Broadband protective optical window coating

• US 5,993,981 A
• Filed: 04/18/1997
• Issued: 11/30/1999
• Est. Priority Date: 04/18/1997
• Status: Expired due to Term

• Current Assignee: Goodrich Corporation (Raytheon Technologies Corporation d/b/a RTX)
• Original Assignee: Raytheon Company (Rtx Corporation)
• Inventors: Vajo, John J., Bui, Hoa T., Narayanan, Authi A., Vigil, Joseph A., Askinazi, Joel
• Primary Examiner(s): Speer, Timothy
• Assistant Examiner(s): STEIN, STEPHEN J
• Application Number:
  US08/844,715
• Time in Patent Office: 956 Days
• Field of Search: 428/688, 428/689, 428/697, 428/699, 428/426, 428/432, 428/433, 428/457, 428/469, 428/472, 428/585, 428/704, 359/350, 359/359, 106/286.2, 106/286.5, 106/287.29
• US Class Current: 428/699
• CPC Class Codes: G02B 1/115 Multilayers

Abstract

The present invention provides a broadband transmitting protective coating (10) including an AlGaP protective layer (14) deposited on an optical substrate (12) and an anti-reflection film (16) deposited on the AlGaP protective layer (14). The coating (10) is suitable for use with typical infrared and broadband optical substrate materials such as germanium or multi-spectral ZnS. In the case of a germanium substrate (12), the anti-reflection film (16), (16a) preferably consists of a single layer of hard carbon or alternating layers of hard carbon and silicon. In the case of a multi-spectral ZnS substrate (12a), the anti-reflection film (16b) preferably consists of layered Al₂ O₃ /TaO₅ /LaF₃ /MgF₂. The protective coating (10) is preferably deposited on the optical substrate (12) by a metal organic chemical vapor deposition process wherein an initial layer of AlP is nucleated on the substrate (12) at a temperature of approximately 400° C. The temperature of the substrate (12) is then raised to approximately 600° C. and a layer of AlGaP (14) is grown on the substrate (12) to a preselected thickness. The AlGaP coated optical substrate (12) is then polished to a desired smoothness. The anti-reflection film (16) is then deposited on the AlGaP layer (14) using an RF chemical vapor deposition process or a thermal evaporation process.

Claims

1. A protective coating having broadband transmittance for an optical substrate comprising:

an AlP layer deposited on said substrate;

an AlGaP layer deposited on said AlP layer; and

an anti-reflection film layer deposited on said AlGaP layer.

2. The protective coating of claim 1 wherein said AlGaP layer has a thickness of approximately 10-40 micrometers.

3. The protective coating of claim 1 wherein said AlGaP layer has a thickness of approximately 20-30 micrometers.

4. The protective coating of claim 1 wherein said AlGaP layer has a thickness of approximately 22 micrometers.

5. The protective coating of claim 1 wherein said anti-reflection film comprises one of the group consisting of a single layer of hard carbon, alternating layers of hard carbon and silicon, and layered Al₂ O₃ /TaO₅ /LaF₃ /MgF₂.

6. The protective coating of claim 1 wherein said optical substrate comprises one selected from the group consisting of germanium, zinc sulfide, and zinc selenide.

7. The protective coating of claim 1 wherein said AlGaP layer is deposited by a metal organic chemical vapor deposition process.

8. The protective coating of claim 1 wherein said anti-reflection film is deposited on said AlGaP layer by a process selected from the group consisting of radio frequency chemical vapor deposition and thermal evaporation.

9. An optical window for use in airborne and ground based tactical and surveillance sensors suitable for withstanding high speed rain and sand impact with improved broadband transmittance, said optical window comprising:

a germanium substrate;

an AlP nucleating layer deposited on said germanium substrate;

an AlGaP protective layer deposited on said AlP nucleating layer to a preselected thickness; and

an anti-reflection film deposited on said AlGaP protective layer.

10. The optical window of claim 9 wherein said anti-reflection film further comprises one selected from the group consisting of a single layer of hard carbon, and alternating layers of hard carbon and silicon.

11. The optical window of claim 9 wherein said preselected thickness of said AlGaP protective layer is approximately 20-25 micrometers.

12. The optical window of claim 9 wherein said AlGaP protective layer is deposited on said AlP nucleating layer by a metal organic chemical vapor deposition process.

13. The optical window of claim 9 wherein said anti-reflection film is deposited on said AlGaP protective layer by a radio frequency chemical vapor deposition process.

14. An optical window for use in airborne and ground based tactical and surveillance sensors suitable for withstanding high speed rain and sand impact with improved broadband transmittance, said optical window comprising:

a multi-spectral zinc sulfide, zinc sulfide or zinc selenoid substrate;

an AlP nucleating layer deposited on said substrate;

an AlGaP protective layer deposited on said AlP nucleating layer to a pre-selected thickness; and

an anti-reflection film deposited on said AlGaP protective layer.

15. The optical window of claim 14 wherein said anti-reflection film further comprises layered Al₂ O₃ /TaO₅ /LaF₃ /MgF₂.

16. The optical window of claim 14 wherein said preselected thickness of said AlGaP protective layer is approximately 20-25 micrometers.

17. The optical window of claim 14 wherein said AlGaP protective layer is deposited on said AlP nucleating layer by a metal organic chemical vapor deposition.

18. The optical window of claim 14 wherein said anti-reflection film is deposited on said AlGaP protective layer by a thermal evaporation process.