Methods and apparatus for the application of combined fields to disinfect fluids

• US 5,997,812 A
• Filed: 08/01/1996
• Issued: 12/07/1999
• Est. Priority Date: 06/20/1996
• Status: Expired due to Fees

• Current Assignee: Administrators Of The Tulane Educational Fund (ADMINISTRATORS|DAVID H. COY), Coolant Treatment Systems, LLC, Mcmaster University
• Original Assignee: Administrators Of The Tulane Educational Fund (ADMINISTRATORS|DAVID H. COY), Coolant Treatment Systems, LLC
• Inventors: Reimers, Robert S., Barton, Jery E., Bankston, Warren S., Burnham, Jeffrey C.
• Primary Examiner(s): JASTRZAB, KRISANNE MARIE
• Application Number:
  US08/690,982
• Time in Patent Office: 1,223 Days
• Field of Search: 422/24, 422/186.3, 422/23, 422/1, 210/695, 210/754, 210/748, 210/760, 210/764, 210/766, 210/407, 250/455.11
• US Class Current: 422/24
• CPC Class Codes: A23L 2/50 by irradiation or electric treatment without heating
• CPC Class Codes: A23L 3/28 with ultraviolet light
• CPC Class Codes: A61L 11/00 Methods specially adapted for refuse disintegrating medical waste B02C19/0075; disposal of medical waste B09B3/00
• CPC Class Codes: A61L 2/10 Ultraviolet radiation
• CPC Class Codes: B01J 19/081 employing particle radiation or gamma-radiation
• CPC Class Codes: B01J 19/087 employing electric or magnetic energy
• CPC Class Codes: B01J 19/10 employing sonic or ultrasonic vibrations
• CPC Class Codes: B01J 19/123 Ultraviolet light
• CPC Class Codes: B01J 19/243 spirally, concentrically or zigzag wound
• CPC Class Codes: B01J 2219/00139 using electromagnetic heating
• CPC Class Codes: B01J 2219/0852 employing permanent magnets
• CPC Class Codes: B01J 2219/0854 employing electromagnets
• CPC Class Codes: C02F 1/32 with ultraviolet light
• CPC Class Codes: C02F 1/325 Irradiation devices or lamp constructions
• CPC Class Codes: C02F 1/36 ultrasonic vibrations
• CPC Class Codes: C02F 1/38 by centrifugal separation
• CPC Class Codes: C02F 1/40 Devices for separating or removing fatty or oily substances or similar floating material cleaning or keeping clear the surface of open water from oil or like materials E02B15/04; devices in sewers for separating liquid or solid substances from sewage E03F5/14, e.g. for use in drains leading to the sewer E03F5/16
• CPC Class Codes: C02F 1/48 with magnetic or electric fields C02F1/46 takes precedence
• CPC Class Codes: C02F 1/76 with halogens or compounds of halogens C02F1/4674 takes precedence
• CPC Class Codes: C02F 1/766 by means of halogens other than chlorine or of halogenated compounds containing halogen other than chlorine
• CPC Class Codes: C02F 2101/203 : Iron or iron compound
• CPC Class Codes: C02F 2101/32 : Hydrocarbons, e.g. oil
• CPC Class Codes: C02F 2103/023 : Water in cooling circuits
• CPC Class Codes: C02F 2103/34 : from industrial activities not provided for in groups C02F2103/12 - C02F2103/32
• CPC Class Codes: C02F 2103/365 : from petrochemical industry (e.g. refineries)
• CPC Class Codes: C02F 2201/006 : Cartridges
• CPC Class Codes: C02F 2301/024 : Turbulent
• CPC Class Codes: C02F 2303/04 : Disinfection
• CPC Class Codes: C02F 2303/24 : Separation of coarse particles, e.g. by using sieves or screens
• CPC Class Codes: C02F 9/20 : Portable or detachable small-scale multistage treatment devices, e.g. point of use or laboratory water purification systems
• CPC Class Codes: Y02W 10/37 : using solar energy

Abstract

This invention relates to apparatus and methods for the treatment of fluids with magnetic fields and, in particular, to the disinfection of contaminated fluids by treating the fluids with a high-gauss magnet followed by ultraviolet radiation. Fluids can accumulate organic and non-organic contaminants from multiple and diverse sources. Magnetic treatment enhances the ability to separate hydrophobic contaminants from the fluid and the ability of that fluid to be disinfected. A wide variety of fluids can be treated with these methods including water to be made potable, industrial water and other fluids such as coolants and lubricants, oils, petrochemicals such as fuels, and beverages. Further, fluid can be exposed to UV radiation at a flow rate sufficient to prevent occlusion of UV-transmissible surfaces in the disinfection system by contaminants in the fluid or by removing a set amount of those contaminants. Using these methods, microorganism levels can be substantially decreased with a reduced need for biocides or other anti-bacterial or anti-fungal agents. These methods are highly effective at removing contaminants and extending the useful life of fluids such as coolants and reducing or eliminating the risks posed to workers by heavily contaminated or biocide-treated coolants.

Claims

1. A method for disinfecting a contaminated fluid that is substantially opaque comprising

passing the fluid through a magnetic field at a velocity of greater than about 1 meter per second and

irradiating the fluid with a disinfecting amount of ultraviolet radiation without shaping said fluid into a thin film of less than 5 mm.

2. The method of claim 1 wherein the contaminated fluid is an aqueous fluid, an industrial fluid, a combustible fuel or a liquid beverage.

3. The method of claim 1 wherein the contaminated fluid is selected from the group consisting of water to be made potable, beverages, industrial water, coolant, lubricating oil, fuel, petrochemicals, alcohols, acids and combinations thereof.

4. The method of claim 1 wherein the contaminated fluid is an aqueous fluid and said aqueous fluid is passed through the magnetic field at a velocity of from about 2 to about 5 feet per second.

5. The method of claim 1 wherein the contaminated fluid is an organic fluid and said organic fluid is passed through the magnetic field at a velocity of from about 10 to about 50 feet per second.

6. The method of claim 1 wherein the magnetic field is generated by an electromagnet or a permanent magnet.

7. The method of claim 1 wherein the magnetic field strength is between about 600 to about 9,000 gauss.

8. The method of claim 1 further comprising the step of passing said fluid through a contaminant separation system.

9. The method of claim 8 wherein the contaminant separation system comprises one or more filters or oil separators.

10. The method of claim 9 wherein the one or more filters comprises a magnetic filter that removes ferrous and ferric complexes.

11. The method of claim 9 wherein the one or more oil separators contains an oil adsorption material selected from the group consisting of a particulate copolymer, polypropylene, polyester, peat, kenaf, cellulose fibers and combinations thereof.

12. The method of claim 9 wherein the one or more oil separators comprises a cyclonic separator, a filter bag, a coalescent filter, a skimmer, a centrifuge or a combination thereof.

13. The method of claim 1 wherein the contaminated fluid has a bacterial load that is reduced at least 1 log after irradiation.

14. The method of claim 1 wherein the contaminated fluid has a bacterial load that is reduced at least 2 logs after irradiation.

15. The method of claim 1 wherein the contaminated fluid is contained within a closed system and the bacterial load within said system remains below about 10³ microorganisms per ml.

16. The method of claim 1 wherein the step of passing said fluid through the electric field reduces scale adherence.

17. The method of claim 1 further comprising the step of creating turbulence in the contaminated fluid during irradiation.

18. The method of claim 17 wherein turbulence is created by shape modification of a tubing system that contains and guides passage of said fluid.

19. A fluid disinfected by the method of claim 1.

20. A method for disinfecting a fluid that is substantially opaque comprising

passing oxygenated fluid containing molecular iron through a magnetic field at a velocity of greater than about 1 meter per second wherein said magnetic field is sufficient to form a disinfecting amount of ferrates.

21. The method of claim 20 wherein the fluid is supplemented with an oxidizing agent to form said oxygenated fluid.

22. The method of claim 21 wherein the oxidizing agent is hydrogen peroxide, ozone or a combination thereof.

23. The method of claim 21 wherein the fluid is supplemented with air or oxygen and subsequently treated with sufficient ultraviolet radiation to form said oxidizing agent.

24. The method of claim 20 wherein the disinfecting amount of ferrates is greater than about 10^-3 mM.

25. A fluid disinfected according to the method of claim 20.

26. A method for treating a fluid that is substantially opaque comprised of

passing the fluid through a magnetic field and an ultraviolet disinfection system, without shaping said fluid into a thin film of less than 5 mm, at a velocity of greater than about 1 meter per second.

27. The method of claim 26 wherein the fluid is an aqueous fluid, an organic fluid, an industrial fluid or a combustible fluid.

28. The method of claim 27 wherein the combustible fluid is selected from the group consisting of diesel fuel, gasoline, hydraulic fluid, machine oil, natural gas, petrochemicals, alcohols, acids and combinations thereof.

29. The method of claim 26 wherein the magnetic field is generated by an electromagnet or a permanent magnet.

30. The method of claim 26 wherein the magnetic field strength is between about 600 to about 9,000 gauss.

31. The method of claim 26 wherein the fluid disinfection system comprises a microbe filter, ultraviolet or ionizing radiation treatment, ultrasound treatment, heat treatment, the addition of a biocide or pasteurization of said fluid.

32. The method of claim 26 further comprising the step of passing said fluid through one or more filters.

33. The method of claim 32 wherein the one or more filters comprise oil separators, particle filters, or filters containing magnets.

34. A fluid treated by the method of claim 26.

35. A method for disinfecting a contaminated ultraviolet opaque fluid comprising passing the contaminated fluid through a magnetic field and heating the contaminated fluid to a pasteurizing or sterilizing temperature for a period of time.

36. The method of claim 35 wherein the contaminated fluid is an aqueous fluid, an organic fluid, an industrial fluid or a combustible fluid.

37. The method of claim 35 further comprising the step of passing said fluid through one or more filters.

38. A fluid disinfected by the method of claim 35.