Polymer dispersed liquid crystal (PDLC) film using heat or an electric field to change state and the other to change back

• US 6,002,383 A
• Filed: 03/28/1996
• Issued: 12/14/1999
• Est. Priority Date: 03/30/1995
• Status: Expired due to Fees

• Current Assignee: Dai Nippon Printing Company Limited
• Original Assignee: Dai Nippon Printing Company Limited
• Inventors: Shimada, Naoki
• Primary Examiner(s): Brier, Jeffery
• Assistant Examiner(s): Bell, Paul A.
• Application Number:
  US08/624,316
• Time in Patent Office: 1,356 Days
• Field of Search: 345/87, 345/105, 345/106, 349/86, 349/70, 349/19, 349/20, 349/21, 349/22, 347/171, 347/179, 428/1, 430/20, 252/299.01, 359/490, 359/491, 346/76.1, 257/679, 257/922, 902/26, 235/380, 235/381, 235/382, 235/382.5
• US Class Current: 345/87
• CPC Class Codes: G02F 1/132 Thermal activation of liquid crystals exhibiting a thermo-optic effect
• CPC Class Codes: G06K 1/128 by electric registration, e.g. electrolytic, spark erosion recording apparatus for measuring instruments G01D15/06; information storage in general G11
• CPC Class Codes: G06K 19/07703 the interface being visual
• CPC Class Codes: G06K 19/07749 the record carrier being capable of non-contact communication, e.g. constructional details of the antenna of a non-contact smart card
• CPC Class Codes: G06K 19/07779 the inductive antenna being a coil
• CPC Class Codes: G06K 19/08 using markings of different kinds or more than one marking of the same kind in the same record carrier, e.g. one marking being sensed by optical and the other by magnetic means
• CPC Class Codes: G09F 3/02 Forms or constructions layered products B32B

Abstract

There is disclosed an information displaying medium having a base member and a writable displaying unit disposed thereon. The writable displaying unit has a reversible displaying element including a polymer/liquid crystal composite film. A processing means including a control means and an information recording unit is buried in the base member and functions as a semiconductor device. A communication means is buried in the base member for exchanging signals with an external apparatus.

Claims

1. An information displaying medium comprising:

a base member;

a semiconductor information recording unit buried in the base member;

a writable displaying unit formed on the base member and permitting repeated recording and erasing of visible information; and

a communication means buried in the base member, connected to the semiconductor information recording unit and capable of exchanging signals by radio with an external apparatus;

wherein the writable displaying unit is provided with a reversible display element that is changed from either of a recording state and an erased state to the other by the agency of an electric field and from the latter state to the former state by the agency of heat.

2. An information displaying medium according to claim 1, wherein

the semiconductor information recording unit and the communication means are buried in the base member so that the semiconductor information recording unit and the communication means are not exposed.

3. An information displaying medium according to claim 1, wherein

the visible information to be written to the writable displaying unit is characters or patterns.

4. An information displaying medium according to claim 1, wherein

the visible information to be written to the writable displaying unit is mechanically readable information.

5. An information displaying medium according to claim 1, wherein

the reversible displaying element is changed from a recorded state to a erased state by the agency of an electric field.

6. An information displaying medium comprising:

a base member;

a semiconductor information recording unit buried in the base member; and

a writable displaying unit formed on the base member and permitting repeated recording and erasing of visible information, the writable displaying unit being provided with a reversible display element that is changed from either a recording state and an erased state to the other by the agency of an electric field and from the latter state to the former state by the agency of heat;

wherein the writable displaying unit is disposed in a recess formed in the base member so that the surface of the writable displaying unit is flush with or lies slightly above the surface of the base member.

7. An information displaying medium according to claim 6, wherein

the height of the surface of the writable displaying unit from the surface of the base member is in the range of 0 to 0.5 mm.

8. An information displaying medium comprising:

a base member; and

a writable displaying unit formed on the base member and permitting repeated recording and erasing of visible information;

wherein

(1) the writable displaying unit is provided with a reversible displaying element that is changed from either of a recording state and an erased state to the other by the agency of an electric field and from latter state to the former state by the agency of heat, and

(2) the reversible displaying element has at least a labeling base sheet formed of a noninsulating material, a writable polymer/liquid crystal composite film formed on an outer side of the base sheet, and an adhesive layer formed on an inner dose of the base sheet so as to be adhesively attached to the base member, the polymer/liquid crystal composite film having a protective layer formed on an outer side thereof.

9. An information displaying medium according to claim 8, wherein

a semiconductor information recording unit is buried in the base member.

10. An information displaying medium according to claim 8, wherein

the labeling base sheet is formed of an insulating material, a conductive layer is interlaid between the labeling base sheet and the polymer/liquid crystal composite film, and a protective film is formed on an outer side of the polymer/liquid crystal composite film.

11. An information displaying medium comprising:

a base member; and

a writable displaying unit formed on the base member and permitting repeated recording and erasing of visible information;

wherein

(1) the writable displaying unit is provided with a reversible displaying element that is changed from either of a recording state and an erased state to the other by the agency of an electric field and from the latter state to the former state by the agency of heat,

(2) the reversible displaying element has at least a labeling base sheet, a writable polymer/liquid crystal composite film formed on an outer side of the base sheet, and an adhesive layer formed on an inner side of the base sheet so as to be adhesively attached to the base member, and

(3) the writable displaying unit is disposed in a recess formed in the base member so that the surface of the writable displaying unit is flush with or lies slightly above the surface of the base member.

12. An information displaying medium according to claim 11, wherein

the height of the surface of the writable displaying unit from the surface of the base member is in the range of 0 to 0.5 mm.

13. An information displaying medium comprising:

a base member; and

a writable displaying unit formed on the base member and permitting repeated recording and erasing of visible information;

wherein

(1) the writable displaying unit is provided with a reversible displaying element that is changed from either of a recording state and an erased state to the other by the agency of an electric field and from the latter state to the former state by the agency of heat;

(2) the reversible displaying element has at least a writable polymer/liquid crystal composite film, and an adhesive layer formed on the inner side of the polymer/liquid crystal composite film to be adhesively attached to the base member;

(3) a conductive layer is interlaid between the polymer/liquid crystal composite film and the adhesive layer; and

(4) the conductive layer is a metal thin film, a metallic foil, a conductive resin or a layer containing a conductive material dispersed in the layer.

14. An information displaying medium comprising:

a base member; and

a writable displaying unit formed on the base member and permitting repeated recording and erasing of visible information;

wherein

(1) the writable displaying unit is provided with a reversible displaying element that is changed from either of a recording state and an erased state to the other by the agency of an electric field and from the latter state to the former state by the agency of heat;

(2) the reversible displaying element has at least a writable polymer/liquid crystal composite film, and an adhesive layer formed on the inner side of the polymer/liquid crystal composite film to be adhesively attached to the base member;

(3) a conductive layer is interlaid between the polymer/liquid crystal composite film and the adhesive layer; and

(4) the polymer/liquid crystal composite film is formed of a water-soluble polymer, and a barrier layer is interlaid between the polymer/liquid crystal composite film and the conductive layer.

15. An information displaying medium according to claim 14, wherein

the barrier layer is formed of a water-soluble polymer.

16. An information displaying medium comprising:

a base member; and

a writable displaying unit formed on the base member and permitting repeated recording and erasing of visible information;

wherein

(1) the writable displaying unit is provided with a reversible displaying element that is changed from either of a recording state and an erased state to the other by the agency of an electric field and from the latter state to the former state by the agency of heat;

(2) the reversible displaying element has at least a writable polymer/liquid crystal composite film, and an adhesive layer formed on the inner side of the polymer/liquid crystal composite film to be adhesively attached to the base member; and

(3) the adhesive layer is formed of an adhesive aqueous emulsion or an adhesive water-soluble polymer.

17. An information displaying medium comprising:

a base member; and

a writable displaying unit formed on the base member and permitting repeated recording and erasing of visible information;

wherein

(1) the writable displaying unit is provided with a reversible displaying element that is changed from either of a recording state and an erased state to the other by the agency of an electric field and from the latter state to the former state by the agency of heat;

(2) the reversible displaying element has at least a writable polymer/liquid crystal composite film, and an adhesive layer formed on the inner side of the polymer/liquid crystal composite film to be adhesively attached to the base member; and

(3) the writable displaying unit is disposed in a recess formed in the base member so that the surface of the writable displaying unit is flush with or lies slightly above the surface of the base member.

18. An information displaying medium according to claim 17, wherein

the height of the surface of the writable displaying unit from the surface of the base member is in the range of 0 to 0.5 mm.

19. A writable displaying labeling sheet comprising:

a labeling base sheet;

a writable polymer/liquid crystal composite film formed on one surface of the labeling base sheet; and

an adhesive layer formed on the other surface of the labeling base sheet;

wherein

the labeling base sheet is formed of an noninsulting material, and a protective layer is formed on an outer surface of the polymer/liquid crystal composite film.

20. A writable displaying transfer sheet comprising:

a removable support member;

a writable polymer/liquid crystal composite film formed on the removable support member; and

an adhesive layer formed on the polymer/liquid crystal composite film;

wherein

(1) a conductive layer is interlaid between the polymer/liquid crystal composite film and the adhesive layer and

(2) the polymer/liquid crystal composite film is formed of a water-soluble polymer, and a barrier layer is interlaid between the polymer/liquid crystal composite film and the conductive layer.

21. A writable displaying transfer sheet according to claim 20, wherein

the barrier layer is formed of a water-soluble polymer.

22. A writable displaying transfer sheet comprising:

a removable support member;

a writable polymer/liquid crystal composite film formed on the removable support layer; and

an adhesive layer formed on the polymer/liquid crystal composite film, wherein the adhesive layer is formed of an adhesive aqueous emulsion or an adhesive water-soluble polymer.

23. An information displaying medium comprising:

a base member;

a semiconductor information recording unit buried in the base member; and

a writable displaying unit formed on the base member and permitting repeated recording and erasing of visible information;

wherein the writable displaying unit is provided with a reversible display element that is changed from either of a recording state and an erased state to the other by the agency of an electric field and from the latter state to the former state by the agency of heat, the reversible display element including a polymer/liquid crystal composite film and the liquid crystal phase of the composite film containing a dichroic dye that assumes a displaying state by a guest-host effect.

24. An information displaying medium according to claim 23, wherein

the reversible displaying element further comprises a conductive layer formed on an inner side of the polymer/liquid crystal composite film, and a protective layer formed on an outer side of the polymer/liquid crystal composite film.