Dental resin material and process for producing the same

• US 5,990,195 A
• Filed: 05/08/1998
• Issued: 11/23/1999
• Est. Priority Date: 05/26/1997
• Status: Expired due to Term

• Current Assignee: GC Corporation (General Cannabis Corp.)
• Original Assignee: GC Corporation (General Cannabis Corp.)
• Inventors: Arita, Akishi
• Primary Examiner(s): Merriam, Andrew E. C.
• Application Number:
  US09/074,369
• Time in Patent Office: 564 Days
• Field of Search: 523/115, 523/116, 523/209, 524/493, 524/494, 528/502 C
• US Class Current: 523/116
• CPC Class Codes: A61K 6/887 Compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
• CPC Class Codes: C08K 3/40 Glass
• CPC Class Codes: C08L 33/06 of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical

Abstract

A dental resin material which is formed into a dental prosthesis by milling processing is disclosed, comprising an acrylic resin polymer containing from 20 to 70% by weight of an inorganic filler having a mean particle size of from 0.01 to 0.04 μm in diameter. A process for producing a dental resin material is also disclosed, which comprises polymerizing for curing a mixture comprising a combination of from 20 to 70% by weight of an inorganic filler having a mean particle size of from 0.01 to 0.04 μm in diameter, a methacrylate or acrylate monomer having at least one unsaturated double bond, and a heat polymerization initiator while elevating the pressure and heating under the conditions that the pressure is from 50 to 300 MPa and that the temperature is from 100 to 200° C. The dental resin material according to the invention has esthetics and mechanical properties suitable for dental prostheses such as inlays or crowns and being free from unpolymerized monomers, which is superior in machinability and can be suitably used for the preparation of dental prostheses by milling processing by means of a CAD/CAM device.

Claims

1. A process for producing a dental resin material which comprises polymerizing for curing a mixture comprising a combination of from 20 to 70% by weight of an inorganic filler having a mean particle size of from 0.01 to 0.04 μ

m in diameter, a methacrylate or acrylate monomer having at least one unsaturated double bond, and a heat polymerization initiator while elevating the pressure and heating under the conditions that the pressure is from 50 to 300 MPa and that the temperature is from 100 to 200°

C.

2. A process for producing a dental resin material as claimed in claim 1, in which the mixture further comprises from 1 to 40% by weight of a glass powder having a mean particle size of from 0.1 to 5 μ

m in diameter.

3. A process for producing a dental resin material as claimed in claim 1, in which the mixture further comprises from 1 to 40% by weight of an organic-inorganic composite filler prepared by mixing and curing a mixture of a ultrafine inorganic filler having a mean particle size of from 0.01 to 0.04 μ

m in diameter with a methacrylate or acrylate monomer having at least one unsaturated double bond and pulverizing the cured mixture so as to have a mean particle size of from 5 to 50 μ

m in diameter.

4. A process for producing a dental resin material as claimed in claim 2, in which the mixture further comprises from 1 to 40% by weight of an organic-inorganic composite filler prepared by mixing and curing a mixture of a ultrafine inorganic filler having a mean particle size of from 0.01 to 0.04 μ

m in diameter with a methacrylate or acrylate monomer having at least one unsaturated double bond and pulverizing the cured mixture so as to have a mean particle size of from 5 to 50 μ

m in diameter.

5. The dental resin material produced by the process of claim 1.

6. The dental resin material produced by the process of claim 2.

7. The dental resin material produced by the process of claim 3.

8. The dental resin material produced by the process of claim 4.