Epoxy modified core-shell latices

• US 5,981,627 A
• Filed: 10/09/1992
• Issued: 11/09/1999
• Est. Priority Date: 08/02/1989
• Status: Expired due to Term

• Current Assignee: Celanese International Corporation (Celanese Corporation)
• Original Assignee: National Starch and Chemical Investment Holding Corporation
• Inventors: Pruiksma, Arthur B., Shih, Yen-Jer
• Primary Examiner(s): Lipman, Bernard
• Application Number:
  US07/959,011
• Time in Patent Office: 2,587 Days
• Field of Search: 523/201, 523/402, 523/407, 523/412, 523/414, 523/420, 523/423, 524/271, 524/272, 524/457
• US Class Current: 523/201
• CPC Class Codes: C08F 263/04 on to polymers of vinyl acetate
• CPC Class Codes: C08F 265/04 on to polymers of esters
• CPC Class Codes: C08F 269/00 Macromolecular compounds obtained by polymerising monomers on to polymers of heterocyclic oxygen-containing monomers as defined in group C08F24/00
• CPC Class Codes: C08F 283/10 on to polymers containing more than one epoxy radical per molecule C08F283/004 takes precedence
• CPC Class Codes: C08G 59/5026 cycloaliphatic
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C09J 151/003 grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds C09J151/04, C09J151/06 take precedence

Abstract

This invention relates to stable one-part latex compositions prepared by aqueous emulsion polymerization wherein a core-shell polymer is formed, the core formed by emulsion polymerization of an ethylenically unsaturated monomer in the presence of an epoxy resin and the shell polymer formed by emulsion polymerization of a hydroxy carboxyl containing monomer composition in the presence of the core, providing that the monomers in both the core and the shell do not contain amino functional groups, and post-adding to the formed core-shell polymer an organic compound having at least one amino functional group which is available for later reaction with the epoxy resin upon drying to produce a crosslinked polymer product.

Claims

1. A stable one-part latex composition produced by an aqueous emulsion polymerization method wherein a core-shell polymer is formed, said method comprising:

(a) forming a core polymer by emulsion polymerization, said core polymer comprising;

(1) from 1 to 60% by weight of an epoxy resin, and

(2) from 40 to 99% by weight of at least one ethylenically unsaturated monomer; and

(b) forming a shell polymer on said core by emulsion polymerization of a second monomer composition in the presence of said core, said monomer composition comprising;

(1) from 1 to 99.5% by weight of at least one ethylenically unsaturated monomer; and

(2) from 0.5 to 10% by weight of a hydroxyl or carboxyl functional monomer;

providing that said monomers in both said core and shell do not contain amino functional groups and wherein said core-shell polymer comprises from 1 to 80% by weight of the core polymer and from 20 to 99% by weight of the shell polymer; and

(c) post-adding to the formed core-shell polymer composition an effective curing amount of an organic compound containing at least one amino functional group which is available for later reaction with said epoxy resin upon drying to produce a crosslinked polymer product.

2. The latex composition of claim 1 wherein the core comprises a diglycidyl ether of bisphenol A and vinyl acetate.

3. The latex composition of claim 1 wherein the core-shell polymer has a solids content of at least 40%.

4. The latex composition of claim 1 wherein the core-shell polymer has a Tg of -70 to 50°

C.

5. The latex composition of claim 4 wherein the weight ratio of the core to shell monomers used is from about 40:

60 to 60;

40.

6. The latex composition of claim 4 wherein the epoxy resin is a water insoluble aromatic polyepoxide and the amino containing organic compound is a polyamine.

7. The latex composition of claim 4 wherein the core comprises a diglycidyl ether of bisphenol A and vinyl acetate and the amino containing organic compound is a polyamine.

8. A laminating adhesive comprising the latex composition of claim 1 wherein the core-shell polymer has a Tg of -70 to 30°

C. and a solids content of at least 40% by weight.

9. The laminating adhesive of claim 8 wherein the epoxy resin is a water insoluble aromatic polyepoxide and the amino containing organic compound is a polyamine.

10. A heat resistant binder comprising the latex composition of claim 1 wherein the core-shell polymer has a Tg of 20 to 50°

C. and a solids content of at least 40% by weight.

11. The heat resistant binder of claim 10 wherein the epoxy resin is a water insoluble aromatic polyepoxide and the amino containing organic compound is a polyamine.

12. A contact adhesive comprising the latex composition of claim 1 wherein the core-shell polymer has a Tg of -70 to 50°

C. and an effective tackifying amount of a tackifer.

13. The contact adhesive of claim 12 wherein the tackifier is rosin or a rosin derivative.

14. The contact adhesive of claim 12 wherein the core-shell polymer has a Tg of -40 to 20°

C. and a solids content of at least 40% by weight.

15. The contact adhesive of claim 14 wherein the epoxy resin is a water insoluble aromatic polyepoxide and the amino containing organic compound is a polyamine.

16. The contact adhesive of claim 15 wherein from about 10 to 150 parts by weight of the tackifier is used per hundred parts by weight of the core-shell polymer.

17. The contact adhesive of claim 16 wherein the tackifier is rosin or a rosin derivative.

18. The contact adhesive of claim 17 wherein the core comprises a polyepoxide which is a glycidyl ether of bisphenol A, vinyl acetate and butyl acrylate.