Process cartridge

• US 6,002,895 A
• Filed: 07/15/1997
• Issued: 12/14/1999
• Est. Priority Date: 05/13/1994
• Status: Expired due to Term

• Current Assignee: Canon Kabushiki Kaisha (Canon Inc.)
• Original Assignee: Canon Kabushiki Kaisha (Canon Inc.)
• Inventors: Katada, Masaichiro, Kasuya, Takashige, Kobori, Takakuni, Yusa, Hiroshi, Tomiyama, Koichi, Suematsu, Hiroyuki
• Primary Examiner(s): Rodee, Christopher D.
• Application Number:
  US08/892,913
• Time in Patent Office: 882 Days
• Field of Search: 399/108, 399/111, 430/109, 430/110
• US Class Current: 399/111
• CPC Class Codes: G03G 9/0834 Non-magnetic inorganic compounds chemically incorporated in magnetic components
• CPC Class Codes: G03G 9/08795 characterised by their chemical properties, e.g. acidity, molecular weight, sensitivity to reactants

Abstract

A toner is comprised of a composition containing at least a polymer component and a charge control agent. The polymer component contains substantially no tetrahydrofuran (THF)-insoluble matter. The polymer component THF-soluble has a major peak and a minor peak in the specific molecular weight regions in gel permeation chromatography (GPC). The low molecular weight component and high molecular weight component of the polymer component, each of which shows the specific molecular weight region in GPC, have the specific acid values, respectively. The difference between the acid values is in the specific range.

Claims

1. A process cartridge comprising an electrostatic image bearing member and a developing means for developing an electrostatic image formed on the electrostatic image bearing member, which comprises a toner;

said electrostatic image bearing member and said developing means being held into one unit as a cartridge; and

said process cartridge being detachable from the main body of an image forming apparatus;

wherein;

said toner comprises a composition containing at least a polymer component (A) and a charge control agent,

wherein;

said polymer component (A);

a) contains substantially no tetrahydrofuran-insoluble matter;

b) in a chromatogram in gel permeation chromatography for tetrahydrofuran-soluble matter of said polymer component (A), has a main peak in the region of molecular weight of from 3,000 to 30,000 and a subpeak or a shoulder in the region of molecular weight of from 100,000 to 3,000,000; and

c) has a low-molecular weight polymer component (L) corresponding to the region of molecular weight less than 50,000 in a chromatogram in gel permeation chromatography, having an acid value A_VL of from 21 mg·

KOH/g to 35 mg·

KOH/g, and a high-molecular weight polymer component (H) corresponding to the region of molecular weight not less than 50,000 in the chromatogram in gel permeation chromatography, having an acid value A_VH of from 0.5 mg·

KOH/g to 11 mg·

KOH/g;

said acid values having a difference of 10≦

(A_VL -A_VH)≦

27.

2. The process cartridge according to claim 1, wherein said polymer component has a value of acid value/total acid value, of 0.7 or less.

3. The process cartridge according to claim 1, wherein the tetrahydrofuran-soluble matter of said polymer component has a minimum value in the region of molecular weight of not less than 30,000 to less than 100,000 in its chromatogram in gel permeation chromatography.

4. The process cartridge according to claim 1, wherein said composition has a glass transition temperature Tg of from 50°

C. to 70°

C., and Tg_L of the low-molecular weight polymer component and Tg_H of the high-molecular weight polymer component of said composition are in the relationship within the range of;

Tg_L ≧

Tg_H -5.

5. The process cartridge according to claim 4, wherein said composition has a glass transition temperature Tg of from 55°

C. to 65°

C., and Tg_L of the low-molecular weight polymer component and Tg_H of the high-molecular weight polymer component of said composition are in the relationship within the range of;

Tg_L ≧

Tg_H.

6. The process cartridge according to claim 1, wherein said polymer component satisfies the relationship of:

space="preserve" listing-type="equation">W.sub.L ;

W.sub.H =50;

50 to 90;

10

space="preserve" listing-type="equation">A.sub.VL ×

W.sub.L /(W.sub.L +W.sub.H)≧

A.sub.VH ×

W.sub.H /(W.sub.L +W.sub.H)×

4

space="preserve" listing-type="equation">11≦

(W.sub.L +W.sub.H).sup.-1 (A.sub.VL W.sub.L +A.sub.VH W.sub.H)≦

30

wherein W_L represents a content (% by weight) of the low-molecular weight polymer component;

W_H represents a content (% by weight) of the high-molecular weight polymer component;

A_VL represents an acid value (mg·

KOH/g) of the low-molecular weight polymer component; and

A_VH represents an acid value (mg·

KOH/g) of the high-molecular weight polymer component.

7. The process cartridge according to claim 1, wherein said low-molecular weight polymer component and said high-molecular weight polymer component each contain at least a styrene monomer component unit in an amount not less than 65% by weight.

8. The process cartridge according to claim 1, wherein said high-molecular weight polymer component has a polymer polymerized using a polyfunctional polymerization initiator.

9. The process cartridge according to claim 8, wherein said high-molecular weight polymer component has a polymer polymerized using a polyfunctional polymerization initiator and a monofunctional polymerization initiator in combination.

10. The process cartridge according to claim 1, wherein said composition contains magnetic iron oxide particles, and the magnetic iron oxide particles contain silicon element.

11. The process cartridge according to claim 10, wherein said magnetic iron oxide particles have a silicon element content of from 0.1% by weight to 2.0% by weight based on the weight of iron element.

12. The process cartridge according to claim 10 or 11, wherein said magnetic iron oxide particles have a silicon oxide on their surfaces in an amount of from 0.01% by weight to 1.00% by weight in terms of SiO₂.

13. The process cartridge according to claim 10, wherein said magnetic iron oxide particles have a smoothness of from 0.3 to 0.8.

14. The process cartridge according to claim 10 or 13, wherein said magnetic iron oxide particles have a bulk density of 0.8 g/cm³ or more.

15. The process cartridge according to claim 10 or 13, wherein said magnetic iron oxide particles have a BET specific surface area of 15.0 m² /g or less.

16. The process cartridge according to claim 10 or 11, wherein said magnetic iron oxide particles have been treated with an aluminum hydroxide used in an amount of from 0.01% by weight to 2.0% by weight in terms of aluminum element.

17. The process cartridge according to claim 10 or 13, wherein said magnetic iron oxide particles have a total pore volume of from 7.0×

10^-3 ml/g to 15.0×

10^-3 ml/g.

18. The process cartridge according to claim 1, wherein said charge control agent is a compound represented by the formula:

##STR18## wherein X₁ and X₂ each represent a hydrogen atom, a lower alkyl group, a lower alkoxyl group, a nitro group or a halogen atom, and m and m'"'"' each represent an integer of 1 to 3;

Y₁ and Y₃ each represent a hydrogen atom, an alkyl group having 1 to 18 carbon atoms, an alkenyl group having 2 to 18 carbon atoms, a sulfonamide group, a mesyl group, a sulfonic acid group, a carboxyester group, a hydroxyl group, an alkoxyl group having 1 to 18 carbon atoms, an acetylamino group, a benzoyl group, an amino group or a halogen atom, and n and n'"'"' each represent an integer of 1 to 3;

Y₂ and Y₄ each represent a hydrogen atom or a nitro group;

provided that the above X₁ and X₂, m and m'"'"', Y₁ and Y₃, n and n'"'"', and Y₂ and Y₄ may be the same or different; and

A⁺ represents H⁺, Na⁺, K⁺, NH₄⁺ or mixed ions thereof.

19. The process cartridge according to claim 18, wherein said compound is a compound represented by the formula:

##STR19## wherein A⁺ represents H⁺, Na⁺, K⁺, NH₄⁺ or mixed ions thereof.

20. The process cartridge according to claim 1, which is further provided with a contact charging means for electrostatically charging said electrostatic image bearing member.

21. The process cartridge according to claim 20, wherein said contact charging means is a charging roller.

22. The process cartridge according to claim 20, wherein said contact charging means is a charging brush.

23. The process cartridge according to claim 20, wherein said contact charging means is a charging blade.