Multilayer polarizer having a continuous and disperse phase

• US 6,005,713 A
• Filed: 04/30/1999
• Issued: 12/21/1999
• Est. Priority Date: 08/21/1998
• Status: Expired due to Term

• Current Assignee: 3M Innovative Properties Company (3M Company)
• Original Assignee: 3M Innovative Properties Company (3M Company)
• Inventors: Weber, Michael F., Ouderkirk, Andrew J., Nevitt, Timothy J., Stover, Carl A., Allen, Richard C., Majumdar, Biswaroop, Carlson, Lockwood W., Kotz, Arthur L.
• Primary Examiner(s): Spyrou, Cassandra
• Assistant Examiner(s): Juba, Jr., John
• Application Number:
  US09/302,880
• Time in Patent Office: 235 Days
• Field of Search: 252/585, 359/483, 359/485, 359/486, 359/492, 359/500, 359/494
• US Class Current: 359/487.02
• CPC Class Codes: G02B 5/3008 comprising dielectric particles, e.g. birefringent crystals embedded in a matrix
• CPC Class Codes: G02B 5/305 including organic materials, e.g. polymeric layers

Abstract

An optical film is provided which comprises a disperse phase of polymeric particles disposed within a continuous birefringent matrix. The film is oriented, typically by stretching, in one or more directions. The size and shape of the disperse phase particles, the volume fraction of the disperse phase, the film thickness, and the amount of orientation are chosen to attain a desired degree of diffuse reflection and total transmission of electromagnetic radiation of a desired wavelength in the resulting film.

Claims

1. A polarizer, comprising:

a plurality of layers arranged in a repeating sequence of at least a first and second layer type;

wherein said first layer type comprises a polyester continuous phase and a disperse phase, randomly distributed throughout said continuous phase, and wherein said continuous and disperse phases comprise diverse thermoplastic polymers.

2. The polarizer of claim 1, wherein said continuous and disperse phases have indices of refraction which differ by less than about 0.05 for visible light polarized along a first axis, and which differ by more than about 0.05 for visible light polarized along a second axis.

3. The polarizer of claim 2, wherein said polarizer has a total transmission of greater than 50% for visible light polarized along said first axis, and a total reflectivity of greater than 50% for visible light polarized along said second axis.

4. The polarizer of claim 1, wherein said continuous phase is birefringent.

5. The polarizer of claim 1, wherein said continuous phase has a birefringence of at least about 0.05.

6. The polarizer of claim 1, wherein said polarizer has a total diffuse reflectivity of at least 30% for visible light.

7. The polarizer of claim 1, wherein said second layer type also comprises a polyester.

8. The polarizer of claim 1, wherein said polyester is a naphthalene dicarboxylic acid polyester.

9. The polarizer of claim 1, wherein said repeating sequence has at least a first, second, and third layer type.

10. The polarizer of claim 1, wherein said polarizer is a multi-layer film.

11. The polarizer of claim 1, wherein said disperse phase is present in an amount within the range of about 15% to about 30% by volume relative to said continuous phase.

12. The polarizer of claim 1, wherein said first layer type further comprises a compatibilizer.

13. The polarizer of claim 1, wherein said disperse phase has a core and shell construction.

14. The polarizer of claim 1, wherein said disperse phase comprises a plurality of essentially spherical particles.

15. The polarizer of claim 1, wherein said disperse phase comprises a plurality of particles having essentially elliptical cross-sections.

16. The polarizer of claim 1, wherein said disperse phase comprises a plurality of essentially rod-like particles.

17. The polarizer of claim 1, further comprising a UV-stabilizer.

18. The polarizer of claim 1, further comprising at least one skin layer.

19. The polarizer of claim 1, further comprising an antioxidant.

20. The polarizer of claim 1, further comprising an antireflection layer.

21. The polarizer of claim 1, wherein said first layer type contains a plurality of voids.

22. A polarizer, comprising:

a plurality of layers arranged in a repeating sequence of at least a first and second layer type;

wherein said first layer type comprises a continuous phase, a disperse phase, and a compatibilizer, and wherein said continuous and disperse phases comprise diverse thermoplastic polymers.

23. The polarizer of claim 22, wherein said continuous phase comprises a first polymer and said disperse phase comprises a second polymer, and wherein said compatibilizer is a block copolymer of at least one of said first and second polymers.

24. The polarizer of claim 23, wherein said compatibilizer is a block copolymer of said first polymer.

25. The polarizer of claim 24, wherein said first polymer is polystyrene.

26. The polarizer of claim 22, wherein said first phase is syndiotactic polystyrene.

27. The polarizer of claim 22, wherein said continuous and disperse phases have indices of refraction which differ by less than about 0.05 for visible light polarized along a first axis, and which differ by more than about 0.05 for visible light polarized along a second axis.

28. The polarizer of claim 22, wherein said polarizer has a total diffuse reflectivity of at least 30% for visible light.

29. The polarizer of claim 22, wherein said disperse phase is present in an amount within the range of about 15% to about 30% by volume relative to said continuous phase.

30. A polarizer, comprising:

a plurality of layers arranged in a repeating sequence of at least a first and second layer type;

wherein said first layer type comprises a continuous phase and a disperse phase, wherein said continuous and disperse phases comprise diverse thermoplastic polymers, wherein said disperse phase comprises a plurality of particles, and wherein each of said particles have an essentially elliptical cross-section.

31. The polarizer of claim 30, wherein said polarizer further comprises a compatibilizer.

32. The polarizer of claim 31, wherein said continuous phase comprises a polyester.

33. The polarizer of claim 30, wherein said continuous phase comprises a naphthalene dicarboxylic acid polyester and wherein said disperse phase comprises polystyrene.

34. The polarizer of claim 33, wherein said polystyrene is syndiotactic polystyrene.

35. The polarizer of claim 33, wherein said continuous and disperse phases have indices of refraction which differ by less than about 0.05 for visible light polarized along a first axis, and which differ by more than about 0.05 for visible light polarized along a second axis.

36. The polarizer of claim 33, wherein said polarizer has a total diffuse reflectivity of at least 30% for visible light.

37. The polarizer of claim 33, wherein said disperse phase is present in an amount within the range of about 15% to about 30% by volume relative to said continuous phase.

38. In combination with a mirror, a polarizer, comprising:

a continuous phase; and

a disperse phase, disposed within said continuous phase;

wherein said continuous and disperse phases comprise diverse thermoplastic polymers.

39. The combination of claim 38, wherein said continuous and disperse phases have indices of refraction which differ by less than about 0.05 for visible light polarized along a first axis, and which differ by more than about 0.05 for visible light polarized along a second axis.

40. The combination of claim 38, wherein said polarizer has a total diffuse reflectivity of at least 30% for visible light.

41. The combination of claim 38, wherein said disperse phase is present in an amount within the range of about 15% to about 30% by volume relative to said continuous phase.