Plasma generation of supported metal catalysts

• US 5,989,648 A
• Filed: 05/06/1998
• Issued: 11/23/1999
• Est. Priority Date: 05/06/1997
• Status: Expired due to Term

• Current Assignee: Penn State Research Foundation
• Original Assignee: Penn State Research Foundation
• Inventors: Phillips, Jonathan
• Primary Examiner(s): PIANALTO, BERNARD D
• Application Number:
  US09/072,741
• Time in Patent Office: 566 Days
• Field of Search: 427/456, 427/476, 427/580, 427/217, 427/250, 427/255.19, 427/255.25, 427/255.27, 427/255.395, 427/422, 427/427
• US Class Current: 427/456
• CPC Class Codes: B01J 37/349 making use of flames, plasmas or lasers
• CPC Class Codes: C23C 4/123 Spraying molten metal
• CPC Class Codes: C23C 4/134 Plasma spraying
• CPC Class Codes: Y10S 977/777 Metallic powder or flake

Abstract

The present invention relates to a method of producing catalytic materials which comprises passing an aerosol comprising a mixture of metal powder and support through a plasma torch.

Claims

1. A method of producing catalytic materials which comprises passing an aerosol comprising a mixture of at least one metal powder and at least one support through a plasma torch.

2. The method of claim 1, wherein the metal powder partially atomizes when passing through the plasma torch and coats the support.

3. The method of claim 1, wherein the support is a refractory material.

4. The method of claim 3, wherein the refractory material is selected from the group consisting of silica, alumina, niobia, magnesia, chromia, titania, ceria, lanthanum oxide, praseodymium oxide, high surface area carbides and nitrides and mixtures thereof.

5. The method of claim 1, wherein the metal powder is selected from the group consisting of manganese, iron, nickel, rhenium, cobalt, copper, zinc, ruthenium, rhodium, palladium, gold, silver, lithium, sodium, potassium, rubidium, cesium, magnesium, calcium, strotium, barium, boron, aluminum and mixture thereof.

6. The method of claim 1, wherein the metal powder is present in an amount of 0.01 to 80 wt %.

7. The method of claim 1, wherein the mixture of metal powder and support is a physical mixture of palladium and carbon.

8. The method of claim 1, wherein the support is present in an amount of 20 to 99.99 wt %.

9. The method of claim 1, wherein the aerosol is a gas aerosol wherein the gas is selected from the group consisting of nitrogen, oxygen, fluorine, neon, chlorine, argon, krypton, xenon, hydrogen and mixtures thereof.

10. The method of claim 1, wherein the inert gas is argon.

11. The method of claim 1, wherein the mixture is an inert gas plasma aerosol that is formed by passing inert plasma gas and mixture of at least one metal and at least one support through a microwave generated inert gas plasma.

12. The method of claim 1, wherein the metal is palladium and the support is alumina, silica and/or carbon.

13. The method of claim 1, wherein the size of the metal powder is 0.05 to 500 microns.

14. The method of claim 1, wherein the mixture comprises 0.01 to 80 wt % metal powder and 20 to 99.99 wt % support.

15. The method of claim 1, wherein the plasma torch is operated between 300 to 1000 Watts with less than 40 w/reflected power.

16. The method of claim 1, wherein a first and a second stream is passed through the plasma torch, the first stream comprising aerosol and the second stream comprising plasma gas, wherein the flow rate of the first and second stream is 1 to 5000 standard liters/min.

17. The method of claim 16, wherein the first and the second stream are fed through the center of a microwave applicator of the plasma torch.

18. The method of claim 1, wherein the average residence time of the aerosol in the applicator is 0.001 to 1000 sec.

19. A method of producing catalytic materials which comprises passing (i) a plasma gas and (ii) an aerosol comprising a mixture of 0.01 to 80 wt % of at least one metal powder selected from the group consisting of Pt, Pd, Fe, V, Cr, Mn, Co, Ni, Cu, Zn, Ru, Rh, Ag, Os, Ir, Au and mixtures thereof and 20 to 99.99 wt % support selected from the group consisting of silica, alumina, niobia, magnesia, chromia, titania, ceria, lanthanum oxide, praseodymium oxide, high surface area carbides and nitrides and mixtures thereof, through a plasma torch at a flow rate of 1 to 5000 standard liters/min. and at a power range of 100 to 1000 watts.