Thermally-protective intumescent coating system and method

• US 5,989,706 A
• Filed: 09/30/1998
• Issued: 11/23/1999
• Est. Priority Date: 09/30/1998
• Status: Expired due to Fees

• Current Assignee: Battelle Memorial Institute
• Original Assignee: Battelle Memorial Institute
• Inventors: McGinniss, Vincent D., Rogers, Stephen D., Russell, Robert E. III, Dick, Richard J.
• Primary Examiner(s): DUDASH, DIANA L
• Application Number:
  US09/163,511
• Time in Patent Office: 419 Days
• Field of Search: 427/393.3, 427/408, 427/397.8, 427/228, 427/224, 427/379, 427/386, 427/407.11, 252/601, 252/604, 252/606, 252/607, 106/15.05, 106/18.11, 106/18.13, 106/18.14, 106/18.15, 106/18.16, 106/18.17, 106/18.21, 428/411.1, 428/413, 428/341, 428/322.7
• US Class Current: 428/341
• CPC Class Codes: C09D 5/185 Intumescent paints
• CPC Class Codes: C09K 21/00 Fireproofing materials for use in a particular application, see the relevant places, e.g. fireproofing of wood B27K, of polymers C08, of textiles D06M, of paper D21H; fireproof paints C09D5/18
• CPC Class Codes: Y10T 428/273 of coating
• CPC Class Codes: Y10T 428/31504 Composite [nonstructural laminate]
• CPC Class Codes: Y10T 428/31511 Of epoxy ether

Abstract

An intumescent coating system and method therefor is disclosed for thermally protecting a substrate having a surface exposed to fire conditions. The coating system of the present invention is provided as having a having a first film layer which forms a rigid carbonific char foam having toughness and rigidity, and a second film layer which forms an insulative carbonific char foam having insulation properties. The two foam components may be separately provided in a laminate-type arrangement as, respectively, an inner coating layer coated and cured on the surface of the substrate to form an inner film layer, and an outer coating layer coated and cured on the inner film layer to form an outer film layer. In providing two foam components, one protecting the substrate from breakthrough and direct exposure to the fire conditions, and the other insulating the substrate to protect it from conductive, radiant, and/or convective heating by the fire conditions, the present invention affords a capability to offer flame retardancy at film thicknesses of 1.27 mm (50 mils) or less.

Claims

1. An intumescent coating system for thermally protecting a substrate having a surface exposed to fire conditions comprising:

(a) a first coating layer coated on the surface of said substrate and cured thereon to form a first film layer which layer is thermally decomposable upon exposure to said fire conditions to form a first carbonific char which char intumesces to form a first rigid carbonific char foam; and

(b) a second coating layer coated on said first film layer and cured thereon to form a second film layer which layer is thermally decomposable upon exposure to said fire conditions to form a second carbonific char which char intumesces to form an insulative carbonific char foam; and

wherein said intumescent coating system has a thickness of 1.27 mm (50 mils) or less.

2. The intumescent coating system of claim 1 wherein said insulative carbonific char foam has a density of between about 0.01 g/cm³ and less than about 0.5 g/cm³.

3. The intumescent coating system of claim 1 wherein upon exposure to fire conditions

said rigid carbonific char foam is harder relative to said insulative carbonific char foam.

4. The intumescent coating system of claim 1 wherein, upon exposure to fire conditions, said insulative carbonific char foam comprises a lower density foam exhibiting has a lower thermal conductivity relative to said rigid carbonific char foam.

5. The intumescent coating system of claim 1 further comprising a third coating layer coated on said second film layer and cured thereon to form a third film layer which layer is thermally decomposable upon exposure to said fire conditions to form a third carbonific char which char intumesces to form a second rigid carbonific char foam, said insulative carbonific char foam forming under said second rigid carbonific char foam.

6. The intumescent coating system of claim 1 further comprising a third coating layer formulated as a blend of said first and said second coating layers, said third coating layer being coated on said second film layer and cured thereon to form a third film layer which layer is thermally decomposable upon exposure to said fire conditions to form a third carbonific char which char intumesces to form a carbonific char foam blend, said insulative carbonific char foam forming under said carbonific char foam blend.

15. The intumescent coating system of claim 1 wherein said rigid carbonific char foam has a density of between about 0.5 g/cm³ and less than about 1.0 g/cm³, and said insulative carbonific char foam has a density of between greater than about 0.01 g/cm³ and less than about 0.5 g/cm³.

16. The intumescent coating system of claim 1 further comprising a third coating layer coated on said second film layer and cured thereon to form a third film layer which layer is thermally decomposable upon exposure to said fire conditions to form a third carbonific char which char intumesces to form a second insulative carbonific char foam.

17. The intumescent coating system of claim 5 wherein said first and second rigid carbonific char foams have a density of between about 0.5 g/cm³ and less than about 1.0 g/cm³, and said insulative carbonific char foam has a density of between greater than about 0.01 g/cm³ and less than about 0.5 g/cm³.

7. A method for thermally protecting a substrate having a surface exposed to fire conditions comprising the steps of:

(a) coating said surface of said substrate with a first coating layer;

(b) curing said first coating layer on said surface of said substrate to form a first film layer which layer is thermally decomposable upon exposure to said fire conditions to form a first carbonific char which char intumesces to form a first rigid carbonific char foam;

(c) coating a second coating layer on said first film layer; and

(d) curing said second coating layer on said first coating layer to form a second film layer which layer is thermally decomposable upon exposure to said fire conditions to form a second carbonific char which char intumesces to form an insulative carbonific char foam; and

wherein said first and second film layers comprise an intumescent coating system having a thickness of 1.27 mm (50 mils) or less.

8. The method of claim 7 wherein said insulative carbonific char foam has a density of between about 0.01 g/cm³ and less than about 0.5 g/cm³.

9. The method of claim 7 wherein said rigid carbonific char foam has a density of between about 0.5 g/cm³ and less than about 1.0 g/cm³, and said insulative carbonific char foam has a density of between greater than about 0.01 g/cm³ and less than about 0.5 g/cm³.

10. The method of claim 7 further comprising the steps of:

(e) coating a third coating layer on said second film layer; and

(f) curing said third coating layer on said second coating layer to form a third film layer which layer is thermally decomposable upon exposure to said fire conditions to form a third carbonific char which char intumesces to form a second rigid carbonific char foam, said insulative carbonific char foam forming under said second rigid carbonific char foam.

11. The method of claim 7 further comprising the steps:

(e) coating a third coating layer on said second film layer, said third coating layer formulated as a blend of said first and said second coating layers; and

(f) curing said third coating layer on said second coating layer to form a third film layer which layer is thermally decomposable upon exposure to said fire conditions to form a third carbonific char which char intumesces to form a carbonific char foam blend having a first foam component, and a second foam component, said insulative carbonific char foam forming under said carbonific char foam blend.

12. The substrate coated according to the method of claim 7.

13. The substrate coated according to the method of claim 10.

14. The substrate coated according to the method of claim 11.

18. The method of claim 10 wherein said first and second rigid carbonific char foams have a density of between about 0.5 g/cm³ and less than about 1.0 g/cm³, and said insulative carbonific char foam has a density of between greater than about 0.01 g/cm³ and less than about 0.5 g/cm³.