Polypropylene waxes modified so as to be polar

• US 5,998,547 A
• Filed: 11/24/1997
• Issued: 12/07/1999
• Est. Priority Date: 11/26/1996
• Status: Expired due to Term

• Current Assignee: Clariant International AG (Clariant AG)
• Original Assignee: Clariant GmbH (Clariant AG)
• Inventors: Hohner, Gerd
• Primary Examiner(s): Dawson, Robert
• Assistant Examiner(s): AYLWARD, DAVID E
• Application Number:
  US08/977,088
• Time in Patent Office: 743 Days
• Field of Search: 525/263, 525/301, 525/333.8, 525/386, 525/387
• US Class Current: 525/301
• CPC Class Codes: C08F 10/06 Propene
• CPC Class Codes: C08F 8/00 Chemical modification by after-treatment graft polymers, block polymers, crosslinking with unsaturated monomers or with polymers C08F251/00 - C08F299/00; of conjugated diene rubbers C08C

Abstract

The present invention relates to partially crystalline polypropylene homopolymer or copolymer waxes modified so as to be polar and having an acid or saponification number of from 0.5 to 120 mg KOH/g, a melt viscosity of from 20 to 50,000 mPa.s/170° C. and a softening point (ring/ball) of from 90 to 165° C., prepared by reacting a nonpolar polypropylene homopolymer or copolymer wax with an α,β-unsaturated carboxylic acid or a derivative thereof in the presence of free-radical formers, wherein the nonpolar polypropylene wax has been prepared by direct polymerization of propylene or copolymerization of propylene with higher 1-olefins using catalysts of Ziegler or metallocene type and has a softening point (ring/ball) of from 90 to 165° C.

The waxes are useful as plastics additives, for aqueous dispersions or for melt adhesive formulations.

Claims

1. A partially crystalline polypropylene homopolymer or copolymer wax modified so as to be polar and having an acid or saponification number of from 0.5 to 120 mg KOH/g, a melt viscosity of from 20 to 50,000 mPa.s/170°

C. and a softening point (ring/ball) of from 90 to 165°

C., prepared by reacting a nonpolar polypropylene homopolymer or copolymer wax with an α

,β

-unsaturated carboxylic acid or a derivative thereof in the presence of free-radical formers, wherein the nonpolar polypropylene wax has been prepared by direct polymerization of propylene or copolymerization of propylene with higher 1-olefins using catalysts of the Ziegler or metallocene type and has a softening point (ring/ball) of from 90 to 165°

C.

5. A process for the use of the waxes as claimed in claim 1 comprising:

incorporating said wax into articles selected from the group consisting of a dispersion, a hot melt adhesive, and a plastic article.

2. A partially crystalline polypropylene homopolymer wax modified so as to be polar and having an acid or saponification number of from 0.5 to 120 mg KOH/g, a melt viscosity of from 20 to 50,000 mPa.s/170°

C. and a softening point (ring/ball) of from 90 to 165°

C., prepared by reacting a nonpolar polypropylene homopolymer wax with an α

,β

-unsaturated carboxylic acid or a derivative thereof in the presence of free-radical formers, wherein the nonpolar polypropylene wax has been prepared by direct polymerization of propylene using catalysts of the Ziegler or metallocene type and has a softening point (ring/ball) of from 90 to 165°

C.

6. A process for the use of the waxes as claimed in claim 2 comprising:

incorporating said wax into articles selected from the group consisting of a dispersion, a hot melt adhesive, and a plastic article.

3. A partially crystalline polypropylene homopolymer or copolymer wax modified so as to be polar and having an acid or saponification number of from 0.5 to 120 mg KOH/g, a melt viscosity of from 20 to 50,000 mPa.s/170°

C. and a softening point (ring/ball) of from 90 to 145°

C., prepared by reacting a nonpolar polypropylene homopolymer or copolymer wax with an α

,β

-unsaturated carboxylic acid or a derivative thereof in the presence of free-radical formers, wherein the nonpolar polypropylene wax has been prepared by direct polymerization of propylene or copolymerization of propylene with higher 1-olefins using catalysts of the Ziegler or metallocene type and has a softening point (ring/ball) of from 90 to 145°

C.

7. A process for the use of the waxes as claimed in claim 3 comprising:

incorporating said wax into articles selected from the group consisting of a dispersion, a hot melt adhesive, and a plastic article.

4. A partially crystalline polypropylene homopolymer wax modified so as to be polar and having an acid or saponification number of from 0.5 to 120 mg KOH/g, a melt viscosity of from 20 to 50,000 mPa.s/170°

C. and a softening point (ring/ball) of from 90 to 145°

C., prepared by reacting a nonpolar polypropylene homopolymer wax with an α

,β

-unsaturated carboxylic acid or a derivative thereof in the presence of free-radical formers, wherein the nonpolar polypropylene wax has been prepared by direct polymerization of propylene using catalysts of the Ziegler or metallocene type and has a softening point (ring/ball) of from 90 to 145°

C.

8. A process for the use of the waxes as claimed in claim 4 comprising:

incorporating said wax into articles selected from the group consisting of a dispersion, a hot melt adhesive, and a plastic article.

9. A process for producing a partially crystalline polypropylene homopolymer or copolymer wax modified so as to be polar and having an acid or saponification number of from 0.5 to 120 mg KOH/g, a melt viscosity of from 20 to 50,000 mPa.s/170°

C. and a softening point (ring/ball) of from 90 to 165°

C. comprising;

preparing a nonpolar polypropylene homopolymer or copolymer wax with a softening point (ring/ball) of from 90 to 165°

C. by direct polymerization of propylene or copolymerization of propylene with higher 1-olefins using catalysts of the Ziegler or metallocene type; and

reacting the nonpolar polypropylene homopolymer or copolymer wax with an α

,β

-unsaturated carboxylic acid or a derivative thereof in the presence of free-radical formers to form the partially crystalline polypropylene homopolymer or copolymer wax.

13. The process as claimed in claim 9, further comprising incorporating the partially crystalline polypropylene homopolymer or copolymer wax into articles selected from the group consisting of a dispersion, a hot melt adhesive, and a plastic article.

10. A process for producing a partially crystalline polypropylene homopolymer wax modified so as to be polar and having an acid or saponification number of from 0.5 to 120 mg KOH/g, a melt viscosity of from 20 to 50,000 mPa.s/170°

C. and a softening point (ring/ball) of from 90 to 165°

C. comprising;

preparing a nonpolar polypropylene homopolymer wax with a softening point (ring/ball) of from 90 to 165°

C. by direct polymerization of propylene or copolymerization of propylene with higher 1-olefins using catalysts of the Ziegler or metallocene type; and

reacting the nonpolar polypropylene homopolymer wax with an α

,β

-unsaturated carboxylic acid or a derivative thereof in the presence of free-radical formers to form the partially crystalline polypropylene homopolymer wax.

14. The process as claimed in claim 10, further comprising incorporating the partially crystalline polypropylene homopolymer wax into articles selected from the group consisting of a dispersion, a hot melt adhesive, and a plastic article.

11. A process for producing a partially crystalline polypropylene homopolymer or copolymer wax modified so as to be polar and having an acid or saponification number of from 0.5 to 120 mg KOH/g, a melt viscosity of from 20 to 50,000 mPa.s/170°

C. and a softening point (ring/ball) of from 90 to 145°

C. comprising;

preparing a nonpolar polypropylene homopolymer or copolymer wax with a softening point (ring/ball) of from 90 to 145°

C. by direct polymerization of propylene or copolymerization of propylene with higher 1-olefins using catalysts of the Ziegler or metallocene type; and

reacting the nonpolar polypropylene homopolymer or copolymer wax with an α

,β

-unsaturated carboxylic acid or a derivative thereof in the presence of free-radical formers to form the partially crystalline polypropylene homopolymer or copolymer wax.

15. The process as claimed in claim 11, further comprising incorporating the partially crystalline polypropylene homopolymer or copolymer wax into articles selected from the group consisting of a dispersion, a hot melt adhesive, and a plastic article.

12. A process for producing a partially crystalline polypropylene homopolymer wax modified so as to be polar and having an acid or saponification number of from 0.5 to 120 mg KOH/g, a melt viscosity of from 20 to 50,000 mPa.s/170°

C. and a softening point (ring/ball) of from 90 to 145°

C. comprising;

preparing a nonpolar polypropylene homopolymer wax with a softening point (ring/ball) of from 90 to 145°

C. by direct polymerization of propylene or copolymerization of propylene with higher 1-olefins using catalysts of the Ziegler or metallocene type; and

reacting the nonpolar polypropylene homopolymer wax with an α

,β

-unsaturated carboxylic acid or a derivative thereof in the presence of free-radical formers to form the partially crystalline polypropylene homopolymer wax.

16. The process as claimed in claim 12, further comprising incorporating the partially crystalline polypropylene homopolymer wax into articles selected from the group consisting of a dispersion, a hot melt adhesive, and a plastic article.