Annealed low emissivity coating

• US 6,010,602 A
• Filed: 05/12/1997
• Issued: 01/04/2000
• Est. Priority Date: 12/27/1994
• Status: Expired due to Fees

• Current Assignee: PPG Industries Ohio Incorporated (Nouryon BV)
• Original Assignee: PPG Industries Ohio Incorporated (Nouryon BV)
• Inventors: Finley, James J., Arbab, Mehran, Miller, Larry A.
• Primary Examiner(s): Nguyen, Nam
• Assistant Examiner(s): MCDONALD, RODNEY GLENN
• Application Number:
  US08/854,591
• Time in Patent Office: 967 Days
• Field of Search: 204/192.26, 204/192.27, 204/192.28, 204/192.29, 204/192.15, 427/165, 427/166, 65/60.2, 65/60.4, 65/60.5
• US Class Current: 204/192.27
• CPC Class Codes: C03C 17/36 at least one coating being a metal
• CPC Class Codes: C03C 17/3618 Coatings of type glass/inorganic compound/other inorganic layers, at least one layer being metallic
• CPC Class Codes: C03C 17/3639 Multilayers containing at least two functional metal layers
• CPC Class Codes: C03C 17/3642 the multilayer coating containing a metal layer
• CPC Class Codes: C03C 17/3644 the metal being silver
• CPC Class Codes: C03C 17/3652 the coating stack containing at least one sacrificial layer to protect the metal from oxidation
• CPC Class Codes: C03C 17/366 Low-emissivity or solar control coatings
• CPC Class Codes: C03C 17/3681 the multilayer coating being used in glazing, e.g. windows or windscreens
• CPC Class Codes: C03C 2217/78 Coatings specially designed to be durable, e.g. scratch-resistant
• CPC Class Codes: C23C 14/58 After-treatment
• CPC Class Codes: C23C 14/5806 Thermal treatment

Abstract

A low emissivity coated article comprising a glass substrate and a coating comprising a layer of infrared reflective metal between layers of antireflective metal oxide is heated to a temperature below the strain point of the substrate for a sufficient time to anneal the coating without affecting the substrate to improve the chemical and mechanical durability of the coating.

Claims

1. A method of increasing the shear resistance of a sputter coating deposited on a soda-lime-silica glass substrate, the glass substrate having a strain point comprising the steps of:

sputter coating onto the glass substrate successive layers of an antireflective metal oxide, an infrared reflective metal, a metal primer, an antireflective metal oxide, an infrared reflective metal, a metal primer, an antireflective metal oxide and a protective overcoat, and

heating the coated glass substrate to a temperature not exceeding the strain point of the glass substrate and between about 600 and 1000°

F. (about 315 to 538°

C.) for a time period within the range of 1 to 8 minutes to increase the shear resistance of the coating.

2. The method according to claim 1 wherein the temperature is between about 700 and 850°

F. (about 371 and 454°

C.).

3. The method according to claim 1 wherein one of the layers of the antireflective metal oxide include a layer of a zinc/tin oxide and one of the layers of the infrared reflective metal is silver.

4. The method according to claim 1 wherein one of the layers of the metal primer is titanium.

5. The method according to claim 1 wherein the temperature is between about 800 to 900°

F. (about 427 to 482°

C.).

6. The method according to claim 5 wherein the temperature is about 850°

F. (about 454°

C.) and the time period is within the range of about 2 to 6 minutes.

7. The method according to claim 1 wherein the coated substrate is heated to a temperature of about 1000°

F. (about 538°

C.) and the time period is within the range of about one to two minutes.

8. The method according to claim 5, wherein each of the antireflective metal oxide layers comprises a mixture of zinc and tin, each of the infrared reflective metal layers is silver and each of the metal primer layers is titanium.

9. A method of increasing the shear resistance of a sputter coating deposited on a soda-lime-silica glass substrate, the glass substrate having a strain point comprising the steps of:

sputter coating onto the glass substrate successive layers of an antireflective metal oxide, an infrared reflective metal and a metal primer to provide a coated article defined as coated glass;

heating the coated glass to a temperature not exceeding the strain point of the substrate and between about 600 and 1000°

F. (about 315 to 538°

C.) for a time period in the range of about 1 to 8 minutes to increase the shear resistance of the coating on the coated glass, and

sputter coating over the metal primer of the coated glass successive layers of an antireflective metal oxide, an infrared reflective metal, a metal primer, an antireflective metal oxide and a protective overcoat.

10. The method according to claim 9 wherein the temperature is between about 700 and 850°

F. (about 371 and 454°

C.).

11. The method according to claim 9 wherein one of the layers of the antireflective metal oxide include a layer of zinc/tin oxide and one of the layers of the infrared reflective metal is silver.

12. The method according to claim 9 wherein one of the layers of the metal primer is titanium.

13. The method according to claim 9 wherein the temperature is between about 800 to 900°

F. (about 427 to 482°

C.).

14. The method according to claim 13 wherein the temperature is about 850°

F. (about 454°

C.) and the time period is within the range of about 2 to 6 minutes.

15. The method according to claim 9 wherein the coated glass is heated to a temperature of about 1000°

F. (about 538°

C.) and the time period is within the range of about one to two minutes.

16. The method according to claim 15, wherein each of the antireflective metal oxide layers comprises a mixture of zinc and tin, each of the infrared reflective metal layers is silver and each of the metal primer layers is titanium.