Self-regulating heat pack

• US 5,984,953 A
• Filed: 05/21/1998
• Issued: 11/16/1999
• Est. Priority Date: 05/21/1998
• Status: Expired due to Fees

• Current Assignee: Tempra Technology, Inc.
• Original Assignee: Tempra Technology, Inc.
• Inventors: Sabin, Cullen M., Sabin, Martin W.
• Primary Examiner(s): Cohen, Lee
• Assistant Examiner(s): ROLLINS, ROSILAND STACIE
• Application Number:
  US09/083,005
• Time in Patent Office: 544 Days
• Field of Search: 607/108, 607/109, 607/110, 607/111, 607/114, 62/530, 62/4
• US Class Current: 607/114
• CPC Class Codes: A47J 36/28 Warming devices generating the heat by exothermic reactions, e.g. heat released by the contact of unslaked lime with water
• CPC Class Codes: A61F 2007/0276 with separate compartments connectable by rupturing a wall or membrane
• CPC Class Codes: A61F 2007/0292 using latent heat produced or absorbed during phase change of materials, e.g. of super-cooled solutions
• CPC Class Codes: A61F 7/03 thermophore, i.e. self-heating, e.g. using a chemical reaction
• CPC Class Codes: B65D 81/3484 Packages having self-contained heating means, e.g. heating generated by the reaction of two chemicals warming devices A47J36/24
• CPC Class Codes: C09K 5/18 Non-reversible chemical reactions
• CPC Class Codes: F24V 30/00 Apparatus or devices using heat produced by exothermal chemical reactions other than combustion
• CPC Class Codes: F28D 20/02 using latent heat
• CPC Class Codes: Y02E 60/14 Thermal energy storage

Abstract

The invention relates to a self-heating, disposable heating pack utilizing an exothermic chemical reaction. Self-moderation of the heat pack is provided through the use of a preformed reversibly stiffenable gel that alters the rate of exothermic chemical reactions. A vaporizable solvent is used to adjust the gel stiffness. The heat pack can be used in heat transfer or ambient temperature conditions which differ from those anticipated as design conditions.

Claims

1. A disposable heating device comprising:

a disposable container having at least one liquid-impermeable first zone and at least one liquid-impermeable second zone;

a separator disposed between the at least one first zone and the at least one second zone, the separator being operable to provide communication between said zones;

a mixture comprising a primary fuel, a preformed stiffenable gel, and a vaporizable solvent in the at least one second zone; and

a substantially solid and particulate oxidizing agent in the at least one first zone, said oxidizing agent being embedded and dispersed throughout solid pieces of a binding agent dissolvable in at least one of said solvent and said primary fuel,

wherein communication between the first and second zones allows mixing of the contents therein and at ambient temperature initiates a primary exothermic chemical reaction producing heat in said container,

wherein the dissolvable binding agent dissolves during said exothermic chemical reaction to controllably expose said particulate oxidizing agent at a predetermined rate,

wherein the container includes a vapor space and a condensation surface above the contents of the zones after communication between the zones is provided,

wherein the vaporizable solvent vaporizes into the vapor space and condenses on the condensation surface when the temperature of the device approaches a predetermined maximum temperature during operation of the device, causing stiffening of the gel, and

wherein the amount of said preformed stiffenable gel is sufficient to prevent said exothermic chemical reaction from causing the temperature of the container to overshoot the predetermined maximum temperature during operation of the device.

2. The heating device of claim 1, wherein the container comprises a thin-walled envelope that conforms to the shape of its surroundings.

3. The heating device of claim 2, wherein the container comprises a polymeric material.

4. The heating device of claim 1, wherein the oxidizing agent comprises an alkali metal salt of permanganate.

5. The heating device of claim 1, wherein the vaporizable solvent is water and said primary exothermic chemical reaction occurs in an aqueous environment.

6. The heating device of claim 1, further comprising a temperature stabilizing means in at least one of the zones.

7. The heating device of claim 6, wherein the temperature stabilizing means comprises a phase change material.

8. The heating device of claim 1, wherein the preformed stiffenable gel comprises an organic material.

9. The heating device of claim 8, wherein the organic material is starch.

10. The heating device of claim 1, wherein the primary fuel comprises glycerin.

11. The heating device of claim 1, further comprising a plurality of zones of the first type and a plurality of zones of the second type.

12. The heating device of claim 1, wherein the separator is a single-use, frangible membrane.

13. The heating device of claim 1, wherein the exothermic chemical reaction is a reduction-oxidation reaction.

14. The heating device of claim 1, further comprising a secondary fuel in the at least one first zone, wherein the secondary fuel is soluble in the solvent, and wherein the primary exothermic chemical reaction heats the device to a temperature which initiates a secondary exothermic chemical reaction.

15. The heating device of claim 14, wherein the secondary fuel is substantially solid and particulate.

16. The heating device of claim 14, wherein the container comprises a thin-walled envelope that conforms to the shape of its surroundings.

17. The heating device of claim 16, wherein the container comprises a polymeric material.

18. The heating device of claim 14, wherein the oxidizing agent comprises an alkali metal salt of permanganate.

19. The heating device of claim 14, wherein the binding agent is sodium silicate.

20. The heating device of claim 14, wherein the vaporizable solvent is water and said primary and secondary exothermic chemical reactions occur in water.

21. The heating device of claim 14, further comprising a temperature stabilizing means in at least one of the zones.

22. The heating device of claim 21, wherein the temperature stabilizing means comprises a phase change material.

23. The heating device of claim 14, wherein the preformed stiffenable gel comprises an organic material.

24. The heating device of claim 23, wherein the organic material is starch.

25. The heating device of claim 14, wherein the primary fuel comprises a polyhydroxy compound and the secondary fuel comprises a polyhydroxy compound.

26. The heating device of claim 25, wherein the primary fuel comprises glycerine.

27. The heating device of claim 25, wherein the secondary fuel comprises a sugar.

28. A method of heating objects, comprising the steps of:

a) providing the disposable heating device of claim 1;

b) contacting said device with an object to be heated;

c) compromising the separator to permit contact between the zones; and

d) mixing the contents of the first and second zones together to insure contact of their contents thereby initiating an exothermic chemical reaction.

29. The method of claim 28, wherein steps c) and d) are performed before performance of step b).

30. The method of claim 28, wherein the object to be heated is a container containing food or drink.

31. The method of claim 28, wherein the object to be heated is a part of the body of a human or animal.

32. The method of claim 31, wherein the human or animal is a medical patient.

33. The method of claim 28, wherein the object to be heated is an article of clothing or footwear.

34. A disposable heating device comprising:

a disposable container having at least one liquid-impermeable first zone and at least one liquid-impermeable second zone;

a separator disposed between the at least one first zone and the at least one second zone, the separator being operable to provide communication between the zones,

a mixture comprising glycerine, a preformed stiffenable starch gel and water in the at least one second zone; and

particles of potassium permanganate and sugar in the at least one first zone, said particles of potassium permanganate being embedded in and dispersed throughout solid pieces of sodium silicate,

wherein communication between the first and second zones allows mixing of the contents therein and initiates an exothermic reduction/oxidation reaction, producing heat in said container,

wherein the solid pieces of sodium silicate dissolves during said exothermic reaction to controllably expose said particles of potassium permanganate at a predetermined rate,

wherein the container includes a vapor space and a condensation surface above the contents of the zones after communication between the zones is provided,

wherein the water vaporizes into the vapor space and condenses on the condensation surface when the temperature of the device approaches a predetermined maximum temperature during operation of the device, causing stiffening of the starch gel, and

and wherein the amount of said preformed stiffenable starch gel is sufficient to prevent said exothermic chemical reaction from causing the temperature of the container to overshoot the predetermined maximum temperature during operation of the device.

35. The heating device of claim 34, wherein the separator comprises a single-use frangible membrane.