Pourous fluorocarbon membrane, method for producing thereof and cartridge filter based on said membrane

• US 5,988,400 A
• Filed: 06/20/1997
• Issued: 11/23/1999
• Est. Priority Date: 10/23/1995
• Status: Expired due to Fees

• Current Assignee: Zao Stc "Valdipor"
• Original Assignee: Aktsionernoe Obschestvo "Polimersintez"
• Inventors: Amelina, Natalia Vladimirovna, Karachevtcev, Vyacheslav Grigorievich, Dubjaga, Vladimir Pavlovich, Tarasov, Aleksandr Valentinovich
• Primary Examiner(s): Kim, John
• Application Number:
  US08/860,065
• Time in Patent Office: 886 Days
• Field of Search: 210/483, 210/484, 210/488, 210/489, 210/490, 210/493.1, 210/493.2, 210/321.77, 210/493.4, 210/321.86, 210/493.5, 210/498, 210/496, 210/500.36 , 210/500.42, 264/41, 264/136, 264/241
• US Class Current: 210/483
• CPC Class Codes: B01D 39/1692 Other shaped material, e.g. perforated or porous sheets
• CPC Class Codes: B01D 63/067 with pleated membranes
• CPC Class Codes: B01D 69/12 Composite membranes; Ultra-thin membranes
• CPC Class Codes: B01D 71/32 containing fluorine atoms
• CPC Class Codes: B01D 71/34 Polyvinylidene fluoride
• CPC Class Codes: B01D 71/36 Polytetrafluoroethene
• CPC Class Codes: B01D 71/76 Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74 rubbers in general B01D71/24

Abstract

A porous fluorocarbon membrane has a porous support completely impregnated with tetrafluoroethylene/vinylidene fluoride copolymer. There is a process for producing this membrane by impregnating a porous support with a copolymer solution in a readily-boiling solvent and a precipitating mixture of alcohol and water followed by curing for partial hardening of the solution and subsequent drying at elevated temperature. A cartridge filter includes protective and supporting cylindrical perforated hollow housings, containing a fluorocarbon membrane or two superimposed flourocarbon membranes. Membranes and a cartridge filter find extensive use in separation of gases and aggressive media.

Claims

1. A porous fluorocarbon membrane comprising

a porous support and a layer of fluorocarbon polymer connected to said porous support, said porous support having an average pore size ranging from 5.0 to 500.0 microns and difference by specific weight in any two points of a sample having various sizes of not more than 7%;

said porous support is completely impregnated with a copolymer solution soluble in organic solvent wherein the copolymer is consisting of 23-25 weight percent tetrafluoroethylene and 75-77 weight percent vinylidene fluoride,

the ratio of viscosity of the copolymer solution in acetone, with copolymer content in the solution in the amount of 0.01 g/cm³, to acetone equal to 2.0-4.0.

2. A porous fluorocarbon membrane of claim 1,

wherein said membrane contains, as fluorocarbon polymer, the mixture of polymers comprised of at least 85.0 weight percent tetrafluoroethylene/vinylidene fluoride copolymer and fluorocarbon polymer selected from the group consisting of polyvinylidene fluoride, vinylidene fluoride/trifluorochloroethylene copolymer and hexafluoropropylene/vinylidene fluoride copolymer.

3. A method for producing a porous fluorocarbon membrane by dissolving tetrafluoroethylene/vinylidene fluoride copolymer in an organic readily-boiling solvent, mixing the resultant copolymer solution with a precipitating mixture to produce a casting solution, forming said casting solution into a membrane on a continuously moving carrying surface and drying the resulting continuously moving membrane at elevated temperature, wherein porous material having the average pore size within the range of 5.0-500.0 microns and difference by specific weight in any two points of a sample having various sizes of not more than 7% is used as a carrying surface;

formation is performed by the complete impregnation of porous material moving at a constant speed with heated casting solution of a copolymer comprising 23-25 tetrafluoroethylene and 75-77 weight percent vinylidene fluoride and having the ratio of viscosity of the copolymer solution in acetone, with copolymer content in the solution in the amount of 0.01 g/cm³, to acetone equal to 2.0-4.0;

short-term storage of continuously moving porous material while applying the casting solution under the conditions of free evaporation of a portion of solvent for partial hardening of the casting solution and consequent drying of continuously moving porous material is effected in at least three successive drying zones wherein temperature, increasing from one zone to another, is maintained.

4. A method of claim 3, comprising using a ketone as a solvent for tetrafluoroethylene/vinylidene fluoride copolymer.

5. A method of claim 4, comprising using acetone as ketone in the amount of 60-70 weight percent of said casting solution comprising from 7.0 to 12.0 weight percent of tetrafluoroethylene/vinylidene fluoride copolymer or mixture thereof with other fluorocarbon polymers.

6. A method of claim 3, comprising

using a mixture of alcohol and deionized water as a precipitating mixture.

7. A method of claim 3, wherein the alcohol is propyl alcohol or isopropyl alcohol in the amount of at least 14.0 weight percent of said casting solution containing at least 5.0 weight percent of deionized water.

8. A method of claim 3, comprising

effecting dissolution of tetrafluoroethylene/vinylidene fluoride copolymer at the temperatures ranging from 30°

C. to 50°

C.

9. A method of claim 3, comprising,

in the course of mixing a copolymer solution with a precipitating mixture maintaining a difference in temperatures thereof at 3°

C. max.

10. A method of claim 3, comprising

carrying out impregnation of porous material with said casting solution by means of the application and sizing rollers rotating at various speed and partly submerged into said casting solution, and

applying said solution onto the porous support moving at a constant speed within the range of 1.0-10.0 m/min.

11. A method of claim 3, comprising applying a casting solution onto said porous support in the amount of 10.0-50.0 g of copolymer per 1 m² of said support.

12. A method of claim 3, comprising maintaining temperature of a casting solution applied onto said porous support within the range of 25°

C.-45°

C.

13. A method of claim 3, comprising

performing short-storage for partial hardening of casting solution at 18°

C.-25°

C. for about 0.5-1.0 min.

14. A method of claim 3, comprising

maintaining temperatures within the drying zones within the following ranges:

first zone--ranging from 45°

C. to 55°

C.

second zone--from 55°

C. to 65°

C.

third zone--from 90°

C. to 100°

C.

and absolute humidity in each drying zone is maintained at the level of not more than 5.0 g/m³.

15. A cartridge filter comprising

protective and supporting cylindrical perforated hollow housings, a pleated porous membrane provided with a prefiltration device and a drainage placed between said housings and tightly connected to the cases of end caps, at least one said end caps having a central drain duct,

said cartridge filter further comprises a membrane consisting of a porous support having an average pore size within the range of 5.0-500.0 microns and the difference by specific weight in any two points of a sample having various sizes of 7.0% max., which porous support is completely impregnated with a copolymer solution soluble in organic solvent wherein the copolymer solution containing 23-25% by weight tetrafluoroethylene and 75-77% by weight vinylidene fluoride and having the ratio of viscosity of the solution thereof in acetone, with copolymer content in solution in the amount of 0.01 g/cm³ to acetone equal to 2.0 to 4.0.

16. A cartridge filter of claim 15, wherein said filter comprises two porous fluorocarbon membranes superimposed so that the one closer to the prefiltration device has the pore size ranging from 0.25 to 0.65 microns and second membrane has the pore size ranging from 0.15 to 0.45 microns.

17. A cartridge filter of claim 16, wherein said filter comprises two porous membranes superimposed so that active surfaces of said membranes are directed towards the prefiltration device.

18. A cartridge filter of claim 16, wherein said filter comprises two porous membranes superimposed so that surfaces of said membranes are opposite to active surfaces.