Solvent process for recovering indigo dye from textile scrap

• US 5,989,296 A
• Filed: 02/02/1998
• Issued: 11/23/1999
• Est. Priority Date: 02/02/1998
• Status: Expired due to Fees

• Current Assignee: SSI Holdco, Inc.
• Original Assignee: American Renewable Resources, LLC
• Inventors: Hall, David, Patton, Robert T.
• Primary Examiner(s): Einsmann, Margaret
• Assistant Examiner(s): MRUK, BRIAN P
• Application Number:
  US09/017,063
• Time in Patent Office: 659 Days
• Field of Search: 8/440, 8/102, 8/586, 8/614, 8/650, 8/653, 8/918
• US Class Current: 8/440
• CPC Class Codes: C09B 67/0078 Preparations of vat, sulfur or indigo dyes in liquid form
• CPC Class Codes: C09B 67/0096 Purification; Precipitation; Filtration
• CPC Class Codes: D06P 5/137 with other compounds
• CPC Class Codes: Y10S 8/918 Cellulose textile

Abstract

A process for recovering a vat dye from a textile using a heated organic solvent. The textile is contacted with a heated organic solvent in which the dye is soluble until dye is extracted from the textile into the solvent to produce a dye-containing solvent solution. The dye is then recovered from the organic solvent by evaporation of the solvent leaving a dye residue, cooling and precipitation of the dye, or extraction of the dye by contacting the dye-containing solvent solution with an aqueous solution containing a reducing agent for the dye. When dye is extracted from the dye-containing solvent solution by contacting it with an aqueous solution containing a reducing agent, the dye is subsequently insolubilized by oxidation, and the dye is recovered from the aqueous dye solution. This process is particularly advantageous for recovering indigo dye from denim scrap.

Claims

1. A process for recovering a vat dye from a cotton textile using an organic solvent, comprising the steps of

a) contacting the textile with a heated organic solvent in which the dye is soluble until dye is extracted from the textile into the solvent to produce a dye-containing solvent solution;

and

b) precipitating dye from the dye-containing solvent solution by cooling said solvent solution.

2. A process of claim 1 wherein the dye is a mixture of dyes.

3. A process of claim 1 including the further step of

c) recovering dye from the solvent solution.

4. A process of claim 1 wherein the solvent removes fats, waxes or finishing agents from the cotton textile.

5. The process of claim 1, wherein the cotton textile is denim scrap.

6. The process of claim 1, wherein the dye comprises indigo dye.

7. The process of claim 1, wherein the organic solvent has a boiling point within the range of 50°

C. to 150°

C.

8. The process of claim 1, wherein the organic solvent is applied to the cotton textile at such a temperature and pressure so as to prevent boiling of the solvent.

9. The process of claim 1, wherein the dye-containing solvent solution is cooled to a temperature less than 70°

C.

10. The process of claim 3, wherein the organic solvent is water-immiscible and wherein the process of recovering the dye from the solvent solution comprises the steps of

c1) contacting the dye-containing solvent solution with an aqueous solution containing a reducing agent for the dye, wherein said reducing agent is present in said aqueous solution in an amount and at a pH sufficient to reduce and solubilize dye from said solvent solution, whereby the dye is converted to its water-soluble leuco state;

c2) contacting the dye in aqueous solution with an oxidant, whereby the dye is insolubilized and caused to precipitate, producing an aqueous dye suspension; and

c3) removing precipitated dye from said aqueous dye suspension.

11. The process of claim 10, wherein the water-immiscible organic solvent is 1,1,2-trichloroethane.

12. The process of claim 10, wherein the reducing agent is selected from the group consisting of alkali metal hydrosulfites, sulfides, thiosulfates, and oxalates;

thiourea dioxide; and

alkali metal sulfoxylate formaldehyde.

13. The process of claim 10, wherein the oxidant in step c2 is air.

14. The process of claim 10, wherein the dye is recovered by removing water from the suspension through a permeable or semi-permeable membrane.

15. The process of claim 3, wherein the process of recovering the dye from the solvent solution comprises the steps of

c1) removing precipitated dye from the solvent solution by filtering said solvent solution to produce a dye filter cake;

and

c2) vaporizing solvent from said dye filter cake.

16. The process of claim 15, wherein the organic solvent is water-soluble.

17. The process of claim 16, wherein the water-soluble organic solvent is dimethyl formamide.

18. The process of claim 3, wherein the process of recovering the dye from the solvent solution comprises the steps of

c1) vaporizing solvent from said dye-containing solvent solution to concentrate the dye and form a suspension;

and

c2) recovering dye from the concentrated dye solution and suspension.

19. The process of claim 18, wherein the organic solvent is water-soluble.

20. The process of claim 19, wherein the water-soluble organic solvent is dimethyl formamide.

21. The process of claim 1, further including the step of

c) recovering the solvent from the cotton textile.