 510/512, 510/514
• US Class Current: 510/220
• CPC Class Codes: C11D 3/0073 Anticorrosion compositions
• CPC Class Codes: C11D 3/3719 Polyamides or polyimides
• CPC Class Codes: C11D 3/3723 Polyamines or polyalkyleneimines
• CPC Class Codes: C11D 3/3769 (Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
• CPC Class Codes: C11D 3/3776 Heterocyclic compounds, e.g. lactam
• CPC Class Codes: C11D 3/3796 Amphoteric polymers or zwitterionic polymers
• CPC Class Codes: C23F 11/173 Macromolecular compounds

Abstract

An automatic dishwashing detergent composition is described which contains an effective amount of a defined water soluble cationic or amphoteric polymer and a phosphate or nonphosphate builder. The polymers are soluble or dispersible to at least 0.01% by weight in distilled water at 25° C. A method of using the polymers to prevent fading or corrosion of dishware is also described.

Claims

1. A detergent composition which reduces corrosion of dishware in an automatic dishwashing machine comprising:

a) a glassware protective amount of a water-soluble cationic polymer having at least 1 monomer unit having a cationic charge over a portion of the pH range 6-11, wherein the cationic polymer is a compound of formula I;

##STR7## and b) 1 to 90 wt. % of a builder selected from the group consisting of a phosphate builder, a non-phosphate builder and mixtures thereof.

3. A composition according to claim 1 wherein the polymer is present at a level of 0.1 to 20 wt. % of the total composition.

4. A composition according to claim 1 wherein the phosphate builder is selected from the group consisting of alkali metal tripolyphosphates, sodium, potasssium and ammonium pyrophosphate, sodium and potassium orthophosphate, sodium polymeta/phosphate in which the degree of polymerization ranges from about 6 to 21, and salts of phytic acid.

5. A composition according to claim 1 wherein the nonphosphate builder is selected from the group consisting of water soluble alkali metal carbonates, bicarbonates, sesquicarbonates, borates, silicates, layered silicates, metasilicates, crystalline and amorphous aluminosilicates, alkali metal citrates, nitrilotriacetates, oxydisuccinates, acrylate/maleate copolymers and acrylate/maleate/vinyl alcohol terpolymers.

6. A composition according to claim 1 wherein the composition further comprises an effective amount of an oxygen bleach source.

2. A detergent composition which reduces corrosion of dishware in an automatic dishwashing machine comprising:

a) a glassware protective amount of a water-soluble cationic polymer, having at least 1 monomer unit having a cationic charge over a portion of the pH range 6-11, wherein the cationic polymer is a compound having the formula III;

##STR8## and b) 1 to 90 wt. % of a builder selected from the group consisting of a phosphate builder, a non-phosphate builder and mixtures thereof.

7. A method for reducing fading or corrosion of dishware in an automatic dishwashing machine comprising the steps of:

a) applying a glassware protective amount of a composition comprising;

(i) a glassware protective amount of a water soluble cationic polymer having at least 1 monomer unit having a cationic charge over a portion of the pH range 6-11, wherein the cationic polymer is a compound of formula I;

##STR9## (ii) a phosphate or nonphosphate builder present in an amount of from 1 to 90 wt. %; and

b) substantially cleaning the dishware without substantially fading or corroding.

9. A method according to claim 7 wherein the polymer is present at a level of 0.1 to 20 wt. % of the total composition.

10. A method according to claim 7 wherein the phosphate builder is selected from the group consisting of alkali metal tripolyphosphates, sodium, potasssium and ammonium pyrophosphate, sodium and potassium orthophosphate, sodium polymeta/phosphate in which the degree of polymerization ranges from about 6 to 21, and salts of phytic acid.

11. A method according to claim 7 wherein the nonphosphate builder is selected from the group consisting of water soluble alkali metal carbonates, bicarbonates, sesquicarbonates, borates, silicates, layered silicate, metasilicates, crystalline and amorphous aluminosilicates, alkali metal citrates, nitrilotriacetates, oxydisuccinates, acrylate/maleate copolymers and acrylate/maleate/vinyl alcohol terpolymers.

12. A method according to claim 7 wherein the composition further comprises a bleach an effective amount of an oxygen bleach source.

8. A method for reducing fading or corrosion of dishware in an automatic dishwashing machine comprising the steps of:

a) applying a glassware protective amount of a composition comprising;

(i) a glassware protective amount of a water soluble cationic or amphoteric polymer having at least 1 monomer unit having a cationic change over a portion of the pH ranges 6-11, wherein the cationic polymer is a compound having the formula III;

##STR10## (ii) a phosphate or nonphosphate builder present in an amount of from 1 to 90 wt. %; and

b) substantially cleaning the dishware without substantially fading or corroding.