Method for producing millable polyurethanes and polyurethane elastomers

• US 6,008,312 A
• Filed: 12/02/1996
• Issued: 12/28/1999
• Est. Priority Date: 12/01/1995
• Status: Expired due to Term

• Current Assignee: Daicel Chemical Industries Limited (Daicel Corporation), Synztec Company Limited (NOK Corporation)
• Original Assignee: Daicel Chemical Industries Limited (Daicel Corporation), Hokushin Corporation (NOK Corporation)
• Inventors: Shirasaka, Hitoshi
• Primary Examiner(s): GORR, RACHEL F
• Application Number:
  US08/758,892
• Time in Patent Office: 1,121 Days
• Field of Search: 528/75, 528/80, 525/450, 525/453, 525/458
• US Class Current: 528/75
• CPC Class Codes: C08G 18/10 Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
• CPC Class Codes: C08G 18/4277 Caprolactone and/or substituted caprolactone
• CPC Class Codes: C08G 18/70 characterised by the isocyanates or isothiocyanates used
• CPC Class Codes: C08G 18/86 by peroxides
• CPC Class Codes: C08G 18/87 by sulfur
• CPC Class Codes: C08G 2250/00 Compositions for preparing crystalline polymers

Abstract

A method for producing millable polyurethanes by first producing a poly-ε-caprolactone based diol, the poly-ε-caprolactone based diol containing a controlled average number of caprolactone units and having a molecular weight distribution; and reacting the poly-ε-caprolactone based diol with a diisocyanate to produce a polyurethane with a restricted crystallizability having a rubber elasticity. The resulting millable polyurethanes exhibit excellent hydrolysis resistance, show no crystallization at low temperatures and have excellent mechanical properties.

Claims

1. A method for producing a crosslinkable millable polyurethane rubber having substantially no hard segments and being millable on conventional rubber machinery comprising the steps of:

producing a poly-ε

-caprolactone based diol represented by formula (I) ##STR3## wherein ( ) is a caprolactone unit;

m and n are numbers of caprolactone units; and

R₁ is a divalent group derived from a polymerization initiator of formula R₁,(OH)₂, the poly-ε

-caprolactone based diol containing a controlled average number of caprolactone units and having a molecular weight distribution Mw/Mn of 1.0 to 1.5; and

reacting said poly-ε

-caprolactone based diol with a diisocyanate to produce a polyurethane rubber having a restricted crystallizability.

2. A method of claim 1 wherein the molecular weight distribution Mw/Mn of said poly-ε

-caprolactone based diol is about from 1.0 to 1.3.

3. A method for producing a crosslinkable millable polyurethane rubber of claim 1, wherein a polymerization initiator represented by formula, R₁ (OH)₂, for said poly-ε

-caprolactone based diol is at least one member selected from the group consisting of straight chain glycols having 2 to 12 carbon atoms;

diols having and containing up to 12 carbon atoms and having a side chain; and

diols having an unsaturated group containing up to 12 carbon atoms, and wherein said caprolactone unit is present in an average number of about from 3 to 6.

4. A method for producing a crosslinkable millable polyurethane rubber as claimed in claim 3, wherein said polymerization initiator, R₁ (OH)₂, is at least one member selected from the group consisting of straight chain glycols having 2 to 12 carbon atoms, said glycols having no side chain.

5. A method for producing a crosslinkable millable polyurethane rubber as claimed in claim 1, wherein said polymerization initiator R₁ (OH)₂, is at least one member selected from the group consisting of diols having an aromatic ring;

and alicyclic diols, and wherein said caprolactone unit is present in an average number of 4 to 8.

6. A method for producing a crosslinkable millable polyurethane rubber as claimed in claim 1, wherein said polyol further comprises a chain extender.

7. A method for producing a crosslinkable millable polyurethane rubber as claimed in claim 1, wherein said millable polyurethane has a glass transition temperature, Tg, of no higher than -20°

C.

8. A method for producing a crosslinkable millable polyurethane rubber as claimed in claim 1, wherein said diisocyanate is at least one member selected from the group consisting of 2,6-toluene diisocyanate (TDI), 4,4'"'"'-diphenylmethane diisocyanate (MDI), p-phenylene diisocyanate (PPDI), 1,5-naphthalene diisocyanate (NDI), and 3,3-dimethyldiphenyl-4,4'"'"'-diisocyanate (TODI).

9. A method for producing a crosslinkable millable polyurethane rubber as claimed in claim 1, wherein said poly-ε

-caprolactone based diol is prepared under conditions of no higher than 130°

C. using a tin catalyst represented by formula (II) ##STR4## wherein R₂ is a hydrogen atom, an alkyl group, or an aryl group; and

X is a hydroxyl group, an alkoxide group or a halogen atom other than fluoride.

10. A method for producing a polyurethane elastomer, comprising the steps:

producing a crosslinkable millable polyurethane rubber according to the method of claim 1; and

crosslinking said crosslinkable millable polyurethane rubber with a curing agent and molding the resulting cured polyurethane to form a polyurethane elastomer.

11. A method of claim 10 wherein said curing agent is at least one member selected from the group consisting of organic peroxides, sulfur, organic nitrogen-containing compounds, and isocyanate compounds.

12. A polyurethane molded article comprising a mixture of a crosslinkable millable polyurethane rubber prepared by a method of claim 1 and a curing agent, said mixture being molded and crosslinked.

13. The polyurethane molded article as claimed in claim 12, wherein said curing agent is at least one member selected from the group consisting of organic peroxides, sulfur, organic nitrogen-containing compounds, and isocyanate compounds.