Mar resistant, corrosion inhibiting, weldable coating containing iron powder for metal substrates

• US 6,008,462 A
• Filed: 10/01/1997
• Issued: 12/28/1999
• Est. Priority Date: 10/01/1997
• Status: Expired due to Term

• Current Assignee: PPG Industries Ohio Incorporated (Nouryon BV)
• Original Assignee: Morton International Incorporated (Autoliv Incorporated)
• Inventors: Soltwedel, Jeffrey N.
• Primary Examiner(s): LUSIGNAN, MICHAEL R
• Application Number:
  US08/942,220
• Time in Patent Office: 818 Days
• Field of Search: 427/386, 427/388.2, 427/388.4, 219/91.2, 219/91.21, 219/117.1, 219/118, 523/402, 523/406, 523/442, 523/512
• US Class Current: 219/91.2
• CPC Class Codes: B23K 35/226 Non-corrosive coatings; Primers applied before welding
• CPC Class Codes: C09D 5/08 Anti-corrosive paints
• CPC Class Codes: C09D 5/24 Electrically-conducting paints conductive materials H01B1/00

Abstract

A weldable heat curable liquid coating composition for steel is provided that exhibits improved mar resistance without impairing the weldability characteristics of the coating. To this end, the composition contains a conductive welding aid of iron dust. The weldable coating when applied to steel and cured thereon to a dry film allows for spot welding of the coated steel without requiring special welding equipment and techniques.

Claims

1. A mar resistant, weldable, liquid coating composition, which comprises a solvent blend of:

a) an effective film-forming amount of a resin having crosslinkable functional groups;

b) a crosslinker in an effective amount for curing said resin; and

,

c) a weldably effective amount of a welding aid of finely divided non-magnetized iron metal particles naturally oxidized on their surface, randomly dispersed in said liquid coating,

said coating being essentially free of ferroalloy and nickel welding aids, and said coating being capable of forming a dry coating film on a metal substrate after curing which is weldable.

2. The composition of claim 1, which further comprises:

e) a pigment in an effective amount to impart color, lightness and opacity to the coating film upon curing.

3. The composition of claim 2, in which:

said iron particles are present up to about 50 wt. % of total solids.

4. The composition of claim 2, in which:

said iron particles are substantially smooth irregular spheroids.

5. The composition of claim 2, in which:

said iron particles have a particle size below about 100 mesh.

6. The composition of claim 2, in which:

a plurality of said iron particles have a particle size below about 325 mesh and the balance between about 100 and about 325 mesh.

7. The composition of claim 2, which further comprises:

d) a catalyst in an effective amount to accelerate cure.

8. The composition of claim 2, which further comprises:

f) an internal lubricant comprising polytetrafluoroethylene in an effective amount to reduce the coefficient of friction of the cured coating film.

9. The composition of claim 2, which further comprises:

g) an effective amount of a suspension agent for stably suspending said iron particles in the liquid coating.

10. The coating composition of claim 1, in which:

said dry weldable coating film formed after curing is an epoxy-pendant, urethane containing compound which is the reaction product of a) said film-forming resin comprising a mixture of at least one hydroxy-functional polyester resin and at least one bisphenol A epoxy resin, and b) said crosslinker comprising a mixture of at least one blocked isocyanate and at least one aminoplast.

11. The composition of claim 7, in which:

said coating is essentially free of anticorrosive chromate pigments.

12. A method of welding, which comprises:

a) applying said weldable liquid coating composition of claim 7 onto a metal substrate;

b) heat curing said coating to a dry film; and

,

c) welding said coated metal substrate to another similarly coated or bare metal substrate using a weld cycle similar to that for bare metal.

13. A mar resistant, weldable, liquid coating composition, which comprises a solvent blend of:

a) an effective film-forming amount of a resin comprising a mixture of one or more hydroxy-functional polyester resins and one or more epoxy resins;

b) an effective amount of a crosslinker for said resin which effects a urethane cure;

c) an effective amount of catalyst to accelerate cure;

d) a weldably effective amount up to about 50 wt. % of total solids of non-magnetized iron powder particles naturally oxidized on their surface, randomly dispersed in said liquid coating, said iron powder particles comprising irregular spheroids having a particle size below about 100 mesh;

e) a pigment in an effective amount to impart color, lightness and opacity to said coating upon curing;

f) a suspension agent in an effective amount for suspending said iron powder particles in said liquid coating,

said coating being essentially free of ferroalloy and nickel welding aids, and said coating being capable of forming a dry coating film on a metal substrate after curing which is weldable.

14. The composition of claim 13, in which:

said coating is essentially free of anticorrosive chromate pigments.

15. A mar resistant, internally lubricated, weldable, liquid coating composition, which comprises a solvent blend of:

a) an effective film-forming amount of a resin having crosslinkable functional groups;

b) a crosslinker in an effective amount for curing said resin into a dry coating film;

c) an internal lubricant comprising polytetrafluoroethylene in an effective amount to reduce the coefficient of friction of said dry coating film after curing, and,

d) a weldably effective amount of a welding aid of finely divided non-magnetized iron metal particles naturally oxidized on their surface, randomly dispersed in said liquid coating,

said coating being essentially free of ferroalloy and nickel welding aids, and said coating being capable of forming a dry coating film on a metal substrate after curing which is weldable.

16. The composition of claim 15, which further comprises:

f) a pigment in an effective amount to impart color, lightness and opacity to said cured coating film.

17. The composition of claim 16, in which:

said iron particles are present up to about 50 wt. % of total solids.

18. The composition of claim 16, in which:

said iron particles are substantially smooth irregular spheroids.

19. The composition of claim 16, in which:

said iron particles have a particle size below about 100 mesh.

20. The composition of claim 16, in which:

a plurality of said iron particles have a particle size below about 325 mesh and the balance between about 100 and 325 mesh.

21. The composition of claim 16, which further comprises:

e) a catalyst in an effective amount to accelerate cure.

22. The composition of claim 16, in which:

said coating is essentially free of anticorrosive chromate pigments.

23. The composition of claim 16, which further comprises:

g) a suspension agent in an effective amount for stably suspending the iron particles in the liquid coating.

24. The composition of claim 16, in which:

said dry weldable coating film formed after curing is an epoxy-pendant, urethane containing compound which is the reaction product of a) said film-forming resin comprising a mixture of at least one hydroxy-functional polyester resin and at least one bisphenol A epoxy resin, and b) said crosslinker comprising a mixture of at least one blocked isocyanate and at least one aminoplast.

25. A method of welding, which comprises:

a) applying said weldable liquid coating composition of claim 16 onto a metal substrate;

b) heat curing said coating to a dry film; and

,

c) welding said coated metal substrate to another similarly coated or bare metal substrate using a weld cycle similar to that for bare metal.

26. A mar resistant, internally lubricated, weldable, liquid coating composition, which comprises a solvent blend of:

a) an effective film-forming amount of a film-forming resin comprising a mixture of one or more hydroxy-functional polyester resins and one or more epoxy resins;

b) an effective amount of a crosslinker for said resin which effects a urethane cure;

c) a catalyst in an effective amount to accelerate cure;

d) a weldably effective amount up to about 50 wt. % of total solids of non-magnetized iron powder particles, naturally oxidized on their surface, randomly dispersed in said liquid coating, said iron powder particles comprising irregular spheroids having a particle size below about 100 mesh;

e) a pigment in an effective amount to impart color, lightness and opacity to said coating upon curing;

f) an internal lubricant comprising polytetrafluoroethylene in an effective amount to reduce the coefficient of friction of said coating upon curing; and

,

g) a suspension agent in an effective amount for suspending said iron powder in said liquid coating,

said coating being essentially free of ferroalloy and nickel welding aids, and said coating being capable of forming a dry coating film on a metal substrate after curing which is weldable.