Oxygen barrier composite film structure

• US 6,004,660 A
• Filed: 03/12/1998
• Issued: 12/21/1999
• Est. Priority Date: 03/12/1998
• Status: Expired due to Term

• Current Assignee: DuPont Performance Elastomers L (Bristol-Myers Squibb Company)
• Original Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Inventors: Britt, David Henry, Topolski, Alvin Stanley, Cumberbatch, George Merton Gordon, Chang, Clifford Cheng-Shiou
• Primary Examiner(s): Knynski, William
• Assistant Examiner(s): SHEWAREGED, BETELHEM
• Application Number:
  US09/041,321
• Time in Patent Office: 649 Days
• Field of Search: 428/212, 428/195, 428/220, 428/457, 428/688
• US Class Current: 428/212
• CPC Class Codes: B32B 27/36 comprising polyesters
• CPC Class Codes: C08J 7/0423 with at least one layer of inorganic material and at least one layer of a composition containing a polymer binder
• CPC Class Codes: C08J 7/043 Improving the adhesiveness of the coatings per se, e.g. forming primers adhesives in the form of films or foils characterised by the primer layers between the polymer carriers and the adhesives C09J7/50
• CPC Class Codes: C08J 7/048 Forming gas barrier coatings
• CPC Class Codes: Y10T 428/24802 Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
• CPC Class Codes: Y10T 428/24942 including components having same physical characteristic in differing degree
• CPC Class Codes: Y10T 428/31678 Of metal

Abstract

A composite film structure containing two inorganic layers each being not greater than 600 angstroms in thickness and having an oxygen transmission rate (OTR) not greater than 0.8 cubic centimeters/square meter-day-atmosphere with one of the layers in contact or in substantial contact with a polymeric barrier layer having an oxygen permeability coefficient (OPV) not greater than 1.5 cubic centimeters-25 microns/square meter-day-atm. The composite film structure has an oxygen transmission rate (OTR) of not greater than 0.012 cubic centimeters/square meter-day-atm and can be used in vacuum panel insulation structures.

Claims

1. A composite film structure containing a plurality of separate layers comprising:

(a) a first inorganic layer having a thickness not greater than 600 angstroms and having an oxygen transmission rate (OTR) not greater than 0.8 cubic centimeters/square meter-day-atmosphere;

(b) a second inorganic layer having a thickness not greater than 600 angstroms and having an oxygen transmission rate (OTR) not greater than 0.8 cubic centimeters/square meter-day-atmosphere; and

(c) a polymeric barrier layer having an oxygen permeability coefficient (OPV) not greater than 1.5 cubic centimeters-25 microns/square meter-day-atmosphere

wherein the polymeric barrier layer (c) is in contact or in substantial contact with at least one of the first (a) and second (b) inorganic layers, wherein the first (a) and second (b) inorganic layers are separated from one another by an intermediate adhesive layer and wherein the oxygen transmission rate (OTR) of the composite film structure is not greater than 0.012 cubic centimeters/square meter-day-atmosphere and the oxygen transmission rate (OTR) and oxygen permeability coefficient (OPV) are measured in accordance with ASTM D3985-81 at a temperature of 23°

C., 50% relative humidity and using 100% oxygen on one side of the film at 760 mm Hg (1 atmosphere) and 100% nitrogen on the other side of the film at 760 mm Hg (1 atmosphere).

2. The composite film structure of claim 1 wherein the polymeric barrier layer (c) is in contact with at least one of the first (a) and second (b) inorganic layers.

3. The composite film structure of claim 1 wherein the first (a) and second (b) inorganic layers are metal.

4. The composite film structure of claim 3 wherein the metal is selected from the group consisting of aluminum, nickel, copper, tin and stainless steel.

5. The composite film structure of claim 4 wherein the metal is vacuum deposited aluminum.

6. The composite film structure of claim 1 wherein the polymeric barrier layer comprises polyvinyl alcohol, ethylene vinyl alcohol, polyacrylonitrile, or combinations thereof.

7. The composite film structure of claim 2 wherein the polymeric barrier layer has a thickness of from 0.01 to 75 microns.

8. The composite film structure of claim 7 wherein the polymeric barrier layer has a thickness of from 0.40 to 0.80 micron.

9. The composite film structure of claim 1 which is flexible and can be wound in a roll.

10. The composite film structure of claim 1 wherein the polymeric barrier layer (c) is positioned between the first (a) and second (b) inorganic layers.

11. The composite film structure of claim 10 wherein the polymeric barrier layer (c) contacts or substantially contacts both the first (a) and second (b) inorganic layers.

12. The composite film structure of claim 11 wherein the first (a) and second (b) inorganic layers are metal.

13. The composite film structure of claim 12 wherein the metal is vacuum deposited aluminum.

14. The composite film structure of claim 1 wherein each of the first (a) and second (b) inorganic layers has a thickness of not greater than 350 angstroms.

15. The composite film structure of claim 14 wherein each of the first (a) and second (b) inorganic layers has a thickness of not greater than 230 angstroms.

16. The composite film structure of claim 1 wherein the first (a) and second (b) layers are silicon dioxide or aluminum oxide.

17. The composite film structure of claim 11 wherein the first (a) and second (b) inorganic layers are silicon dioxide or aluminum oxide.