Aqueous, radiation-curable coating compositions

• US 6,011,078 A
• Filed: 05/04/1998
• Issued: 01/04/2000
• Est. Priority Date: 05/05/1997
• Status: Expired due to Term

• Current Assignee: BASF AG (BASF SE)
• Original Assignee: BASF AG (BASF SE)
• Inventors: Menzel, Klaus, Beck, Erich, Enenkel, Peter, Reich, Wolfgang, Lokai, Matthias, Keil, Edmund
• Primary Examiner(s): Seidleck, James J.
• Assistant Examiner(s): MCCLENDON, SANZA L
• Application Number:
  US09/071,155
• Time in Patent Office: 610 Days
• Field of Search: 522/84, 522/86, 522/85, 522/100, 522/103, 522/92, 427/508, 427/517
• US Class Current: 522/86
• CPC Class Codes: C09D 167/07 having terminal carbon-to-carbon unsaturated bonds
• CPC Class Codes: G03F 7/033 the binders being polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers
• CPC Class Codes: G03F 7/11 having cover layers or intermediate layers, e.g. subbing layers G03F7/091 - G03F7/093, B41N3/03 take precedence

Abstract

Described are aqueous, radiation-curable coating compositions comprising:

a) from 5.0 to 90.0% by weight of at least one water-dispersible polymer P comprising at least one α,β-ethylenically unsaturated, radiation-polymerizable double bond,

b) from 0.1 to 90% by weight of at least one radiation-curable compound S which is different from P and which is soluble in water or is dilutable with at least 10% by weight of water, based on the overall weight of the coating composition, and which comprises at least one α,β-ethylenically unsaturated, radiation-polymerizable double bond,

c) from 0 to 20% by weight of a photoinitiator,

d) from 0 to 60% by weight of a filler,

e) from 0 to 20% by weight of further additives,

f) water to 100% by weight and their use.

Claims

1. An aqueous, radiation-curable coating composition comprising:

a) from 5.0 to 90.0% by weight of at least one water-dispersible polymer P comprising at least one α

,β

-ethylenically unsaturated, radiation-polymerizable double bond,

b) from 0.1 to 90% by weight of at least one radiation-curable compound S which is different from P and which is soluble in water or is dilutable with at least 10% by weight of water, based on the overall weight of the coating composition, and which comprises at least one α

,β

-ethylenically unsaturated, radiation-polymerizable double bond,

c) from 0 to 20% by weight of a photoinitiator,

d) from 0 to 60% by weight of a filler,

e) from 0 to 20% by weight of further additives, and

f) water to 100% by weight.

2. A coating composition as claimed in claim 1 where the polymer P is selected from esters of α

,β

-ethylenically unsaturated monocarboxylic acids with hydroxyl-containing polycondensates Pk, esters of α

,β

-ethylenically unsaturated dicarboxylic monoesters with polycondensates Pk, ethers of α

,β

-ethylenically unsaturated alcohols with polycondensates Pk, epoxy resin derivatives containing α

,β

-ethylenic double bonds, polyurethane derivatives containing α

,β

-ethylenic double bonds, and polymers with repeating units which comprise acyl residues having α

,β

-ethylenic double bonds, and mixtures thereof.

3. A coating composition as claimed in claim 2, where the polycondensate Pk is selected from polyesters with or without ether groups, polyethers with or without ester groups, alkoxylates of dihydric or polyhydric alcohols, polyalkylene glycols, polyaddition polymers of cyclic ethers, and mixtures and copolymers thereof.

4. A coating composition as claimed in claim 1, where the compound S is dilutable with at least 15% by weight, of water, based on the overall weight of the coating composition.

5. A coating composition as claimed in claim 1, where the compound S is selected from epoxy acrylates, epoxy methacrylates, polyether acrylates, polyether methacrylates, polyester acrylates, polyester methacrylates, polyurethane acrylates, polyurethane methacrylates, melamine acrylates, melamine methacrylates, thickeners, and mixtures thereof.

6. A coating composition as claimed in claim 1, where

I) the polymer P is an ester of α

,β

-ethylenically unsaturated monocarboxylic acids with hydroxyl-containing polycondensates Pk and the compound S is an epoxy acrylate, epoxy methacrylate, polyether acrylate or polyether methacrylate, or

II) the polymer P is a polyurethane derivative which contains α

,β

-ethylenic double bonds, and the compound S is a polyurethane thickener with α

,β

-ethylenically unsaturated, radiation-polymerizable double bonds, or

III) the polymer P is a polyurethane derivative containing α

,β

-ethylenic double bonds, and the compound S is an acrylate-based thickener with α

,β

-ethylenically unsaturated, radiation-polymerizable double bonds, or

IV) the polymer P is an ester of α

,β

-ethylenically unsaturated monocarboxylic acids with hydroxyl-containing polycondensates Pk and the compound S is a melamine acrylate or melamine methacrylate.

7. A coating composition as claimed in claim 1, comprising as component c) from 0.05 to 20% by weight, preferably from 0.05 to 10% by weight and, in particular, from 0.1 to 5% by weight of a photoinitiator.

8. A coating composition as claimed in claim 1, where the photoinitiator is selected from benzophenone and derivatives thereof, benzoin and derivatives thereof, benzil and derivatives thereof, anthraquinone and derivatives thereof, anthrone and derivatives thereof, phosphine oxides and derivatives thereof, phosphine sulfides and derivatives thereof, and mixtures of these.

9. A coating composition as claimed in claim 1, wherein the photoinitiator additionally comprises a synergist.

10. A coating composition as claimed in claim 9 where the synergist is selected from triethylamine, dimethylethanolamine, methyldiethanolamine, triethanolamine, amino acrylates, and mixtures thereof.

11. A coating composition as claimed in claim 1, where the solids content is at least 50% by weight.

12. A process for preparing coated surfaces, which comprises

i) applying a coating composition as claimed in claim 1 to the surface,

ii) curing the applied coating composition by irradiation with UV radiation or electron beams,

iii) applying at least one further radiation-curable coating material to the coated surface, and carrying out curing.

13. A process as claimed in claim 12, wherein the coating composition, following application to the surface in step i), is not additionally dried prior to irradiation.

14. The process as claimed in claim 12, wherein the coating composition is used as a primer, especially beneath radiation-curable coating materials.

15. The process as claimed in claim 14, wherein the coating composition is used as a primer for nonabsorbent surfaces, preferably metals, plastics and synthetic textile fibers.

16. The process as claimed in claim 14, wherein the coating composition is used as a primer for absorbent substrates, preferably wood, wood-derived materials, paper, cotton and leather.

17. The coating composition as claimed in claim 10, wherein the synergist is an amine-modified polyether acrylate.

18. The coating composition as claimed in claim 1, wherein the solids content is at least 60% by weight.

19. The coating composition as claimed in claim 1, wherein the solids content is at least 70% by weight.

20. The coating composition as claimed in claim 1, wherein the compound S is dilutable with at least 20% by weight of water, based on the overall weight of the coating composition.