Alkaline hair conditioning compositions containing cationic guar

• US 6,010,690 A
• Filed: 03/05/1998
• Issued: 01/04/2000
• Est. Priority Date: 03/05/1998
• Status: Expired due to Term

• Current Assignee: CLAIROL INCORPORATED (The Procter & Gamble Company)
• Original Assignee: Bristol-Myers Squibb Company
• Inventors: Varco, Joseph J.
• Primary Examiner(s): Page, Thurman K.
• Assistant Examiner(s): Seidlech, Brian K.
• Application Number:
  US09/035,392
• Time in Patent Office: 670 Days
• Field of Search: 424/70.13, 424/70.11, 424/70.5, 424/70.1, 514/880, 132/202, 132/203
• US Class Current: 424/70.13
• CPC Class Codes: A61K 2800/5426 cationic
• CPC Class Codes: A61K 8/737 Galactomannans, e.g. guar; Derivatives thereof
• CPC Class Codes: A61P 17/16 Emollients or protectives, e.g. against radiation
• CPC Class Codes: A61Q 5/04 Preparations for permanent waving or straightening the hair
• CPC Class Codes: A61Q 5/12 Preparations containing hair conditioners

Abstract

The invention provides compositions for relaxing and conditioning keratinous fibers, particularly human hair. The compositions of the present invention have a high pH, i.e., a pH greater than 10, preferably, in the range of about 11 to about 14, more preferably about 12 to about 13.5, and include as a conditioning additive a cationic guar. Surprisingly, the cationic guar maintains stability, viscosity and activity over time in the highly alkaline pH of the inventive hair relaxer and conditioning compositions of the present invention. The relaxer compositions of the present invention afford beneficial effects to the user, such as softness and ease of wet combing, and cause less damage to hair following application and use. In addition, the conditioning relaxer compositions of the present invention remain on the hair and provide lasting conditioning and relaxing effects after one or more shampoos.

Claims

1. A stable viscous hair relaxer, waving or curling composition having hair conditioning activity comprising a mixture of at least one alkaline earth metal hydroxide that relaxes strands of hair;

and a hair conditioning amount of at least one cationic guar, said cationic guar being stable in the composition over time, and a cosmetically acceptable vehicle therefor, said composition having a pH of 12 to 14, said cationic guar being a polygalactomannan comprising mannose and galactose having at least one quaternary ammonium compound reacted therewith, said quaternary ammonium compound having the structure;

##STR5## wherein R₁, R₂, and R₃ are alkyl, aryl and substituted alkyl and aryl groups;

R₄ is selected from the group consisting of epoxyalkyl and halohydrin, and Z^-- is an anion.

2. The composition according to claim 1, wherein the alkaline earth metal hydroxide is selected from the group consisting of sodium hydroxide, lithium hydroxide, potassium hydroxide, barium hydroxide, strontium hydroxide, and mixtures thereof, provided that when the alkaline earth hydroxide is calcium hydroxide the composition further contains an activator.

3. The composition according to claim 1, wherein the alkaline earth metal hydroxide is present in an amount of about 1.5 to about 5% by weight based on the total weight of the composition.

4. The composition according to claim 1, wherein the pH of the composition is about 12 to about 13.5.

5. The composition according to claim 4, wherein the pH of the composition is about 12.5 to about 13.5.

6. The composition according to claim 1, wherein the cationic guar is a quaternary ammonium derivative of hydroxypropyl guar.

7. The composition according to claim 6, wherein the cationic guar is guar hydroxypropyltrimonium chloride.

8. The composition according to claim 1, wherein the cationic guar is present in the composition at about 0.5% to about 5.0%, by weight, based on the total weight of the composition.

9. The composition according to claim 1, wherein the relaxer component is an alkaline earth metal hydroxide selected from the group consisting of sodium hydroxide, calcium hydroxide, lithium hydroxide, potassium hydroxide, barium hydroxide, strontium hydroxide and mixtures thereof.

10. The composition according to claim 1, further comprising an auxiliary conditioning agent.

11. The composition according to claim 10, wherein the auxiliary conditioning agent is selected from the group consisting of quaternary ammonium compounds, amines, ethyl sulfates and cationic polymers.

12. The composition according to claim 11, wherein the auxiliary conditioning agent is polyquaternium 10 or benhentrimonium methosulfate.

13. A composition for conditioning hair comprising a mixture of a cationic guar in an amount effective to impart a conditioning effect to the hair and a cosmetically acceptable vehicle therefor, said composition having a pH 12 to 14, said cationic guar being a polygalactomannan comprising mannose and galactose having at least one quaternary ammonium compound reacted therewith, said quaternary ammonium compound having the structure:

##STR6## wherein R₁, R₂, and R₃ are alkyl, aryl and substituted alkyl and aryl groups;

R₄ is selected from the group consisting of epoxyalkyl and halohydrin, and Z^-- is an anion.

14. The composition according to claim 13, wherein the pH is about 12 to about 13.5.

15. The composition according to claim 14, wherein the pH of the composition is about 12.5 to about 13.5.

16. The composition according to claim 13, wherein the cationic guar is a quaternary ammonium derivative of hydroxypropyl guar.

17. The composition according to claim 16, wherein the cationic guar is guar hydroxypropyltrimonium chloride.

18. The composition according to claim 13, wherein the cationic guar is present in the composition at about 0.5% to about 5.0%, by weight, based on the total weight of the composition.