Multi-gas sensor

• US 6,008,928 A
• Filed: 02/05/1998
• Issued: 12/28/1999
• Est. Priority Date: 12/08/1997
• Status: Expired due to Fees

• Current Assignee: College of William & Mary, National Aeronautics and Space Administration (Government of the United States of America)
• Original Assignee: Department of Health and Human Services (State of Victoria)
• Inventors: Rana, Mauro, Steele, Tommy C., LeBel, Peter J., Wang, Liang-guo, Sachse, Glenn W.
• Primary Examiner(s): Ben, Loha
• Application Number:
  US09/019,473
• Time in Patent Office: 691 Days
• Field of Search: 359/246, 359/247, 359/281, 359/252, 359/287, 359/250, 250/338.5, 250/338.1, 250/339.13, 356/437, 356/438, 356/346, 356/414
• US Class Current: 359/246
• CPC Class Codes: G01N 21/3504 for analysing gases, e.g. multi-gas analysis

Abstract

A multi-gas sensor is provided which modulates a polarized light beam over a broadband of wavelengths between two alternating orthogonal polarization components. The two orthogonal polarization components of the polarization modulated beam are directed along two distinct optical paths. At least one optical path contains one or more spectral discrimination element, with each spectral discrimination element having spectral absorption features of one or more gases of interest being measured. The two optical paths then intersect, and one orthogonal component of the intersected components is transmitted and the other orthogonal component is reflected. The combined polarization modulated beam is partitioned into one or more smaller spectral regions of interest where one or more gases of interest has an absorption band. The difference in intensity between the two orthogonal polarization components is then determined in each partitioned spectral region of interest as an indication of the spectral emission/absorption of the light beam by the gases of interest in the measurement path. The spectral emission/absorption is indicative of the concentration of the one or more gases of interest in the measurement path. More specifically, one embodiment of the present invention is a gas filter correlation radiometer which comprises a polarizer, a polarization modulator, a polarization beam splitter, a beam combiner, wavelength partitioning element, and detection element. The gases of interest are measured simultaneously and, further, can be measured independently or non-independently. Furthermore, optical or electronic element are provided to balance optical intensities between the two optical paths.

Claims

1. A method for sensing the concentration of two or more gases of interest within a measurement path, comprising the steps of:

modulating a polarized light beam, the light beam having passed through the measurement path, over a broadband of wavelengths between two alternating orthogonal polarization components;

directing one orthogonal polarization component of the polarization modulated beam along a first optical path and directing the other orthogonal polarization component along a second optical path, at least one optical path containing one or more spectral discrimination means, each spectral discrimination means having spectral absorption features of one or more gases of interest;

intersecting the two optical paths at an intersection point;

transmitting, at the intersection point, one orthogonal component of the intersected components and reflecting the other orthogonal component, whereby a combined polarization modulated beam is formed comprising the two orthogonal components in alternate order;

partitioning the combined polarization modulated beam into one or more smaller spectral regions of interest where one or more gases of interest has an absorption band; and

determining the difference in intensity between the two orthogonal polarization components in each partitioned spectral region of interest as an indication of the spectral emission/absorption of the light beam by the gases of interest in the measurement path, the spectral emission/absorption being indicative of the concentration of the one or more gases of interest in the measurement path.

2. The method of claim 1, further comprising the step of polarizing an unpolarized light beam prior to modulation.

3. The method of claim 1, wherein the one or more spectral discrimination means are one or more gas cells, each gas cell containing one or more gases of interest.

4. The method of claim 1, wherein the one or more spectral discrimination means are one or more optical interference elements, each optical interference element having spectral transmissions which approximately replicate the absorption features of one or more gases of interest.

5. The method of claim 1, further comprising the step of balancing the optical intensities between the two optical paths for one or more partitioned spectral regions of interest.

6. The method of claim 5, wherein the balancing is performed optically within the corresponding partitioned spectral region of interest.

7. The method of claim 5, wherein the balancing is performed electronically.

8. A multi-gas sensor for simultaneously measuring the concentration of two or more gases of interest within a measurement path, comprising:

a polarization modulator for modulating a polarized light beam, the light beam having passed through the measurement path, over a broadband of wavelengths between two alternating orthogonal polarization components;

a polarization beam splitter for switching the polarization modulated beam by transmitting one orthogonal polarization component of the polarization modulated light beam along a first optical path and reflecting the other orthogonal polarization component of the polarization modulated light beam along a second optical path;

at least one spectral discrimination means located in at least one of the first and second optical paths, each spectral discrimination means having spectral absorption features of one or more gases of interest;

means for intersecting the two optical paths at an intersection point;

a beam combiner located at the intersection point of the first and second optical paths, the beam combiner transmitting one orthogonal component of the intersected components and reflecting the other orthogonal component, whereby a combined polarization modulated beam is formed comprising the two orthogonal components in alternate order;

means for partitioning the combined polarization modulated beam into a detection path for each wavelength region of interest corresponding to an absorption band for the gases of interest;

a detector in each detection path for receiving the incident partitioned beam in the corresponding wavelength region of interest and for sensing a difference in the intensity between the two orthogonal polarization components of the incident partitioned beam as an indication of the spectral emission/absorption of the light beam by the gases of interest in the measurement path, the spectral emission/absorption being indicative of the concentration of the one or more gases of interest in the measurement path; and

a control and data acquisition means for exciting the polarization modulator, controlling the temperature of each detector, and processing the output of each detector.

9. The multi-gas sensor of claim 8, wherein each spectral discrimination means comprises a gas correlation cell, each gas correlation cell containing at least one gas of interest.

10. The multi-gas sensor of claim 8, wherein each spectral discrimination means comprises an optical interference element having a spectral transmission which approximately replicates the absorption feature of a wavelength region of interest.

11. The multi-gas sensor according to claim 8, further comprising an optical polarizer for polarizing an incoming light beam prior to modulation by the polarization modulator.

12. The multi-gas sensor according to claim 8, further comprising an optical waveplate positioned before the polarization modulator.

13. The multi-gas sensor according to claim 8, wherein the polarization modulator is selected from the group consisting of electro-optic, magneto-optic and photo-elastic modulators and liquid crystal devices.

14. The multi-gas sensor according to claim 8, wherein the polarization beam splitter is selected from the group consisting of prism, reflector, and wire grid beam splitters.

15. The multi-gas sensor according to claim 8, wherein the intersecting means comprises a respective reflecting mirror arranged in each of the two optical paths.

16. The multi-gas sensor according to claim 8, wherein the intersecting means is located such that the two optical paths from the polarization beam splitter to the intersection point are optically similar.

17. The multi-gas sensor according to claim 8, wherein the beam combiner is selected from the group consisting of polarization beamsplitter and broadband beamsplitter.

18. The multi-gas sensor according to claim 8, wherein the partitioning means comprises one or more optical filters operatively arranged to pass a unique wavelength band to each detector, each unique wavelength band corresponding to an absorption band of one or more gases of interest.

19. The multi-gas sensor according to claim 18, further comprising a focusing means positioned in front of each detector for focusing the incident beam on each detector, wherein the focusing means is selected from the group consisting of focusing mirror and refractive lens.

20. The multi-gas sensor according to claim 8, wherein the partitioning means comprises a beamsplitter and one or more downstream optical filters, the beamsplitter and optical filters operatively arranged to pass a unique wavelength band to each detector, each unique wavelength band corresponding to an absorption band of one or more gases of interest.

21. The multi-gas sensor according to claim 19, further comprising a focusing means in each detection path for focusing the incident beam on each detector, wherein the focusing means is selected from the group consisting of focusing mirror and refractive lens.

22. The multi-gas sensor according to claim 8, wherein two or more gases of interest have absorption features in a common wavelength region and are measured simultaneously but not independently.

23. The multi-gas sensor according to claim 8, wherein the gases of interest are spectrally non-overlapping within the one or more wavelength regions of interest and are measured simultaneously and independently.

24. The multi-gas sensor according to claim 8, wherein the optical polarizer is selected from the group consisting of prism, reflection, dichroic and wire grid polarizers.

25. The multi-gas sensor according to claim 8, further comprising a vacuum cell located in one of the first and second optical paths.

26. The multi-gas sensor of claim 8, wherein the control and data acquisition means comprises:

a variable gain amplifier corresponding to each detector for amplifying the AC portion of the detector'"'"'s signal;

a variable gain amplifier corresponding to each detector for amplifying the DC portion of the detector'"'"'s signal;

a synchronous demodulator corresponding to each detector for receiving the amplified AC signal and extracting its magnitude using a frequency reference signal from the polarization modulator;

a low pass filter corresponding to each detector for receiving the amplified DC signal and narrowing its electronic bandpass;

a low pass filter corresponding to each detector for receiving the demodulated AC signal and narrowing its electronic bandpass;

an A/D converter for converting the filtered AC and DC signals into digital representations for processing by a computer;

a controller corresponding to each detector for controlling the operating temperature of the corresponding detector; and

a controller for exciting the polarization modulator and providing a reference frequency for the demodulator.

27. The multi-gas sensor of claim 8, further comprising a polarization dependent optic operatively positioned in front of at least one detector to balance the corresponding optical intensities between the two optical paths.

28. The multi-gas sensor of claim 27, wherein the polarization dependent optic is selected from the group consisting of pellicle, infrared transmitting crystal, amorphous window and infrared polarizer.

29. The multi-gas sensor of claim 8, wherein the control and data acquisition means balances the optical intensities between the two optical paths for one or more partitioned spectral regions of interest.