Composite battery and methods of forming same

• US 5,998,052 A
• Filed: 12/02/1997
• Issued: 12/07/1999
• Est. Priority Date: 12/02/1997
• Status: Expired due to Term

• Current Assignee: Tadiran Batteries Ltd. (Totalenergies Se)
• Original Assignee: Tadiran Batteries Ltd. (Totalenergies Se)
• Inventors: Yamin, Herzel
• Primary Examiner(s): Nuzzolillo, Maria
• Assistant Examiner(s): WEINER, LAURA S
• Application Number:
  US08/982,522
• Time in Patent Office: 735 Days
• Field of Search: 429/9, 429/123, 429/101, 429/105, 429/50, 429/231.95, 429/49, 320/103, 320/126, 320/137, 320/FOR 114, 320/FOR 115
• US Class Current: 429/9
• CPC Class Codes: H01M 10/052 Li-accumulators
• CPC Class Codes: H01M 10/0525 Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
• CPC Class Codes: H01M 10/44 Methods for charging or discharging circuits for charging H02J7/00
• CPC Class Codes: H01M 16/00 Structural combinations of different types of electrochemical generators
• CPC Class Codes: H01M 50/213 adapted for cells having curved cross-section, e.g. round or elliptic H01M50/209, H01M50/216 take precedence
• CPC Class Codes: H01M 6/14 Cells with non-aqueous electrolyte
• CPC Class Codes: H01M 6/5033 used as charging means for another battery
• CPC Class Codes: H01M 6/5088 Initial activation; predischarge; Stabilisation of initial voltage
• CPC Class Codes: H02J 7/0069 Charging or discharging for charge maintenance, battery initiation or rejuvenation
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

A composite electrical battery including a primary electrochemical cell and a fully or partially discharged rechargeable electrochemical cell. The rechargeable electrochemical cell is electrically connected in parallel to the primary electrochemical cell. The open circuit voltage of the primary electrochemical cell is significantly lower than the open circuit voltage of the rechargeable cell when the rechargeable cell is fully charged. The self discharge rate of the rechargeable electrochemical cell after electrically connecting the rechargeable electrochemical cell to the primary electrochemical cell is less than a predetermined self discharge rate. The composite battery has an improved current delivery capability for an extended life span compared to the primary electrochemical cell by itself. A method is provided for forming such a composite electrical battery. The method includes providing a primary electrochemical cell, providing a fully or partially discharged rechargeable electrochemical cell, and electrically connecting the primary electrochemical cell in parallel with the fully or partially discharged rechargeable electrochemical cell to form the composite electrical battery. The self discharge rate of the rechargeable electrochemical cell after electrically connecting to the primary electrochemical cell is less than a predetermined self discharge rate for extending the useful lifespan of the composite battery.

Claims

1. A composite electrical battery, comprising:

a primary electrochemical cell; and

a fully or partially discharged rechargeable electrochemical cell electrically connected in parallel to said primary electrochemical cell,

wherein the open circuit voltage of said primary electrochemical cell is lower than the open circuit voltage of said rechargeable cell when said rechargeable cell is not connected to said primary cell and is fully charged, and wherein the self discharge rate of said rechargeable electrochemical cell after electrically connecting said rechargeable electrochemical cell to said primary electrochemical cell is less than the self discharge rate of said rechargeable electrochemical cell when said rechargeable electrochemical cell is not connected to said primary cell and is fully charged.

2. The composite battery according to claim 1, wherein after electrically connecting said primary electrochemical cell with said rechargeable electrochemical cell, said primary electrochemical cell charges said rechargeable electrochemical cell until the open circuit voltage of said composite battery stabilizes at a voltage equal to or lower than the open circuit voltage of said primary electrochemical cell prior to said electrically connecting.

3. The composite battery according to claim 1 wherein said rechargeable electrochemical cell is disposed within said primary electrochemical cell.

4. The composite battery according to claim 1 wherein said primary electrochemical cell is disposed within said rechargeable electrochemical cell.

5. The composite battery according to claim 1 wherein said primary electrochemical cell is electrically connected in parallel with said rechargeable electrochemical cell by electrical connectors which are included in a printed circuit board.

6. The composite battery according to claim 1 wherein said primary electrochemical cell is a lithium/oxyhalide electrochemical cell.

7. The composite battery according to claim 6 wherein said lithium/oxyhalide electrochemical cell is a lithium/thionyl chloride electrochemical cell.

8. The composite battery according to claim 6 wherein said lithium/oxyhalide electrochemical cell is a lithium/sulfuryl chloride electrochemical cell.

9. The composite battery according to claim 6 wherein said lithium/oxyhalide electrochemical cell comprises a mixture of sulfuryl chloride and thionyl chloride.

10. The composite battery according to claim 1 wherein said rechargeable electrochemical cell is a lithium ion rechargeable cell.

11. The composite battery according to claim 1 wherein said rechargeable electrochemical cell is a rechargeable lithium polymer cell.

12. The composite battery according to claim 1 wherein said self discharge rate of said rechargeable electrochemical cell after electrically connecting said rechargeable electrochemical cell to said primary electrochemical cell is less than 30 percent of the initial charge of said composite battery per year at a temperature of 25 degrees centigrade.

13. A method for forming a composite electrical battery, the method comprising the steps of:

providing a primary electrochemical cell;

providing a fully or partially discharged rechargeable electrochemical cell; and

electrically connecting said primary electrochemical cell in parallel with said fully or partially discharged rechargeable electrochemical cell to form said composite electrical battery,

wherein the open circuit voltage of said primary electrochemical cell is lower than the open circuit voltage of said rechargeable cell when said rechargeable cell is not connected to said primary cell and is fully charged, and wherein the self discharge rate of said rechargeable electrochemical cell after the step of electrically connecting is less than the self discharge rate of said rechargeable electrochemical cell when said rechargeable electrochemical cell is not connected to said primary cell and is fully charged.

14. The method according to claim 13, further comprising after said step of electrically connecting the step of allowing said primary electrochemical cell to charge said rechargeable electrochemical cell until the open circuit voltage of said composite battery stabilizes at a voltage equal to or lower than the open circuit voltage of said primary electrochemical cell prior to said step of electrically connecting.

15. The method according to claim 13 wherein said rechargeable electrochemical cell is disposed within said primary electrochemical cell.

16. The method according to claim 13 wherein said primary electrochemical cell is disposed within said rechargeable electrochemical cell.

17. The method according to claim 13 wherein said primary electrochemical cell is electrically connected in parallel with said rechargeable electrochemical cell by electrical connectors which are included in a printed circuit board.

18. The method according to claim 13 wherein said primary electrochemical cell is a lithium/oxyhalide electrochemical cell.

19. The method according to claim 18 wherein said lithium/oxyhalide electrochemical cell is a lithium/thionyl chloride electrochemical cell.

20. The method according to claim 18 wherein said lithium/oxyhalide electrochemical cell is a lithium/sulfuryl chloride electrochemical cell.

21. The method according to claim 18 wherein said lithium/oxyhalide electrochemical cell comprises a mixture of sulfuryl chloride and thionyl chloride.

22. The method according to claim 13 wherein said rechargeable electrochemical cell is a lithium ion rechargeable cell.

23. The method according to claim 13 wherein said rechargeable electrochemical cell is a rechargeable lithium polymer cell.

24. The method according to claim 13 wherein said self discharge rate of said rechargeable electrochemical cell after electrically connecting said rechargeable electrochemical cell to said primary electrochemical cell is less than 30 percent of the initial charge of said composite battery per year at a temperature of 25 degrees centigrade.