Indicator ink compositions

• US 5,990,199 A
• Filed: 04/19/1995
• Issued: 11/23/1999
• Est. Priority Date: 04/19/1995
• Status: Expired due to Term

• Current Assignee: Crosstex International Incorporated (Steris PLC)
• Original Assignee: North American Science Associates, Inc.
• Inventors: Gorski, Joel R., Bealing, John R.
• Primary Examiner(s): Jagannathan, Vasu
• Assistant Examiner(s): GUARRIELLO, JOHN J
• Application Number:
  US08/423,452
• Time in Patent Office: 1,679 Days
• Field of Search: 523/164, 523/208, 260/DIG. 38, 524/508, 524/509, 524/510, 160/20 R, 160/22 R, 160/31.13, 160/31.18, 160/31.27
• US Class Current: 523/161
• CPC Class Codes: A61L 2/28 Devices for testing the effectiveness or completeness of sterilisation, e.g. indicators which change colour apparatus involving enzymes or microorganisms C12M1/34; methods involving enzymes or microorganisms C12Q1/00
• CPC Class Codes: C09D 11/50 Sympathetic, colour changing or similar inks
• CPC Class Codes: G01N 31/226 for investigating the degree of sterilisation
• CPC Class Codes: Y10S 260/38 Ink

Abstract

The invention relates to indicator ink compositions that contain a water-based dispersion of a phenol-formaldehyde resin, at least one colorant and an amine-terminated catalyst. These indicator ink compositions are fixed to a surface, such as by drying, and respond to specific conditions of time, temperature, humidity, pressure and the presence or absence of certain chemicals by changing color. Compositions provide a means for detecting exposure to a predetermined condition and can be fixed or otherwise attached to nearly any article or designed into patterns on materials. Exposure of the indicator ink to the specific condition, the indicator ink provides a permanent detectable record of the event. Further, by varying the amount of amine-terminated catalyst in the formulation, the specific conditions at which the indicator composition will change color can be altered. Such compositions are specifically useful for determining the effectiveness of a sterilization process.

Claims

1. An indicator ink comprising a dispersion of phenol-formaldehyde resin in water, at least one colorant and between about 0.5% to about 13% of the total weight of the composition a polyamide curing agent with an amine value between about 100 to about 400.

2. The indicator ink of claim 1 which has a thermotropic property.

3. The indicator ink of claim 2 wherein the thermotropic property is adjustable by altering the concentration of the polyamide curing agent in relation to the concentration of the phenol-formaldehyde resin.

4. The indicator ink of claim 1 wherein the phenol-formaldehyde resin is stabilized with a coating.

5. The indicator ink of claim 4 wherein the coating is a non-ionic colloid.

6. The indicator ink of claim 5 wherein the non-ionic colloid is a polyvinyl alcohol or a polyvinyl acrylic.

7. The indicator ink of claim 1 wherein the phenol-formaldehyde resin has a molecular weight of less than about 1000.

8. The indicator ink of claim 1 wherein the phenol-formaldehyde resin is cross-linked on exposure to a temperature of greater than about 150°

C.

9. The indicator ink of claim 1 wherein the phenol-formaldehyde resin is an alkaline catalyzed phenolic resin.

10. The indicator ink of claim 1 wherein the at least one colorant is present at between about 0.5% to about 5% of the total weight of the composition.

11. The indicator ink of claim 1 wherein the at least one colorant comprises one or more dyes selected from the group consisting of reactive dyes and extractable dyes.

12. The indicator ink of claim 11 wherein the reactive dye is selected from the group consisting of substituted phenazines, diazotized products of safranine and quinine oximes.

13. The indicator ink of claim 11 wherein the extractable dye is selected from the group consisting of aniline dyes, sodium sulfonate salts of triphenyl methane dyes and sodium sulfonate salts of induline.

14. The indicator ink of claim 1 further comprising a non-extractable dye.

15. The indicator ink of claim 14 wherein the non-extractable dye is a phenylsafranine dye.

16. The indicator ink of claim 1 further comprising one or more ingredients selected from the group consisting of electrolytes, defoaming agents, dispersing agents, drying agents, opacifiers, rheology modifiers, slip additives, surfactants and viscosity increasing agents.

17. The indicator ink of claim 16 wherein the surfactant is sodium lauryl sulfate.

18. A thermotropic indicator ink comprising a dispersion of phenol-formaldehyde resin in water, at least one colorant and between about 0.5% to about 13% of the total weight of the composition a polyamide curing agent with an amine value between about 100 to about 400 wherein said resin has a molecular weight of less than 1000.

19. The indicator ink of claim 18 wherein the thermotropic property of said ink is adjustable by altering the concentration of the polyamide curing agent in relation to the concentration of the phenol-formaldehyde resin.

20. The indicator ink of claim 18 wherein the phenol-formaldehyde resin is stabilized with a coating.

21. The indicator ink of claim 18 wherein the phenol-formaldehyde resin is cross-linked on exposure to a temperature of greater than about 150°

C.

22. The indicator ink of claim 18 wherein the phenol-formaldehyde resin is an alkaline catalyzed phenolic resin.

23. The indicator ink of claim 18 wherein the at least one colorant is present at between about 0.5% to about 5% of the total weight of the composition.