Compositions and methods for the remediation of chemical contamination in subsurface water bearing geological formations

• US 6,001,769 A
• Filed: 09/25/1997
• Issued: 12/14/1999
• Est. Priority Date: 09/25/1997
• Status: Expired due to Fees

• Current Assignee: Correctivation LLC
• Original Assignee: Correctivation LLC
• Inventors: Kumar, Sam, Citterbart, John Michael
• Primary Examiner(s): Niebling, John F.
• Assistant Examiner(s): Ghyka, Alexander G.
• Application Number:
  US08/937,938
• Time in Patent Office: 810 Days
• Field of Search: 502/400, 502/401, 502/416, 502/417, 502/437, 502/512, 210/691
• US Class Current: 502/437
• CPC Class Codes: B09C 1/002 involving in-situ ground water treatment
• CPC Class Codes: B09C 1/02 Extraction using liquids, e.g. washing, leaching , flotation
• CPC Class Codes: C02F 1/683 by addition of complex-forming compounds
• CPC Class Codes: Y10S 502/512 Carboxylic acid or salt thereof other than formic, acetic, or oxalic acid

Abstract

Compositions and methods for decreasing chemical contamination in subsurface water bearing geological formations, comprising an oxidized form of lignitic coal, or its derivatives, preferably leonardite, and at least one surface active agent. The compositions can be applied to an affected water bearing formation by conventional groundwater management methods, e.g., injection wells and groundwater extraction systems.

Claims

1. A composition for decreasing chemical contamination in subsurface water bearing geological formations, comprising:

the soluble eluting materials of an oxidized form of lignitic coal; and

at least one surface active agent in concentrations sufficient to complex with a chemical contaminant in a subsurface water bearing geological formation, and water, wherein the insoluble inert substances of the oxidized form of lignitic coal are excluded from said composition.

2. The composition of claim 1, wherein the surface active agent is a cationic surfactant.

3. The composition of claim 1, wherein the surface active agent is an anionic surfactant.

4. The composition of claim 1, wherein the surface active agent is an amphoteric surfactant.

5. The composition of claim 1, wherein the surface active agent is a nonionic surfactant.

37. The compositions of claims 1, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31 or 32, wherein the concentration of the soluble eluting materials of the oxidized form of lignitic coal component ranges from about 1% to about 40% (by weight of the total composition), the concentration of the surface active agent component ranges from about 0.5% to about 20% (by weight of the total composition), and the balance of the composition is water.

38. The composition of claim 37, wherein multiple surface active agents are utilized, wherein each surface active agent is added in an amount so that the total weight percent of the surface active agent component ranges from about 0.5% to about 20% (by weight of the total composition).

39. The composition of claim 37, wherein the oxidized form of lignitic coal is leonardite.

40. The composition of claim 37, wherein the soluble eluting, materials of the oxidized form of lignitic coal in a composition is a water soluble derivative altered by chemical or biological means.

41. The composition of claim 37, wherein the pH range of the composition is about pH 4 to about pH 10.

42. The compositions of claims 1, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31 or 32, wherein the concentration of the soluble eluting materials of the oxidized form of lignitic coal component ranges from about 10% to about 25% (by weight of the total composition), the concentration of surface active agent component ranges from about 5% to about 15% (by weight of the total composition), and the balance of the composition is water.

43. The composition of claim 42, wherein multiple surface active agents are utilized, wherein each surface active agent is added in an amount so that the total weight percent of the surface active agent component ranges from about 5% to about 15% (by weight of the total composition).

44. The composition of claim 42, wherein the oxidized form of lignitic coal is leonardite.

45. The composition of claim 42, wherein the soluble eluting materials of the oxidized form of lignitic coal in a composition is a water soluble derivative altered by chemical or biological means.

46. The composition of claim 42, wherein the pH range of the composition is about pH 4 to about pH10.

51. The compositions of claims 1, 4, 5, 8, 9, 16, 17, 26, or 32, wherein the pH range of the composition is about pH 4 to about pH 10.

74. The composition of claims 1, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 47, 48, 52, 54, 19, 56, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30 31 or 32, further comprising at least one hydroxylic solvent having the general formula R--OH, where R═

C_n H.sub.(2n+1), where n=1 to 10 in an amount sufficient to solubilize the surface active agent utilized.

75. The composition of claim 74, wherein n=1 to 2.

76. The composition of claim 74, wherein n=2.

77. The composition of claim 37, further comprising at least one hydroxylic solvent having the general formula R--OH, where R═

C_n H.sub.(2n+1), where n=1 to 10 in an amount sufficient to solubilize the surface active agent utilized.

78. The composition of claim 77, wherein n=1 to 2.

79. The composition of claim 77, wherein n=2.

80. The composition of claim 42, further comprising at least one hydroxylic solvent having the general formula R--OH, where R═

C_n H.sub.(2n+1), where n=1 to 10 in an amount sufficient to solubilize the surface active agent utilized.

81. The composition of claim 80, wherein n=1 to 2.

82. The composition of claim 80, wherein n=2.

83. The compositions of claims 1, 6, 7, 8, 10, 11, 12, 13, 14, 15, 16, 17, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31 or 32, wherein the oxidized form of lignitic coal is leonardite.

84. The compositions of claims 1, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31 or 32, wherein the soluble eluting materials of the oxidized form of lignitic coal in a composition is a water soluble derivative altered by chemical or biological means.

6. A composition for decreasing chemical contamination in subsurface water bearing geological formations, comprising:

the soluble eluting materials of an oxidized form of lignitic coal; and

at least one cationic surface active agent in concentrations sufficient to complex with a chemical contaminant in a subsurface water bearing geological formation, and water, wherein the insoluble inert substances of the oxidized form of lignitic coal are excluded from said composition.

7. A composition for decreasing chemical contamination in subsurface water bearing geological formations, comprising:

the soluble eluting materials of an oxidized form of lignitic coal; and

at least one anionic surface active agent in concentrations sufficient to complex with a chemical contaminant in a subsurface water bearing geological formation, and water, wherein the insoluble inert substances of the oxidize form of lignitic coal are excluded from said composition.

8. A composition for decreasing chemical contamination in subsurface water bearing geological formations, comprising:

the soluble eluting materials of an oxidized form of lignitic coal; and

at least one amphoteric surface active agent in concentrations sufficient to complex with a chemical contaminant in a subsurface water bearing geological formation, and water, wherein the insoluble inert substances of the oxidized form of lignitic coal are excluded from said composition.

9. A composition for decreasing chemical contamination in subsurface water bearing geological formations, comprising:

the soluble eluling materials of an oxidized form of lignitic coal; and

at least one nonionic surface active agent in concentrations sufficient to complex with a chemical contaminant in a subsurface water bearing geological formation, and water, wherein the insoluble inert substances of the oxidized form of lignitic coal are excluded from said composition.

10. A composition for decreasing chemical contamination in subsurface water bearing geological formations, comprising:

an oxidized form of lignitic coal; and

at least one cationic surface active agent; and

at least one amphotcric surface active agent in concentrations sufficient to complex with a chemical contaminant in a subsurface water bearing geological formation, and water.

35. The compositions of claims 2, 6, 10, 11, 12, 21, 22, 27 or 28, wherein the pH range of the composition is about pH 4 to about pH 7.

11. A composition for decreasing chemical contamination in subsurface water bearing geological formations, comprising:

the soluble eluting materials of an oxidized form of lignitic coal; and

at least one cationic surface active agent; and

at least one nonionic surface active agent in concentrations sufficient to complex with a chemical contaminant in a subsurface water bearing geological formation, and water, wherein the insoluble inert substances of the oxidized form of lignitic coal are excluded from said composition.

72. The compositions of claims 9, 11, 12, 14, 15, 16, 22, 24, 25, 26, 28, 30 31 or 32, wherein the nonionic surface active agent is selected from a group of naturally occurring surfactants consisting of:

xanthan gum, bluran, dextran, agar, galaginan, phaseleran, alginates, locust bean gum, guar gum, fatsia gum, gum arabica, karaya gum, tragacanth, pectin, processed starch, gelatin and casein.

12. A composition for decreasing chemical contamination in subsurface water bearing geological formations, comprising:

an oxidized form of lignitic coal; and

at least one cationic surface active agent; and

at least one amphoteric surface active agent; and

at least one nonionic surface active agent in concentrations sufficient to complex with a chemical contaminant in a subsurface water bearing geological formation, and water.

13. A composition for decreasing chemical contamination in subsurface water bearing geological formations, comprising:

an oxidized form of lignitic coal; and

at least one anionic surface active agent; and

at least one amphoteric surface active agent in concentrations sufficient to complex with a chemical contaminant in a subsurface water bearing geological formation, and water.

36. The compositions of claims 3, 7, 13, 14, 15, 23, 24, 25, 29, 30 or 31, wherein the pH range of the composition is about pH 7 to about pH 10.

14. A composition for decreasing chemical contamination in subsurface water bearing geological formations, comprising:

an oxidized form of lignitic coal; and

at least one anionic surface active agent; and

at least one nonionic surface active agent in concentrations sufficient to complex with a chemical contaminant in a subsurface water bearing geological fornation, and water.

15. A composition for decreasing chemical contamination in subsurface water bearing geological formations, comprising:

an oxidized form of lignitic coal; and

at least one anionic surface active agent; and

at least one amphoteric surface active agent; and

at least one nonionic surface active agent in concentrations sufficient to complex with a chemical contaminant in a subsurface water bearing geological formation, and water.

16. A composition for decreasing chemical contamination in subsurface water bearing geological formations, comprising:

an oxidized form of lignitic coal; and

at least one amphoteric surface active agent; and

at least one nonionic surface active agent in concentrations sufficient to complex with a chemical contaminant in a subsurface water bearing geological formation, and water.

17. A composition for decreasing chemical contamination in subsurface water bearing geological formations, comprising;

the soluble eluting materials of an oxidized form of lignitic coal in a concentration sufficient to complex with a chemical contaminant in a subsurface water bearing geological formation, and water, wherein the insoluble inert substances of the oxidized form of lignitic coal are excluded from said composition.

47. The composition of claim 17, wherein the concentration of the soluble eluting materials of the oxidized form of lignitic coal component ranges from about 1% to about 40% (by weight of the total composition), and the balance of the composition is water.

48. The composition of claim 17, wherein the concentration of the soluble eluting materials of the oxidized form of lignitic coal component ranges from about 10% to about 25% (by weight of the total composition), and the balance of the composition is water.

49. The compositions of claims 47 or 48, wherein the oxidized form of lignitic coal is leonardite.

50. The compositions of claims 47 or 48, wherein the soluble eluting materials of the oxidized form of lignitic coal in a composition is a water soluble derivative altered by chemical or biological means.

18. A method for preparing a composition for decreasing chemical contamination in subsurface water bearing geological formations, comprising the steps of:

(a) pretreating the oxidized form of lignitic coal having soluble eluting materials and insoluble inert substances in a caustic solution at a pH greater than 10.0 at ambient temperature to dissolve the eluting materials;

(b) removing the insoluble inert substances from the solution;

(c) adjusting the concentration of the oxidized form of lignitic coal in the solution by dilution using a hydroxylic solvent with the general formula R--OH, where R═

C_n H.sub.(2n+1), where n=0 to 10;

(d) adjusting the pH of the solution from about pH 4 to about pH 10 using an inorganic acid, organic acid or reducing agent; and

(e) adding at least one surface active agent in a concentration sufficient to complex with a chemical contaminant in a subsurface water bearing geological formation.

57. The methods of claims 18 or 20, wherein the pretreatment step is carried out for about 24 to about 48 hours.

58. The methods of claims 18 or 20, wherein n=0 to 2.

59. The methods of claims 18 or 20, wherein n=0.

60. The methods of claims 18 or 20, wherein the reducing agent is a monovalent sulfite compound or bivalent sulfite compound.

61. The method of claim 60, wherein the bivalent sulfite compound is magnesium sulfite or calcium sulfite.

62. The method of claim 60, wherein the monovalent sulfite compound is sodium bisulfite or potassium bisulfite.

63. The methods of claims 18 or 20, further comprising the step of adjusting the viscosity of the solution using a hydroxylic solvent with the general formula R--OH, where R═

C_n H.sub.(2n+1), where n=0 to 10, prior to removal of the insoluble inert substances.

64. The method of claim 63, wherein n=0 to 2.

65. The method of claim 63, wherein n=0.

66. The methods of claims 52, 54, 18, 19, 56 or 20, wherein the oxidized form of lignitic coal in a composition is leonardite.

67. The methods of claims 52, 54, 18, 19, 56 or 20, wherein the oxidized form of lignitic coal in a composition is a water soluble derivative altered by chemical or biological means.

69. The method of claim 18, further comprising the step (f) of adding a hydroxylic solvent with the general formula R--OH, where R═

C_n H.sub.(2n+1) and where n=1 to 10, in an amount sufficient to solubilize the surface active agent utilized.

70. The method of claim 69, wherein n=1 to 2.

71. The method of claim 69, wherein n=2.

73. The methods of claims 52, 54, 18, 19 or 56, wherein the soluble eluting materials of the oxidized form of lignitic coal in a composition is a water soluble derivative altered by chemical or biological means.

19. A method for preparing a composition for decreasing chemical contamination in subsurface water bearing geological formations comprising the steps of:

combining the soluble eluting materials an oxidized form of lignitic coal in a concentration sufficient to complex with a chemical contaminant in a subsurface water bearing geological formation, and water, wherein the insoluble inert substances of the oxidized form of lignitic coal are excluded from said composition, wherein the concentration of the soluble eluting materials of the oxidized form of lignitic coal component ranges from about 1% to about 40% (by weight of the total composition), and the balance of the composition is water.

56. The method of claim 19, wherein the concentration of the soluble eluting materials of the oxidized form of lignitic coal component ranges from about 10% to about 25% (by weight of the total composition), and the balance of the composition is water.

68. The methods of claims 52, 54, 19, or 56 wherein said method is carried out at a pH range of about pH 4 to about pH 10.

20. A method for preparing compositions for decreasing chemical contamination in subsurface water bearing geological formations, comprising the steps of:

(a) pretreating the oxidized form of lignitic coal having soluble eluting materials and insoluble inert substances in a caustic solution at a pH greater than 10.0 at ambient temperature to dissolve the eluting materials;

(b) removing the insoluble inert substances from the solution;

(c) adjusting the concentration of the oxidized form of lignitic coal in the solution by dilution using a hydroxylic solvent with the general formula R--OH, where R═

C_n H.sub.(2n+1), where n=0 to 10; and

(d) adjusting the pH of the solution from about pH 4 to about pH 10 using an inorganic or organic acid or reducing agent.

21. A composition for decreasing chemical contamination in subsurface water bearing geological formations, comprising:

the soluble eluting materials of an oxidized form of lignitic coal; and

at least one cationic surface active agent; and

at least one amphoteric surface active agent;

in concentrations sufficient to complex with a chemical containmant in a subsurface water bearing geological formation, and water.

33. The compositions of claims 21, 22, 23, 25, 26, 27, 28, 29, 31 or 32, wherein the amphoteric surface active agent is a phosphotidyl choline compound.

34. The composition of claim 33, wherein the phosphotidyl choline compound is lecithin.

22. A composition for decreasing chemical contamination in subsurface water bearing geological formations, comprising:

the soluble eluting materials of an oxidized form of lignitic coal; and

at least one cationic surface active agent; and

at least one amphoteric surface active agent; and

at least one nonionic surface active agent in concentrations sufficient to complex with a chemical contaminant in a subsurface water bearing geological formation, and water.

23. A composition for decreasing chemical contamination in subsurface water bearing geological formations, comprising:

the soluble eluting materials of an oxidized form of lignitic coal; and

at least one anionic surface active agent; and

at least one amphoteric surface active agent in concentrations sufficient to complex with a chemical contaminant in a subsurface water bearing geological formation, and water.

24. A composition for decreasing chemical contamination in subsurface water bearing geological formations, comprising:

the soluble eluting materials of an oxidized form of lignitic coal; and

at least one anionic surface active agent; and

at least one nonionic surface active agent in concentrations sufficient to complex with a chemical contaminant in a subsurface water bearing geological formation, and water.

25. A composition for decreasing chemical contamination in subsurface water bearing geological formations, comprising:

the soluble eluting materials of an oxidized form of lignitic coal; and

at least one anionic surface active agent; and

at least one amphoteric surface active agent; and

at least one nonionic surface active agent in concentrations sufficient to complex with a chemical contaminant in a subsurface water bearing geological formation, and water.

26. A composition for decreasing chemical contamination in subsurface water bearing geological formations, comprising;

the soluble eluting materials of an oxidized form of lignitic coal; and

at least one amphoteric surface active agent; and

at least one nonionic surface active agent in concentrations sufficient to complex with a chemical contaminant in a subsurface water bearing gcological formation, and water.

27. A composition for decreasing chemical contamination in subsurface water bearing geological formations, comprising:

the soluble eluting materials of an oxidized form of lignitic coal;

arid at least one cationic surface active agent; and

at least one amphoteric surface active agent in concentrations sufficient to complex with a chemical contaminant in a subsurface water bearing geological formation, and water, wherein the insoluble inert substances of the oxidized form of lignitic coal are excluded from said composition.

28. A composition for decreasing chemical contamination in subsurface water bearing geological formations, comprising:

the soluble eluting materials of an oxidized form of lignitic coal; and

at least one cationic surface active agent; and

at least one amphoteric surface active agent; and

at least one nonionic surface active agent in concentrations sufficient to complex with a chemical contaminant in a subsurface water bearing geological formation, and water, wherein the insoluble inert substances of the oxidized form of lignitic coal are excluded from said composition.

29. A composition for decreasing chemical contamination in subsurface water bearing geological formations, comprising:

the soluble eluting materials of an oxidized form of lignitic coal; and

at least one anionic surface active agent; and

at least one amphoteric surface active agent in concentrations sufficient to complex with a chemical contaminant in a subsurface water bearing geological formation, and water, wherein the insoluble inert substances of the oxidized form of lignitic coal are excluded from said composition.

30. A composition for decreasing chemical contamination in subsurface water bearing geological formations, comprising:

the soluble eluting materials of an oxidized form of lignitic coal; and

at least one anionic surface active agent; and

at least one nonionic surface active agent in concentrations sufficient to complex with a chemical contaminant in a subsurface water bearing geological formation, and water, wherein the insoluble inert substances of the oxidized form of lignitic coal are excluded from said composition.

31. A composition for decreasing chemical contamination in subsurface water bearing geological formations, comprising:

the soluble eluting materials of an oxidized form of lignitic coal; and

at least one anionic surface active agent, and at least one amphoteric surface active agent; and

at least one nonionic surface active agent in concentrations sufficient to complex with a chemical contaminant in a subsurface water bearing geological formation, and water, wherein the insoluble inert substances of the oxidized form of lignitic coal are excluded from said composition.

32. A composition for decreasing chemical contamination in subsurface water bearing geological formations, comprising:

the soluble eluting materials of an oxidized form of lignitic coal; and

at least one amphoteric surface active agent; and

at least one nonionic surface active agent in concentrations sufficient to complex with a chemical contaminant in a subsurface water bearing geological formation, and water, wherein the insoluble inert substances of the oxidized form of lignitic coal are excluded from said composition.

52. A method for preparing a composition for decreasing chemical contamination in subsurface water bearing geological formations comprising the steps of:

combining the soluble eluting materials of an oxidized form of lignitic coal, and at least one surface active agent in concentrations sufficient to complex with a chemical contaminant in a subsurface water bearing gcological formation, and water, wherein the insoluble inert substances of the oxidized form of lignitic coal are excluded from said composition, wherein the concentration of the soluble eluting materials of the oxidized form of lignitic coal component ranges from about 1% to about 40% (by weight of the total composition), the concentration of surface active agent component ranges from about 0.5% to about 20% (by weight of the total composition), and the balance of the composition is water.

53. The method of claim 52, wherein multiple surface active agents are utilized, wherein each surface active agent is added in an amount so that the total weight percent of the surface active agent component ranges from about 0.5% to about 20% (by weight of the total composition).

54. The method of claim 52, wherein the concentration of the soluble eluting materials of the oxidized form of lignitic coal component ranges from about 10% to about 25% (by weight of the total composition), the concentration of surface active agent component ranges from about 5% to about 15% (by weight of the total composition), and the balance of the composition is water.

55. The method of claim 54, wherein multiple surface active agents are utilized, wherein each surface active agent is added in an amount so that the total weight percent of the surface active agent component ranges from about 5% to about 15% (by weight of the total composition).