Golf ball forming compositions comprising polyamide

• US 5,981,654 A
• Filed: 05/23/1997
• Issued: 11/09/1999
• Est. Priority Date: 05/23/1997
• Status: Expired due to Term

• Current Assignee: Acushnet Company (FILA Holdings Corp.)
• Original Assignee: Acushnet Company (FILA Holdings Corp.)
• Inventors: Rajagopalan, Murali
• Primary Examiner(s): BUTTNER, DAVID J
• Application Number:
  US08/862,831
• Time in Patent Office: 900 Days
• Field of Search: 473/371, 473/377, 473/378, 525/425, 525/66, 525/433
• US Class Current: 525/66
• CPC Class Codes: A63B 37/0003 Golf balls
• CPC Class Codes: A63B 37/0024 Materials other than ionomers or polyurethane
• CPC Class Codes: A63B 37/0037 Flexural modulus; Bending stiffness
• CPC Class Codes: A63B 37/0039 characterised by the material
• CPC Class Codes: A63B 37/0069 Flexural modulus; Bending stiffness

Abstract

The present invention relates to a golf ball, comprising a cover, a core and optional intermediate layers, wherein the various ball components are formed from compositions comprising a polyamide, in the form of a homopolymer, a copolymer or mixtures thereof. The compositions include a substantially optical brightener-free blend of about 1 wt. % to about 99 wt. % of at least one nonionomer polymer and about 99 wt. % to about 1 wt. % of at least one polyamide polymer. The polyamides of the present invention comprise polyamides and polyamide copolymers, such as nylons, nylon copolymers and nylon block copolymers. The nonionomer polymer comprises a nonionomer thermoplastic elastomer or a nonionomer thermoplastic. The present invention also relates to a golf ball comprising a cover layer, a core and at least one intermediate layer interposed between the cover layer and the core, wherein one of said layers comprises a substantially optical brightener-free composition comprising from about 1 wt. % to about 99 wt. % of at least one nonionomer polymer and about 99 wt. % to about 1 wt. % of at least one polyamide polymer, and wherein an other one of said layers comprises a thermoset polymer. The present invention is further directed to a method of making a golf ball core, an intermediate layer or a cover composition, comprising blending one or more nonionomer polymers and one or more polyamides or polyamide copolymers such that there is mixing of the different polymeric components to give a blend suitable for forming into the above golf ball components.

Claims

1. A golf ball consisting of a single layer cover and a single layer core, wherein the cover comprises a polymer composition, which composition consists essentially of a blend of from about 25 wt. % to about 55 wt. % of at least one nonionomer polymer and from about 75 wt. % to about 45 wt. % of at least one polyamide polymer, wherein said blend is formed by melting and blending the polymers, wherein said composition is substantially free of optical brightener, and wherein said nonionomer polymer is at least one polymer selected from the group consisting of a block copoly(ester-ester), a block copoly(ester-ether), a block copoly(urethane-ether) a block polystyrene thermoplastic elastomer comprising an unsaturated rubber, a block polystyrene thermoplastic elastomer comprising an unsaturated rubber that is functionalized by grafting with maleic anhydride, a block polystyrene thermoplastic elastomer comprising an unsaturated rubber that is functionalized by hydroxy termination, a block polystyrene thermoplastic elastomer comprising a functionalized substantially saturated rubber, a block polystyrene thermoplastic elastomer comprising a functionalized substantially saturated rubber that is functionalized by grafting with maleic anhydride, a block polystyrene thermoplastic elastomer comprising a functionalized substantially saturated rubber that is functionalized by hydroxy termination, a thermoplastic and elastomer blend comprising polypropylene and ethylene-propylene-diene monomer terpolymer or ethylene-propylene copolymer rubber wherein the rubber is dynamically vulcanized, polyethylene polypropylene, a copolymer of ethylene or propylene with acrylic acid or methalkylic acid, a polymer formed with the use of metallocene catalysts and consisting essentially of a copolymer of ethylene and butene, a copolymer of ethylene and hexene or a copolymer of ethylene and octene, a terpolymer formed with the use of metallocene catalysts and consisting essentially of a polymer of ethylene, propylene and a diene monomer, poly(methyl acrylate), poly(methyl methacrylate), acrylonitrile-styrene-butadiene terpolymer, a copolymer comprising an alkyl acrylate or an alkyl alkylacrylate, wherein each alkyl group ranges, independently, from methyl to decyl inclusive and may be linear or branched, a terpolymer consisting essentially of an α

-olefin monomer containing from 2 to 10 carbon atoms, an alkyl acrylate or an alkyl alkylacrylate monomer, and a glycidyl acrylate or a glycidyl alkylacrylate monomer, wherein each alkyl group ranges, independently, from methyl to decyl inclusive and may be linear or branched, a copolymer consisting essentially of an α

-olefin monomer containing from 2 to 10 carbon atoms and a vinyloxazoline or 1-alkyl vinyloxazoline monomer, wherein the alkyl group ranges from methyl to decyl inclusive and may be linear or branched, a terpolymer consisting essentially of an α

-olefin monomer containing from 2 to 10 carbon atoms, an alkyl acrylate or an alkyl alkylacrylate monomer, and a vinyloxazoline or 1-alkyl vinyloxazoline monomer, wherein each alkyl group ranges, independently, from methyl to decyl inclusive and may be linear or branched, a copolymer consisting essentially of an α

-olefin monomer containing from 2 to 10 carbon atoms and carbon monoxide, a terpolymer consisting essentially of a first α

-olefin monomer containing from 2 to 10 carbon atoms, a second α

-olefin monomer containing from 2 to 10 carbon atoms, and carbon monoxide, a copolymer consisting essentially of an α

-olefin monomer containing from 2 to 10 carbon atoms and sulfur dioxide, a terpolymer consisting essentially of a first α

-olefin monomer containing from 2 to 10 carbon atoms, a second α

-olefin monomer containing from 2 to 10 carbon atoms, and sulfur dioxide, a copolymer consisting essentially of an α

-olefin monomer containing from 2 to 10 carbon atoms and maleic anhydride, a terpolymer consisting essentially of an α

-olefin monomer containing from 2 to 10 carbon atoms, maleic anhydride, and carbon monoxide;

a terpolymer consisting essentially of an α

-olefin monomer containing from 2 to 10 carbon atoms, maleic anhydride, and sulfur dioxide, and a terpolymer consisting essentially of an α

-olefin monomer containing from 2 to 10 carbon atoms, maleic anhydride, and an alkyl acrylate or an alkyl alkylacrylate monomer, wherein each alkyl group ranges, independently, from methyl to decyl inclusive and may be linear or branched.

2. The golf ball of claim 1, wherein the polyamide polymer is selected from the group consisting of polyamide homopolymers, polyamide copolymers and mixtures thereof;

wherein the polyamide homopolymer is selected from the group consisting of polyamide 6, polyamide 11, polyamide 12, polyamide 4,6, polyamide 6,6, polyamide 6,9, polyamide 6,10, polyamide 6,12 and mixtures thereof; and

wherein the polyamide copolymer is selected from the group consisting of polyamide 6/6,6, polyamide 6,6/6,10, polyamide 6/6,T, polyamide 6/6,6/6,10 and mixtures thereof.

3. The golf ball of claim 1, wherein the nonionomer polymer has a flexural modulus of from about 1,000 psi to about 150,000 psi.

4. The golf ball of claim 1, wherein the nonionomer polymer is selected from the group consisting of block copoly(ester-ester), block copoly(ester-ether), block copoly(amide-ester), block copoly(amide-ether), block copoly(urethane-ether), a block polystyrene thermoplastic elastomer comprising an unsaturated rubber, a block polystyrene thermoplastic elastomer comprising a functionalized substantially saturated rubber, a thermoplastic and elastomer blend comprising polypropylene and ethylene-propylene-diene monomer terpolymer or ethylene-propylene copolymer rubber wherein the rubber is dynamically vulcanized, and mixtures thereof.

5. A method of making a golf ball, comprising:

forming a single layer golf ball core;

preparing a polymeric cover composition, which composition consists essentially of from about 25 wt. % to about 55 wt. % of at least one nonionomer polymer and from about 75 wt. % to about 45 wt. % of at least one polyamide polymer by melting the at least one nonionomer polymer, melting the at least one polyamide polymer and intermixing the melts to form a blend; and

molding the blend around the golf ball core to form the golf ball comprising a single layer cover, wherein said composition is substantially free of optical brightener, and wherein said nonionomer polymer is at least one polymer selected from the group consisting of a block copoly(ester-ester), a block copoly(ester-ether), a block copoly(urethane-ether), a block polystyrene thermoplastic elastomer comprising an unsaturated rubber, a block polystyrene thermoplastic elastomer comprising an unsaturated rubber that is functionalized by grafting with maleic anhydride, a block polystyrene thermoplastic elastomer comprising an unsaturated rubber that is functionalized by hydroxy termination, a block polystyrene thermoplastic elastomer comprising a functionalized substantially saturated rubber, a block polystyrene thermoplastic elastomer comprising a functionalized substantially saturated rubber that is functionalized by grafting with maleic anhydride, a block polystyrene thermoplastic elastomer comprising a functionalized substantially saturated rubber that is functionalized by hydroxy termination, a thermoplastic and elastomer blend comprising polypropylene and ethylene-propylene-diene monomer terpolymer or ethylene-propylene copolymer rubber wherein the rubber is dynamically vulcanized, polyethylene, polypropylene a copolymer of ethylene or propylene with acrylic acid or methacrylic acid, a polymer formed with the use of metallocene catalysts and consisting essentially of a copolymer of ethylene and butene, a copolymer of ethylene and hexene or a copolymer of ethylene and octene, a terpolymer formed with the use of metallocene catalysts and consisting essentially of a polymer of ethylene, propylene and a diene monomer, poly(methyl acrylate), poly(methyl methacrylate), acrylonitrile-styrene-butadiene terpolymer, a copolymer comprising an alkyl acrylate or an alkyl alkylacrylate, wherein each alkyl group ranges, independently, from methyl to decyl inclusive and may be linear or branched a terpolymer consisting essentially of an α

-olefin monomer containing from 2 to 10 carbon atoms, an alkyl acrylate or an alkyl alkylacrylate monomer and a glycidyl acrylate or a glycidyl alkylacrylate monomer, wherein each alkyl group ranges, independently, from methyl to decyl inclusive and may be linear or branched, a copolymer consisting essentially of an α

-olefin monomer containing from 2 to 10 carbon atoms and a vinyloxazoline or 1-alkyl vinyloxazoline monomer, wherein the alkyl group ranges from methyl to decyl inclusive and may be linear or branched, a terpolymer consisting essentially of an α

-olefin monomer containing from 2 to 10 carbon atoms, an alkyl acrylate or an alkyl alkylacrylate monomer, and a vinyloxazoline or 1-alkyl vinyloxazoline monomer, wherein each alkyl group ranges, independently, from methyl to decyl inclusive and may be linear or branched, a copolymer consisting essentially of an α

-olefin monomer containing from 2 to 10 carbon atoms and carbon monoxide, a terpolymer consisting essentially of a first α

-olefin monomer containing from 2 to 10 carbon atoms, a second α

-olefin monomer containing from 2 to 10 carbon atoms, and carbon monoxide, a copolymer consisting essentially of an α

-olefin monomer containing from 2 to 10 carbon atoms and sulfur dioxide, a terpolymer consisting essentially of a first α

-olefin monomer containing from 2 to 10 carbon atoms, a second α

-olefin monomer containing from 2 to 10 carbon atoms, and sulfur dioxide, a copolymer consisting essentially of an α

-olefin monomer containing from 2 to 10 carbon atoms and maleic anhydride, a terpolymer consisting essentially of an α

-olefin monomer containing from 2 to 10 carbon atoms, maleic anhydride, and carbon monoxide;

a terpolymer consisting essentially of an α

-olefin monomer containing from 2 to 10 carbon atoms, maleic anhydride, and sulfur dioxide, and a terpolymer consisting essentially of an α

-olefin monomer containing from 2 to 10 carbon atoms, maleic anhydride, and an alkyl acrylate or an alkyl alkylacrylate monomer, wherein each alkyl group ranges, independently, from methyl to decyl inclusive and may be linear or branched.

6. A golf ball comprising a cover and a core, wherein the cover is formed of a polymeric composition which comprises a blend of from about 1 wt. % to about 99 wt. % of at least one nonionomer polymer and from about 99 wt. % to about 1 wt. % of at least one polyamide polymer, wherein the nonionomer polymer comprises a copoly(ester-ether), the polyamide polymer comprises polyamide 12, the core comprises polybutadiene, and wherein said composition is substantially free of optical brightener.

7. The golf ball of claim 6, wherein the composition comprises a blend of from about 15 wt. % to about 75 wt. % of at least one nonionomer polymer and from about 85 wt. % to about 25 wt. % of at least one polyamide polymer.

8. A golf ball consisting of a single layer cover and a single layer core, wherein the cover comprises a polymer composition, which composition consists essentially of a blend of from about 1 wt. % to about 99 wt. % of at least one nonionomer polymer and from about 99 wt. % to about 1 wt. % of at least one polyamide polymer, wherein said composition is substantially free of optical brightener, wherein said blend is formed by melting and blending the polymers, and wherein the nonionomer polymer is selected from the group consisting of block copoly(ester-ester), block copoly(ester-ether), block copoly(urethane-ether), a block polystyrene thermoplastic elastomer comprising an unsaturated rubber, a block polystyrene thermoplastic elastomer comprising a functionalized substantially saturated rubber, a thermoplastic and elastomer blend comprising polypropylene and ethylene-propylene-diene monomer terpolymer or ethylene-propylene copolymer rubber wherein the rubber is dynamically vulcanized, and mixtures thereof.

9. The golf ball of claim 8, wherein the polyamide polymer is selected from the group consisting of polyamide homopolymers, polyamide copolymers and mixtures thereof;

wherein the polyamide homopolymer is selected from the group consisting of polyamide 6, polyamide 11, polyamide 12, polyamide 4,6, polyamide 6,6, polyamide 6,9, polyamide 6,10, polyamide 6,12 and mixtures thereof; and

wherein the polyamide copolymer is selected from the group consisting of polyamide 6/6,6, polyamide 6,6/6,10, polyamide 6/6,T, polyamide 6/6,6/6,10 and mixtures thereof.

10. The golf ball of claim 8, wherein the nonionomer polymer has a flexural modulus of from about 1,000 psi to about 150,000 psi.

11. A method of making a golf ball, comprising:

forming a single layer golf ball core;

preparing a polymeric cover composition consisting essentially of from about 1 wt. % to about 99 wt. % of at least one nonionomer polymer selected from the group consisting of block copoly(ester-ester), block copoly(ester-ether), block copoly(urethane-ether), a block polystyrene thermoplastic elastomer comprising an unsaturated rubber, a block polystyrene thermoplastic elastomer comprising a functionalized substantially saturated rubber, a thermoplastic and elastomer blend comprising polypropylene and ethylene-propylene-diene monomer terpolymer or ethylene-propylene copolymer rubber wherein the rubber is dynamically vulcanized, and mixtures thereof and from about 99 wt. % to about 1 wt. % of at least one polyamide polymer by melting the at least one nonionomer polymer, melting the at least one polyamide polymer and intermixing the melts to form a blend; and

molding the blend around the golf ball core to form the golf ball comprising a single layer cover, wherein said composition is substantially free of optical brightener.