Fast-setting latex coating and formulations

• US 5,997,952 A
• Filed: 05/23/1997
• Issued: 12/07/1999
• Est. Priority Date: 05/23/1997
• Status: Expired due to Term

• Current Assignee: The Dow Chemical Company (Dow, Inc.)
• Original Assignee: The Dow Chemical Company (Dow, Inc.)
• Inventors: Rose, Gene D., Schmidt, Donald L., Harris, John K.
• Primary Examiner(s): Chen, Vivian
• Application Number:
  US08/862,274
• Time in Patent Office: 928 Days
• Field of Search: 428/463, 428/461, 428/441, 428/442, 428/500, 428/522, 526/274, 526/286, 526/287, 526/310.4, 526/317.1, 526/318.1, 526/318.3, 526/318.4, 526/318.41, 526/319, 526/318.42, 526/329.7, 526/318.44 , 526/303.1, 526/307, 526/307.2, 526/307.3, 526/923, 427/299, 427/301, 427/302, 427/303, 427/322, 427/324, 427/325, 427/326, 427/327
• US Class Current: 427/302
• CPC Class Codes: B05D 1/36 Successively applying liquids or other fluent materials, e.g. without intermediate treatment
• CPC Class Codes: B05D 7/52 Two layers
• CPC Class Codes: C04B 28/02 containing hydraulic cements other than calcium sulfates
• CPC Class Codes: C04B 41/009 characterised by the material treated
• CPC Class Codes: C04B 41/48 Macromolecular compounds
• CPC Class Codes: C04B 41/63 Macromolecular compounds
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 33/064 containing anhydride, COOH or COOM groups, with M being metal or onium-cation
• CPC Class Codes: C09D 133/062 Copolymers with monomers not covered by C09D133/06
• CPC Class Codes: Y10S 526/923 Ethylenic monomers containing at least one salt group

Abstract

A method of preparing a fast-setting coating material on a substrate which comprises contacting a stable aqueous dispersion of a polymer that contains strong cationic groups and weak acid groups onto a substrate that is basic or treated to be basic.

Claims

1. A method of preparing a fast-setting coating on a substrate having a surface comprising the step of contacting the surface of the substrate with a stable aqueous dispersion containing a polymer having pendant strong cationic groups and pendant weak acid groups, wherein the surface of the substrate is, or is treated to be, sufficiently basic so that the stable aqueous dispersion sets in less time than the time required for a latex that contains a polymer having pendant strong cationic groups or pendant weak acid groups, but not both.

2. The method of claim 1 wherein the polymer further contains structural units formed from the polymerization of a non-interfering polymerizable monomer.

3. The method of claim 2 wherein the non-interfering polymerizable monomer is methyl acrylate, ethyl acrylate, butyl acrylate, 2-hydroxyethyl acrylate, 2-hydroxypropyl acrylate, allyl acrylate, glycidyl acrylate, methyl methacrylate, ethyl methylacrylate, butyl methacrylate, allyl methacrylate, glycidyl methacrylate, 2-hydroxyethyl methacrylate, 2-hydroxypropyl methacrylate, a C₃ -C₁₈ -perfluoroalkyl methacrylate, a C₃ -C₁₈ -perfluoroalkyl acrylate, a C₃ -C₁₈ -perfluoroalkyl vinylbenzene, alkenyl aromatic hydrocarbons, styrene, α

-methylstyrene, or vinyltoluene, or a combination thereof.

4. The method of claim 3 wherein the weak acid groups are formed from the polymerization of a polymerizable weak acid monomer which is acrylic acid, methacrylic acid, itaconic acid, β

-carboxyethyl acrylate, or vinylbenzoic acid, or a combination thereof.

5. The method of claim 4 wherein the pendant strong cationic groups are formed either from:

a) the polymerization of a polymerizable strong cationic monomer which is an trialkylammoniumalkyl acrylate;

a trialkylammoniumalkyl methacrylate, a trialkylammoniumalkyl acrylamide, a dialkylsulfonium salt, a benzylsulfonium salt, a cyclic sulfonium salt, a 2-methacryloxyethyltri-C₁ -C₂₀ -alkyl-phosphonium salt, a 2-methacryloxyethyltri-C₁ -C₂₀ -aralkyl-phosphonium salt, a 2-methacryloxyethyltri-C₁ -C₂₀ -aryl-phosphonium salt, a tri-C₁ -C₁₈ -alkyl-vinylbenzylphosphonium salt, a tri-C₁ -C₁₈ -aralkyl-vinylbenzylphosphonium salt, a tri-C₃ -C₁₈ -aryl-vinylbenzylphosphonium salt, a C₃ -C₁₈ -alkenyltrialkyl-phosphonium salt, a C₃ -C₁₈ -aralkyl-phosphonium salt, or a C₃ -C₁₈ -aryl-phosphonium salt, or a combination thereof;

or

b) the polymerization of a polymerizable tertiary amine or sulfide followed by reaction with an alkylating reagent to form a quaternary ammonium salt or a sulfonium salt;

or

c) the polymerization of a polymerizable monomer containing an electrophilic group, followed by the reaction with a tertiary amine or a sulfide to form a quaternary ammonium salt or a sulfonium salt.

6. The method of claim 5 wherein the non-interfering polymerizable monomer is methyl methacrylate, butyl acrylate, 2-hydroxyethyl methacrylate, 4-methacryloxy-2-hydroxy-benzophenone, or 2-(2'"'"'-hydroxy-5-methacrylyloxyethylphenyl)-2H-benzotriazole, styrene, or a combination thereof.

7. The method of claim 6 wherein the ratio of the structural units formed from the non-interfering polymerizable monomer to the strong cationic groups and the weak acid groups is from about 90:

10 to about 99.5;

0.5.

8. The method of claim 7 wherein the strong cationic groups are formed from the polymerization of an ethylenically unsaturated quaternary ammonium salt.

9. The method of claim 8 wherein the quaternary ammonium salt is 2-[(methacryloyloxy)ethyl]trimethylammonium chloride, the polymerizable weak acid monomer is acrylic acid or methacrylic acid, and the non-interfering polymerizable monomer is styrene, methyl methacrylate, or butyl acrylate, or a combination thereof.

10. The method of claim 9 wherein the stable aqueous dispersion is dry-to-the-touch within 5 minutes after contact with the substrate.

11. The method of claim 9 wherein the stable aqueous dispersion is dry-to-the-touch within 3 minutes after contact with the substrate.

12. The method of claim 9 wherein the stable aqueous dispersion is dry-to-the-touch within 1 minute after contact with the substrate.

13. The method of claim 12 wherein the substrate is an cured inorganic cement, an uncured inorganic cement, or is treated to basic and is metal, glass, paper, plastic, cloth, wood, or leather.

14. The method of claim 2, wherein the substrate is cured Portland cement, uncured Portland cement, aluminous cement, inorganic mortar, or cementations fiber board.

15. The method of claim 2 wherein the substrate is treated to be basic and is metal, glass, paper, plastic, cloth, wood, or leather.

16. The method of claim 2 wherein the stable aqueous dispersion has a weight-to-weight solids content in the range of from about 20 percent to about 60 percent.

17. The method of claim 16 wherein the stable aqueous dispersion has a weight-to-weight solids content in the range of from about 30 percent to about 50 percent.

18. A method of preparing a fast-setting coating on a substrate having a surface comprising the step of contacting the surface of the substrate with a stable aqueous dispersion of a polymer having pendant strong cationic groups, pendant weak acid groups, and structural units formed from the polymerization of a non-interfering polymerizable monomer, wherein

a) the ratio of the structural units formed from the non-interfering polymerizable monomer to the strong cationic groups and the weak acid groups is not less than 90:

10 and not greater than 99.5;

0.5;

b) the mole-to-mole ratio of the pendant strong cationic groups to weak anionic groups is from 4;

1 to 1;

4; and

c) the surface of the substrate is, or is treated to be, sufficiently basic so that the stable aqueous dispersion is dry-to-the-touch in less than 5 minutes.