Fiber reinforced, titanium composite engine valve

• US 6,009,843 A
• Filed: 10/22/1997
• Issued: 01/04/2000
• Est. Priority Date: 10/22/1997
• Status: Expired due to Fees

• Current Assignee: 3M Innovative Properties Company (3M Company)
• Original Assignee: 3M Innovative Properties Company (3M Company)
• Inventors: Sorensen, James P., Griffin, Christopher J., Skowronek, Charles J.
• Primary Examiner(s): Solis, Erick R.
• Application Number:
  US08/955,792
• Time in Patent Office: 804 Days
• Field of Search: 123/188.3, 29/888.45, 29/888.452
• US Class Current: 123/188.3
• CPC Class Codes: B22F 2998/00 Supplementary information concerning processes or compositions relating to powder metallurgy
• CPC Class Codes: B22F 3/15 Hot isostatic pressing
• CPC Class Codes: B22F 5/10 of articles with cavities or holes, not otherwise provided for in the preceding subgroups
• CPC Class Codes: C22C 47/025 Aligning or orienting the fibres
• CPC Class Codes: C22C 47/04 by coating, e.g. with a protective or activated covering
• CPC Class Codes: C22C 47/06 by forming the fibres or filaments into a preformed structure, e.g. using a temporary binder to form a mat-like element
• CPC Class Codes: C22C 47/20 by subjecting to pressure and heat an assembly comprising at least one metal layer or sheet and one layer of fibres or filaments
• CPC Class Codes: F01L 3/02 Selecting particular materials for valve-members or valve-seats; Valve-members or valve-seats composed of two or more materials
• CPC Class Codes: Y10T 29/49307 Composite or hollow valve stem or head making
• CPC Class Codes: Y10T 29/49311 including extruding

Abstract

Lightweight, strong, engine valves that incorporate a valve stem made from a refractory monofilament-reinforced, titanium-based metal matrix composite. Advantageously, the composite of the present invention is sufficiently strong so that valve stems incorporating the composite can be hollow for providing significant weight reduction while meeting valve stem strength and stiffness specifications. The valve includes a valve stem comprising a first end, a second end, and EL longitudinal axis extending from the first end to the second end. The valve stem comprises a composite incorporating a titanium-based metal binder matrix and an axially aligned cluster of continuous, refractory monofilaments incorporated in the binder matrix. A valve head is provided at one end of the valve stem, and a valve tip is provided at the other end. The invention also relates to a method of making such valves. The invention further relates to a composite assembly from which such valves may be machined.

Claims

1. A valve for an internal combustion engine, comprising:

(a) a valve stem comprising a first end, a second end, and a longitudinal axis extending from the first end to the second end, said valve stem comprising a composite, said composite comprising;

(i) a titanium-based metal binder matrix; and

(ii) an axially aligned cluster of refractory monofilaments incorporated into the binder matrix; and

(b) a valve head provided at the first end of the valve stem.

2. The valve of claim 1, further comprising a valve tip provided at the second end of the valve stem.

3. The valve of claim 1, wherein the valve stem is hollow such that the valve stem includes an inner wall and an outer wall.

4. The valve of claim 3, wherein the valve stem comprises substantially monofilament-free regions lining the inner and outer walls of the valve stem.

5. The valve of claim 4, wherein the inner and outer regions each independently comprise a titanium-based metal.

6. The valve of claim 1, wherein the valve stem is hollow such that the valve stem includes a first inner wall and a first outer wall each adjacent to said first end and a second inner wall and a second outer wall each adjacent to a second end, where the thickness between said first inner and outer walls as defined by the shortest distance therebetween is greater than the thickness between second inner and outer walls as defined by the shortest distance therebetween.

7. The valve of claim 1, wherein the refractory monofilaments comprise silicon carbide.

8. The valve of claim 7, wherein substantially no monofilament directly contacts another monofilament of the cluster such that substantially all of the monofilaments are spaced apart from each other.

9. The valve of claim 7, wherein at least a portion of the silicon carbide monofilaments extend substantially continuously from the first end to the second end of the valve stem.

10. The valve of claim 1, wherein the valve head comprises a titanium-based metal.

11. The valve of claim 10, wherein the valve head comprises a flared cavity region, wherein the monofilaments at said second end of the valve stem include monofilament ends that are spaced apart from and do not directly contact the titanium-based metal of the valve head.

12. The valve of claim 11, wherein the flared cavity region has an apex positioned substantially at a neutral bending axis of the valve head.

13. The valve of claim 3, wherein the refractory monofilaments comprise silicon carbide.

14. The valve of claim 3, wherein the valve stem comprises substantially monofilament-free regions lining the inner and outer walls of the valve stem.

15. The valve of claim 3, wherein at least a portion of the silicon carbide monofilaments extend substantially continuously from the first end to the second end of the valve stem.

16. The valve of claim 11, wherein the refractory monofilaments comprise silicon carbide.

17. The valve of claim 11, wherein the valve stem comprises substantially monofilament-free regions lining the inner and outer walls of the valve stem.

18. The valve of claim 11, wherein at least a portion of the silicon carbide monofilaments extend substantially continuously from the first end to the second end of the valve stem.

19. A method of making an internal combustion engine valve of the type in which a valve head is attached to a valve stem having a longitudinal axis, comprising the steps of:

(a) providing a cluster of axially aligned, refractory monofilaments, wherein each monofilament comprises a coating including a titanium-based metal or titanium alloy;

(b) subjecting the cluster of axially aligned, coated monofilaments to conditions effective to form a composite comprising said monofilaments incorporated in a binder matrix comprising the titanium-based metal; and

(c) incorporating at least a portion of the composite into the valve stem of the valve such that the monofilaments of the composite are substantially parallel to the longitudinal axis of the stem.

20. The method of claim 19, wherein the forming step comprises forming a tubular cluster of said monofilaments positioned in a cavity between an inner tube concentrically supported in a bore of an outer tube.

21. The method of claim 19, wherein step (b) is carried out under conditions such that substantially no monofilament directly contacts another monofilament of the cluster such that substantially all of the monofilaments are spaced apart from each other.

22. The method of claim 19, wherein substantially all of the monofilaments of the cluster have a length corresponding to the length of the valve stem.

23. The method of claim 19, wherein step (b) includes subjecting the cluster to hot isostatic pressing under conditions effective to cause the titanium based metal coatings of the monofilaments to fuse together to form at least a portion of the binder matrix.

24. The method of claim 23, wherein:

(1) step (b) includes comprises positioning the cluster of monofilaments in a tubular cavity of an assembly formed from an inner tube concentrically supported in a bore of an outer tube; and

(2) hot isostatically pressing the assembly under conditions effective to provide said composite body.

25. The method of claim 24, wherein step (c) includes attaching a valve head blank to the fused assembly and machining the resultant combination to form the valve.

26. The method of claim 25, further including the steps of machining an end of the fused assembly with an inverted taper and attaching said machined end to the valve head blank such that monofilaments at said machined end are spaced apart from directly contacting the valve head.