Multilayer polarizer having a continuous and disperse phase

• US 5,991,077 A
• Filed: 08/21/1998
• Issued: 11/23/1999
• Est. Priority Date: 02/29/1996
• Status: Expired due to Term

• Current Assignee: 3M Innovative Properties Company (3M Company)
• Original Assignee: 3M Innovative Properties Company (3M Company)
• Inventors: Weber, Michael F., Ouderkirk, Andrew J., Nevitt, Timothy J., Stover, Carl A., Allen, Richard C., Majumdar, Biswaroop, Carlson, Lockwood W., Kotz, Arthur L.
• Primary Examiner(s): Spyrou, Cassandra
• Assistant Examiner(s): Juba, Jr., John
• Application Number:
  US09/138,179
• Time in Patent Office: 459 Days
• Field of Search: 252/585, 359/483, 359/485, 359/486, 359/492, 359/500, 359/494
• US Class Current: 359/487.02
• CPC Class Codes: G02B 5/3008 comprising dielectric particles, e.g. birefringent crystals embedded in a matrix
• CPC Class Codes: G02B 5/305 including organic materials, e.g. polymeric layers
• CPC Class Codes: Y10S 359/90 Methods

Abstract

An optical film is provided which comprises a disperse phase of polymeric particles disposed within a continuous birefringent matrix. The film is oriented, typically by stretching, in one or more directions. The size and shape of the disperse phase particles, the volume fraction of the disperse phase, the film thickness, and the amount of orientation are chosen to attain a desired degree of diffuse reflection and total transmission of electromagnetic radiation of a desired wavelength in the resulting film.

Claims

1. A polarizer, comprising:

a plurality of layers arranged in a repeating sequence of at least a first, second, and third layer type;

wherein at least one of said first, second, and third layer type comprises a continuous phase and a disperse phase, and wherein said continuous and disperse phases comprise diverse thermoplastic polymers.

2. The polarizer of claim 1, wherein said continuous and disperse phases have indices of refraction which differ by less than about 0.05 for visible light polarized along a first axis, and which differ by more than about 0.05 for visible light polarized along a second axis.

3. The polarizer of claim 1, wherein said polarizer has a total diffuse reflectivity of at least 30% for visible light.

4. The polarizer of claim 1, wherein said disperse phase is present in an amount within the range of about 15% to about 30% by volume relative to said continuous phase.

5. A polarizing film, comprising:

a first layer comprising a polymeric continuous phase and a disperse phase disposed within said continuous phase; and

a second layer, contiguous to said first layer;

wherein said first and second layers have indices of refraction which differ by less than about 0.05 for visible light polarized along a first axis and which differ by more than about 0.05 for visible light polarized along a second axis orthogonal to said first axis; and

wherein said first axis is perpendicular to the plane of said film.

6. The polarizer of claim 5, wherein said continuous and disperse phases have indices of refraction which differ by less than about 0.05 for visible light polarized along a first axis, and which differ by more than about 0.05 for visible light polarized along a second axis.

7. The polarizer of claim 5, wherein said polarizer has a total diffuse reflectivity of at least 30% for visible light.

8. The polarizer of claim 5, wherein said disperse phase is present in an amount within the range of about 15% to about 30% by volume relative to said continuous phase.

9. A polarizer, comprising:

a core layer comprising a continuous phase and a disperse phase;

a first layer, disposed on a first side of said core layer; and

a second layer, disposed on a second side of said core layer;

wherein said continuous and disperse phases comprise first and second diverse polymeric materials, respectively, and wherein said first and second layers comprise at least one of said first and second polymeric materials.

10. The polarizer of claim 9, wherein each of said first and second layers comprise said first polymeric material.

11. The polarizer of claim 10, wherein said continuous phase comprises a naphthalene dicarboxylic acid.

12. The polarizer of claim 10, wherein said disperse phase comprises syndiotactic polystyrene.

13. The polarizer of claim 11, wherein said naphthalene dicarboxylic acid is polyethylene naphthalate.

14. The polarizer of claim 9, wherein said continuous and disperse phases have indices of refraction which differ by less than about 0.05 for visible light polarized along a first axis, and which differ by more than about 0.05 for visible light polarized along a second axis.

15. The polarizer of claim 9, wherein said polarizer has a total diffuse reflectivity of at least 30% for visible light.

16. The polarizer of claim 9, wherein said disperse phase is present in an amount within the range of about 15% to about 30% by volume relative to said continuous phase.