Process for the removal and recovery of mercury from hydrocarbon streams

• US 5,989,506 A
• Filed: 12/18/1996
• Issued: 11/23/1999
• Est. Priority Date: 12/18/1996
• Status: Expired due to Term

• Current Assignee: UOP Llc (Honeywell International Inc.)
• Original Assignee: UOP Llc (Honeywell International Inc.)
• Inventors: Markovs, John
• Primary Examiner(s): Langel, Wayne
• Assistant Examiner(s): DiMauro, Peter
• Application Number:
  US08/769,027
• Time in Patent Office: 1,070 Days
• Field of Search: 95/134, 423/210, 208/251 R, 210/673, 210/679
• US Class Current: 423/210
• CPC Class Codes: B01D 2253/108 Zeolites
• CPC Class Codes: B01D 2256/24 Hydrocarbons
• CPC Class Codes: B01D 2257/602 Mercury or mercury compounds
• CPC Class Codes: B01D 2259/40088 by heating
• CPC Class Codes: B01D 2259/402 using two beds
• CPC Class Codes: B01D 53/04 with stationary adsorbents B01D53/025 takes precedence
• CPC Class Codes: B01D 53/64 Heavy metals or compounds thereof, e.g. mercury
• CPC Class Codes: C10G 25/05 Removal of non-hydrocarbon compounds, e.g. sulfur compounds
• CPC Class Codes: C10G 53/16 plural parallel stages only

Abstract

The invention relates to a process for removing and recovering mercury, an impurity, from a hydrocarbon feedstream. The process comprises separating the hydrocarbon feedstream into a gaseous portion and a liquid hydrocarbon portion and separately treating the gaseous and liquid portions by adsorption in separate purifier beds. The gas and liquid purifier beds are regenerated sequentially with a heated regenerant stream that following desorption and recovery of mercury is further purified in a secondary regenerable adsorption bed. The sequential regeneration of the two separate purifier beds and the secondary adsorbent bed significantly reduces the capital and operating cost for the process and serves to concentrate the mercury in the secondary adsorbent bed where it can be removed at a lower cost.

Claims

1. A process for recovering and removing mercury from a gaseous stream comprising C₁ -C₃ hydrocarbons water, and mercury and a liquid hydrocarbon stream comprising C₃ + hydrocarbons, water, and mercury, said process comprising the steps of:

a) passing said gaseous stream to a first gas purifier bed of at least two gas purifier beds each of said gas purifier beds being a fixed bed containing a first regenerable adsorbent selective for the adsorption of mercury and water to provide a treated gas effluent having a reduced amount of mercury relative to said gaseous stream and passing said liquid hydrocarbon stream to a first liquid purifier bed of at least two liquid purifier beds each liquid purifier bed being a fixed bed containing a second regenerable adsorbent selective for the adsorption of mercury and water to produce a treated liquid effluent having a reduced amount of mercury relative to said liquid hydrocarbon stream;

b) passing a heated regenerant stream to the first gas purifier bed to regenerate said first gas purifier bed and to produce a first spent regenerant stream and passing the first spent regenerant stream to a common mercury recovery zone to provide a cooled regenerant stream, a water stream and a mercury stream;

c) terminating the passing of the heated regenerant stream to the first gas purifier bed and the passing of the first spent regenerant stream to the common recovery zone and passing the heated regenerant stream to the first liquid purifier bed to sequentially regenerate the first liquid purifier bed and to produce a second spent regenerant stream and passing the second spent regenerant stream to the common mercury recovery zone;

d) terminating the passing of the heated regenerant stream to the first liquid purifier bed and the passing of the second spent regenerant stream to the common recovery zone and passing the cooled regenerant stream to a first secondary adsorption bed of at least two secondary adsorption beds each secondary adsorption bed being a fixed bed containing a third regenerable adsorbent selective for the adsorption of mercury to provide a purified gas stream, terminating the passing of the cooled regenerant stream to the first secondary adsorption bed prior to mercury breakthrough, and passing the heated regenerant stream to the first secondary adsorption bed to sequentially regenerate the first secondary adsorption bed and to provide a third spent regenerant stream and passing the third spent regenerant stream to said common mercury recovery zone; and

,

e) repeating steps (a) to (d) to provide a continuous process.

2. The process of claim 1 wherein said first, second, and third regenerable adsorbents comprise a zeolite molecular sieve containing cationic or finely dispersed elemental forms of a metal selected from the group consisting of silver, gold, platinum, palladium, and mixtures thereof.

3. The process of claim 2 wherein said zeolite molecular sieves are selected from the group consisting of A, X, and Y zeolites.

4. The process of claim 1 wherein the gas purifier beds, the liquid purifier beds and the secondary adsorption beds each contain a first adsorbent zone containing a desiccant and second adsorbent zone containing a zeolite A or zeolite X containing ionic or elemental silver.

5. The process of claim 1 wherein the recovery of mercury in said mercury stream comprises greater than about 80 wt % of the mercury in said feedstream.

11. The process of claim 1 further comprising heating at least a portion of the purified stream to provide said heated regenerant stream.

12. The process of claim 1 wherein the purified gas comprises less than about 0.1 μ

g/Nm³ mercury.

6. A process for recovering and removing mercury from a hydrocarbon feedstream comprising C₁ -C₁₀ hydrocarbons, water, and mercury, said process comprising the steps of:

a) separating the hydrocarbon feedstream in a separation zone to provide a gaseous stream comprising C₁ -C₃ hydrocarbons and a liquid hydrocarbon stream comprising C₃ + hydrocarbons, both said gaseous stream and said liquid hydrocarbon stream comprising mercury and water;

b) passing said gaseous stream to a first gas purifier bed of at least two gas purifier beds each of said gas purifier beds being a fixed bed containing a first regenerable adsorbent selective for the adsorption of mercury and water to provide a treated gas effluent having a reduced amount of mercury relative to said gaseous stream and passing said liquid hydrocarbon stream to a first liquid purifier bed of at least two liquid purifier beds each liquid purifier bed being a fixed bed containing a second regenerable adsorbent selective for the adsorption of mercury and water to produce a treated liquid effluent having a reduced amount of mercury relative to said liquid hydrocarbon stream;

c) terminating prior to mercury breakthrough the passing of said gaseous stream to said first gas purifier bed and terminating prior to mercury breakthrough the passing of said liquid hydrocarbon stream to said first liquid purifier bed;

d) passing a heated regenerant stream to said first gas purifier bed to desorb mercury and provide a first spent regenerant stream and passing said first spent regenerant stream to a condenser/separator to provide a cooled regenerant stream, a water stream, and a mercury stream;

e) passing said cooled regenerant stream to a first secondary adsorption bed of at least two secondary adsorption beds each of said secondary adsorption beds containing a third regenerable adsorbent selective for the adsorption of mercury to produce a purified gas stream containing less than about 0.1 μ

g/Nm³ of mercury;

f) terminating the passing of said heated regenerant stream to said first gas purifier bed, terminating the passing of the first spent regenerant stream to the cooler/condenser, and passing said heated regenerant stream to said first liquid purifier bed to regenerate said first liquid purifier bed and withdrawing a second spent regenerant stream and passing the second spent regenerant stream to the cooler/condenser;

g) terminating the passing of said heated regenerant stream to said first liquid purifier bed, terminating the passing of the second spent regenerant stream to the cooler/condenser, terminating the passing of said cooled regenerant stream to said first secondary adsorption bed prior to mercury breakthrough, passing said heated regenerant stream to said first secondary adsorption bed to regenerate said first secondary adsorption bed and withdrawing a third spent regenerant stream and passing the third spent regenerant stream to the cooler/condenser;

h) terminating the passing of said heated regenerant stream to said first secondary adsorption bed, terminating the passing of the third spent regenerant stream to the cooler/condenser and heating at least a portion of the purified gas stream to provide a portion of said heated regenerant stream;

i) repeating steps (b) through (h) to provide a continuous process.

7. The process if claim 6 wherein said cooled regenerant stream comprises a temperature from about 20°

to about 45°

C.

8. The process if claim 6 wherein said cooled regenerant stream comprises a temperature less than about 2°

C.

9. The process of claim 6 wherein the separation zone comprises a single or a multiple zone flash of the hydrocarbon feedstream.

10. The process of claim 9 wherein said separation zone contains a mechanical removal device selected from the group consisting of filtration and centrifugation.