Golf ball forming compositions comprising polyamide blended with sulfonated or phosphonated polymers

• US 6,001,930 A
• Filed: 12/22/1997
• Issued: 12/14/1999
• Est. Priority Date: 03/13/1997
• Status: Expired due to Term

• Current Assignee: Acushnet Company (FILA Holdings Corp.)
• Original Assignee: Acushnet Company (FILA Holdings Corp.)
• Inventors: Rajagopalan, Murali
• Primary Examiner(s): BUTTNER, DAVID J
• Application Number:
  US08/996,403
• Time in Patent Office: 722 Days
• Field of Search: 473/354, 473/365, 473/374, 473/377, 473/378, 473/385, 528/321, 525/92 B, 525/178, 525/179, 525/183, 525/184, 525/424, 525/425, 525/432, 525/433, 525/420
• US Class Current: 525/92.00B
• CPC Class Codes: A63B 37/0003 Golf balls
• CPC Class Codes: A63B 37/0086 Flexural modulus; Bending stiffness
• CPC Class Codes: C08L 23/08 Copolymers of ethene C08L23/16 takes precedence
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 2666/08 Homopolymers or copolymers according to C08L7/00 - C08L21/00; Derivatives thereof
• CPC Class Codes: C08L 2666/14 Macromolecular compounds according to C08L59/00 - C08L87/00; Derivatives thereof
• CPC Class Codes: C08L 2666/18 Polyesters or polycarbonates according to C08L67/00 - C08L69/00; Derivatives thereof
• CPC Class Codes: C08L 2666/20 Macromolecular compounds having nitrogen in the main chain according to C08L75/00 - C08L79/00; Derivatives thereof
• CPC Class Codes: C08L 53/00 Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 67/025 containing polyether sequences
• CPC Class Codes: C08L 75/04 Polyurethanes
• CPC Class Codes: C08L 77/00 Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain of polyhydrazides C08L79/06; of polyamideimides or polyamide acids C08L79/08; Compositions of derivatives of such polymers

Abstract

The present invention relates to a golf ball, comprising a cover, a core and optional intermediate layers, wherein the various ball components are formed from compositions comprising a polyamide, in the form of a homopolymer, a copolymer or mixtures thereof. The compositions include a blend of about 1 wt. % to about 99 wt. % of at least one sulfonated and/or phosphonated polymer and about 99 wt. % to about 1 wt. % of at least one polyamide polymer. The polyamides of the present invention comprise polyamides and polyamide copolymers, such as polyamide block copolymers. The sulfonated and/or phosphonated polymer preferably comprises sulfonated thermoplastic elastomers, sulfonated thermoplastic polymers, and mixtures thereof. The present invention is further directed to a method of making a golf ball core, an intermediate layer or a cover composition, comprising blending one or more sulfonated and/or phosphonated polymers and one or more polyamides or polyamide copolymers such that there is mixing of the different polymeric components to give a blend suitable for forming into the above golf ball components.

Claims

1. A golf ball comprising a cover and a core, wherein the cover is formed of a composition which comprises a blend of from about 1 wt. % to about 99 wt. % of at least one polyamide polymer and from about 99 wt. % to about 1 wt. % of at least one sulfonated and/or phosphonated polymer selected from the group consisting of sulfonated polymers, phosphonated polymers, sulfonated and phosphonated polymers, and mixtures thereof.

2. The golf ball of claim 1, wherein the polyamide polymer has a flexural modulus of from about 30,000 psi to about 500,000 psi.

3. The golf ball of claim 1, wherein the polyamide polymer is selected from the group consisting of polyamide homopolymers, polyamide copolymers and mixtures thereof.

4. The golf ball of claim 3, wherein the polyamide homopolymer is selected from the group consisting of polyamide 6, polyamide 11, polyamide 12, polyamide 4,6, polyamide 6,6, polyamide 6,9, polyamide 6,10, polyamide 6,12 and mixtures thereof.

5. The golf ball of claim 3, wherein the polyamide copolymer is selected from the group consisting of polyamide 6/6,6, polyamide 6,6/6,10, polyamide 6/6,T, polyamide 6/6,6/6,10 and mixtures thereof.

6. The golf ball of claim 1, wherein the sulfonated and/or phosphonated polymer is a sulfonated polymer selected from the group consisting of sulfonated thermoplastic elastomers, sulfonated thermoplastic polymers, and mixtures thereof.

7. The golf ball of claim 6, wherein the sulfonated polymer contains from about 0.1 mol % to about 30 mol % sulfonate groups.

8. The golf ball of claim 6, wherein the sulfonated polymer comprises sulfonate groups present in the form of a sulfonic acid, a sulfonamide, or mixtures thereof.

9. The golf ball of claim 6, wherein the sulfonated thermoplastic elastomer has a flexural modulus of from about 1,000 psi to about 150,000 psi.

10. The golf ball of claim 9, wherein the sulfonated thermoplastic elastomer is a block copoly(ester-ester), a block copoly(ester-ether), a block copoly(amide-ester), a block copoly(amide-ether), a block copoly(urethane-ester), a block copoly(urethane-ether), a block polystyrene thermoplastic elastomer comprising an unsaturated rubber, a block polystyrene thermoplastic elastomer comprising a functionalized substantially saturated rubber, an unvulcanized thermoplastic and elastomer blend comprising polypropylene and ethylene-propylene-diene monomer terpolymer or ethylene-propylene copolymer rubber, a thermoplastic and elastomer blend comprising polypropylene and ethylene-propylene-diene monomer terpolymer or ethylene-propylene copolymer rubber wherein the rubber is dynamically vulcanized, a melt-bondable thermoplastic and elastomer blend wherein the rubber is dynamically vulcanized, or mixtures thereof.

11. The golf ball of claim 6, wherein the sulfonated thermoplastic polymer has a flexural modulus of from about 30,000 psi to about 500,000 psi.

12. The golf ball of claim 11, wherein the sulfonated thermoplastic polymer is a polyolefin, a polyester, a polyamide, a polycarbonate, a polyphenylene oxide, a polyether ketone, a polysulfone, a poly(phenylene sulfide), poly(ether imide), a reinforced engineering plastic, a polymer comprising styrene, or mixtures thereof.

13. The golf ball of claim 1, wherein said composition is substantially free of optical brightener.

14. The golf ball of claim 1, wherein the composition further comprises from about 90% to about 1% by weight of a co-component polymer and wherein said blend is present in an amount of from about 10% to about 99% by weight.

15. The golf ball of claim 14, wherein the co-component polymer is selected from the group consisting of thermoplastic elastomers, thermoplastic polymers, and mixtures thereof.

16. The golf ball of claim 15, wherein the thermoplastic elastomer is selected from the group consisting of a block copoly(ester-ester), a block copoly(ester-ether), a block copoly(amide-ester), a block copoly(amide-ether), a block copoly(urethane-ester), a block copoly(urethane-ether), a block polystyrene thermoplastic elastomer comprising an unsaturated rubber, a block polystyrene thermoplastic elastomer comprising a functionalized substantially saturated rubber, an unvulcanized thermoplastic and elastomer blend comprising polypropylene and ethylene-propylene-diene monomer terpolymer or ethylene-propylene copolymer rubber, a thermoplastic and elastomer blend comprising polypropylene and ethylene-propylene-diene monomer terpolymer or ethylene-propylene copolymer rubber wherein the rubber is dynamically vulcanized, a melt-bondable thermoplastic and elastomer blend wherein the rubber is dynamically vulcanized, or mixtures thereof.

17. The golf ball of claim 15, wherein the thermoplastic polymer is selected from the group consisting of poly(amide), poly(ethylene terephthalate), poly(butylene terephthalate), poly(trimethylene terephthalate), poly(ethylene naphthalate), poly(vinyl alcohol), poly(vinyl acetate), poly(silane), poly(vinylidene fluoride), acrylonitrile-butadiene-styrene copolymer, their copolymers, and mixtures thereof.

18. The golf ball of claim 15, wherein the thermoplastic polymer comprises at least one olefinic polymer.

19. A golf ball comprising a cover layer, a core layer and at least one intermediate layer interposed between the cover layer and the core layer, wherein at least one of said layers comprises a composition which comprises a blend of from about 1 wt. % to about 99 wt. % of at least one sulfonated and/or phosphonated polymer and from about 99 wt. % to about 1 wt. % of at least one polyamide polymer.

20. The golf ball of claim 19, wherein the polyamide polymer has a flexural modulus of from about 30,000 psi to about 500,000 psi.

21. The golf ball of claim 19, wherein the polyamide polymer is selected from the group consisting of polyamide homopolymers, polyamide copolymers and mixtures thereof.

22. The golf ball of claim 19, wherein the intermediate layer is comprised of said composition and wherein the cover layer comprises at least one material selected from the group consisting of nonionic olefinic polymers, polyolefin ionomers, styrene-butadiene-styrene ionomers, styrene-(hydrogenated butadiene)-styrene ionomers, poly(isoprene) which is at least partially crosslinked, poly(butadiene) which is at least partially crosslinked, a thermoset poly(urethane), and a thermoset poly(urea).

23. The golf ball of claim 19, wherein at least one intermediate layer is a wound layer.

24. The golf ball of claim 19, wherein the core layer comprises a liquid or solid center wrapped in elastomeric windings.

25. The golf ball of claim 19, wherein the sulfonated and/or phosphonated polymer is a sulfonated polymer selected from the group consisting of sulfonated thermoplastic elastomers, sulfonated thermoplastic polymers, and mixtures thereof.

26. The golf ball of claim 25, wherein the sulfonated thermoplastic elastomer has a flexural modulus of from about 1,000 psi to about 150,000 psi.

27. The golf ball of claim 25, wherein the sulfonated thermoplastic polymer has a flexural modulus of from about 30,000 psi to about 500,000 psi.

28. The golf ball of claim 25, wherein the sulfonated polymer contains from about 0.1 mol % to about 30 mol % sulfonate groups.

29. The golf ball of claim 19, wherein the composition further comprises from about 90% to about 1% by weight of a co-component polymer and wherein said blend is present in an amount of from about 10% to about 99% by weight.

30. A golf ball comprising a cover layer, a core layer and at least one intermediate layer interposed between the cover layer and the core layer, wherein at least one of said layers comprises a composition which comprises a polyamide selected from the group consisting of a sulfonated polyamide, a phosphonated polyamide, a sulfonated and phosphonated polyamide, and mixtures thereof.

31. The golf ball of claim 30, wherein the polyamide comprises an aromatic group.

32. The golf ball of claim 30, wherein the aromatic group is present in the form of a monomer used to form the polyamide, and wherein the monomer is selected from the group consisting of m-phenylenediamine, p-phenylenediamine, m-xylylenediamine, isophthalic acid, terephthalic acid, 2,6-naphthalenedicarboxylic acid and mixtures thereof.

33. The golf ball of claim 31, wherein the polyamide is selected from the group consisting of PA-6,T/6,6, PA-6,T/6,I/6,6, PA-6,T/6, PA-6,T/6,I, PA-6,T/6,6, and mixtures thereof.

34. The golf ball of claim 30, wherein the polyamide is a sulfonated polyamide, and wherein the sulfonated polyamide has a flexural modulus of from about 30,000 psi to about 500,000 psi.

35. The golf ball of claim 34, wherein the sulfonated polyamide contains from about 0.1 mol % to about 30 mol % sulfonate groups.

36. The golf ball of claim 30, wherein the composition further comprises from about 90% to about 1% by weight of a co-component polymer and wherein said polyamide is present in an amount of from about 10% to about 99% by weight.

37. A method of making a golf ball, comprising:

forming a core layer;

forming at least one intermediate layer about the core layer; and

forming a cover layer over said at least one intermediate layer;

wherein at least one of said layers is formed of a composition comprising a blend of from about 1 wt. % to about 99 wt. % of at least one polyamide polymer and from about 99 wt. % to about 1 wt. % of at least one sulfonated and/or phosphonated polymer.

38. A method of making a golf ball, comprising:

forming a core layer;

forming at least one intermediate layer about the core layer; and

forming a cover layer over said at least one intermediate layer;

wherein at least one of said layers is formed of a polyamide selected from the group consisting of a sulfonated polyamide, a phosphonated polyamide, a sulfonated and phosphonated polyamide, and mixtures thereof.