Method for electroplating metal coating(s) particulates at high coating speed with high current density

• US 6,010,610 A
• Filed: 02/04/1998
• Issued: 01/04/2000
• Est. Priority Date: 04/09/1996
• Status: Expired due to Term

• Current Assignee: Pay Yih
• Original Assignee: Pay Yih
• Inventors: Yih, Pay
• Primary Examiner(s): Gorgos, Kathryn
• Assistant Examiner(s): Wong, Edna
• Application Number:
  US09/018,553
• Time in Patent Office: 699 Days
• Field of Search: 205/144, 205/145, 205/149
• US Class Current: 205/149
• CPC Class Codes: C25D 21/10 Agitating of electrolytes; Moving of racks
• CPC Class Codes: C25D 7/006 Nanoparticles

Abstract

The electroplating process of the present invention is a cyclical operation having at least three essentially independent steps in each cycle of operation with the independent steps carried out in sequence and consisting of stirring, sedimentation and electroplating. The sedimentation step occurs over an essentially quiescent time interval with essentially no current flow through the electrolyte and essentially no stirring so as to form a sedimentation layer of loosely contacted particulates on said cathode plate. The electroplating step follows the sedimentation step at a current density of over at least 5 A/dm². The stirring step immediately follows the step of electroplating with the stirring operation being sufficiently vigorous to disperse the particulates in the sedimentation layer and to break up particulates bridged by metallic coating formed during the previous step of electroplating.

Claims

1. A method of electroplating particulates in a metallic ion-containing electrolyte solution within an electroplating device having an anode and a cathode plate comprising at least one cycle of operation having at least three essentially independent steps performed separately and in sequence consisting of the steps of:

stirring, sedimentation and electroplating with the sedimentation step occurring over an essentially quiescent time interval with essentially no current flow through the electrolyte and essentially no stirring so as to form a sedimentation layer of loosely contacted particulates on said cathode plate, applying an electromotive potential across said anode and cathode plate to create an electric current in said electrolyte for performing said electroplating step at a current density of over at least 5 A/dm² and performing the stirring step immediately following the step of electroplating with the stirring operation being sufficiently vigorous at least at the outset thereof to disperse the particulates in the sedimentation layer and to break up particulates bridged by metallic coating formed during the previous step of electroplating.

2. A method as defined in claim 1 comprising multiple cycles of operation with each cycle being repeated in the same sequence and having the same three steps of operation.

3. A method as defined in claim 2 wherein the current density is at least about 15 A/dm².

4. A method as defined in claim 2 wherein said electromotive potential is supplied by a power supply having an output which varies between a substantially fixed output and an output of essentially zero current with the steps of stirring and sedimentation occuring during the interval of essentially zero current output.

5. A method as defined in claim 2 wherein said electromotive potential is supplied by a power supply having a switch for turning the power supply on and off and with said power supply being switched off during the steps of stirring and sedimentation in each cycle of operation.

6. A method as defined in claim 2 wherein the stirring speed is in the range of between about 50˜

500 rpm.

7. A method as defined in claim 6 wherein the sedimentation step should occurs over a time interval to permit the sedimentation layer to form having a thickness of at least about 1 mm.

8. A method as defined in claim 7 wherein the sedimentation step should occurs over a time interval to permit the sedimentation layer to form having a thickness of at least about 3-30 mm.

9. A method as defined in claim 8 wherein the sedimentation step should occurs over a time interval to permit about 85˜

90% of the particulates to sedimentate to the cathode plate 4 in any one cycle of operation.

10. A method as defined in claim 7 wherein said particulates vary in size from submicron to thousands of microns.