Hydrocarbon gas processing

• US 5,983,664 A
• Filed: 04/03/1998
• Issued: 11/16/1999
• Est. Priority Date: 04/09/1997
• Status: Expired due to Term

• Current Assignee: UOP Llc (Honeywell International Inc.)
• Original Assignee: Elcor Corporation
• Inventors: Hudson, Hank M., Wilkinson, John D., Pierce, Michael C., Campbell, deceased, Roy E.
• Primary Examiner(s): Kilner, Christopher B.
• Application Number:
  US09/054,802
• Time in Patent Office: 592 Days
• Field of Search: 62/621, 62/935
• US Class Current: 62/621
• CPC Class Codes: F25J 2200/02 in a single pressure main column system
• CPC Class Codes: F25J 2200/50 using multiple (re-)boiler-condensers at different heights of the column
• CPC Class Codes: F25J 2200/70 Refluxing the column with a condensed part of the feed stream, i.e. fractionator top is stripped or self-rectified
• CPC Class Codes: F25J 2200/76 Refluxing the column with condensed overhead gas being cycled in a quasi-closed loop refrigeration cycle
• CPC Class Codes: F25J 2205/04 in the feed line, i.e. upstream of the fractionation step
• CPC Class Codes: F25J 2210/12 Refinery or petrochemical off-gas
• CPC Class Codes: F25J 2235/60 the fluid being (a mixture of) hydrocarbons
• CPC Class Codes: F25J 2240/02 Expansion of a process fluid in a work-extracting turbine (i.e. isentropic expansion), e.g. of the feed stream
• CPC Class Codes: F25J 3/0209 Natural gas or substitute natural gas
• CPC Class Codes: F25J 3/0219 Refinery gas, cracking gas, coke oven gas, gaseous mixtures containing aliphatic unsaturated CnHm or gaseous mixtures of undefined nature
• CPC Class Codes: F25J 3/0233 separation of CnHm with 1 carbon atom or more
• CPC Class Codes: F25J 3/0238 separation of CnHm with 2 carbon atoms or more

Abstract

A process for the recovery of ethane, ethylene, propane, propylene and heavier hydrocarbon components from a hydrocarbon gas stream is disclosed. In recent years, the preferred method of separating a hydrocarbon gas stream generally includes supplying at least a portion of the gas stream to a work expansion device, then directing the work expanded stream to a distillation column at a mid-column feed point below an upper rectification section. The top column feed above the upper rectification section is typically a condensed and subcooled gaseous stream, frequently comprised of a gas stream that would otherwise feed the work expansion device. In the process disclosed, the work expanded stream is further cooled prior to feeding the distillation column at the mid-column feed point, so that a lesser volume of top column feed is required to maintain the column overhead temperature at a temperature whereby the major portion of the desired components is recovered.

Claims

1. In a process for the separation of a gas stream containing methane, C₂ components, C₃ components and heavier hydrocarbon components into a volatile residue gas fraction containing a major portion of said methane and a relatively less volatile fraction containing a major portion of said C₂ components, C₃ components and heavier hydrocarbon components, in which process

(a) said gas stream is treated in one or more heat exchange steps and at least one division step to produce at least a first stream that has been cooled under pressure to condense substantially all of it, and at least a second stream that has been cooled under pressure;

(b) said substantially condensed first stream is expanded to a lower pressure whereby it is further cooled, and thereafter supplied to a fractionation tower at a top feed point;

(c) said cooled second stream is expanded to said lower pressure, and thereafter supplied to said fractionation tower at a mid-column feed point; and

(d) said cooled expanded first stream and said expanded second stream are fractionated at said lower pressure whereby the components of said relatively less volatile fraction are recovered;

the improvement wherein

(1) at least a portion of said expanded second stream is further cooled before being supplied to said fractionation tower at said mid-column feed point; and

(2) the quantities and temperatures of said feed streams to said fractionation tower are effective to maintain the overhead temperature of said fractionation tower at a temperature whereby the major portions of the components in said relatively less volatile fraction are recovered.

3. The improvement according to claims 1 or 2 wherein at least a portion of said volatile residue gas fraction is directed in heat exchange relation with at least a portion of said expanded second stream to supply said further cooling thereto.

4. The improvement according to claims 1 or 2 wherein a liquid distillation stream is withdrawn from said fractionation tower in substantially the same region of said fractionation tower as said mid-column feed point of said further cooled second stream, whereupon said liquid distillation stream is directed in heat exchange relation with at least a portion of said expanded second stream to supply said further cooling thereto.

5. The improvement according to claims 1 or 2 wherein

(a) at least a portion of said volatile residue gas fraction is directed in heat exchange relation with at least a portion of said expanded second stream to supply said further cooling thereto;

and

(b) a liquid distillation stream is withdrawn from said fractionation tower in substantially the same region of said fractionation tower as said mid-column feed point of said further cooled second stream, whereupon said liquid distillation stream is directed in heat exchange relation with at least a portion of said expanded second stream to supply said further cooling thereto.

6. The improvement according to claims 1 or 2 wherein said further cooling of at least a portion of said expanded second stream is accomplished within said fractionation tower by withdrawing a liquid distillation stream from said fractionation tower at a location above said mid-column feed point of said further cooled second stream, whereupon said liquid distillation stream is subcooled and thereafter supplied to said fractionation tower at an upper mid-column feed point above its withdrawal location.

7. The improvement according to claim 6 wherein at least a portion of said volatile residue gas fraction is directed in heat exchange relation with said liquid distillation stream to supply said cooling thereto.

2. In a process for the separation of a gas stream containing methane, C₂ components, C₃ components and heavier hydrocarbon components into a volatile residue gas fraction containing a major portion of said methane and a relatively less volatile fraction containing a major portion of said C₂ components, C₃ components and heavier hydrocarbon components, in which process

(a) said volatile residue gas fraction is re-compressed and a portion is withdrawn to form a compressed first stream;

(b) said compressed first stream is cooled under pressure to condense substantially all of it;

(c) said substantially condensed first stream is expanded to a lower pressure whereby it is further cooled, and thereafter supplied to a fractionation tower at a top feed point;

(d) said gas stream is treated in one or more heat exchange steps to produce at least a second stream that has been cooled under pressure;

(e) said cooled second stream is expanded to said lower pressure, and thereafter supplied to said fractionation tower at a mid-column feed point; and

(f) said cooled expanded first stream and said expanded second stream are fractionated at said lower pressure whereby the components of said relatively less volatile fraction are recovered;

the improvement wherein

(1) at least a portion of said expanded second stream is further cooled before being supplied to said fractionation tower at said mid-column feed point; and

(2) the quantities and temperatures of said feed streams to said fractionation tower are effective to maintain the overhead temperature of said fractionation tower at a temperature whereby the major portions of the components in said relatively less volatile fraction are recovered.