Metal fibermat/polymer composite

• US 6,013,376 A
• Filed: 12/09/1997
• Issued: 01/11/2000
• Est. Priority Date: 12/09/1997
• Status: Expired due to Term

• Current Assignee: 3M Innovative Properties Company (3M Company)
• Original Assignee: 3M Innovative Properties Company (3M Company)
• Inventors: Yenni, Donald M. Jr.
• Primary Examiner(s): Krynski, William
• Assistant Examiner(s): Xu, Hong J.
• Application Number:
  US08/987,336
• Time in Patent Office: 763 Days
• Field of Search: 428/457, 428/458, 428/459, 428/465, 428/480, 428/484, 428/689, 428/688, 428/174, 428/294.4, 264/510
• US Class Current: 428/458
• CPC Class Codes: B29C 45/14778 the article consisting of a material with particular properties, e.g. porous, brittle
• CPC Class Codes: B29C 70/885 with incorporated metallic wires, nets, films or plates as lost heating elements B29C35/0272, B29C61/0625
• CPC Class Codes: B29K 2995/0011 Electromagnetic wave shielding material
• CPC Class Codes: H05K 9/009 comprising electro-conductive fibres, e.g. metal fibres, carbon fibres, metallised textile fibres, electro-conductive mesh, woven, non-woven mat, fleece, cross-linked
• CPC Class Codes: Y10T 428/24628 Nonplanar uniform thickness material
• CPC Class Codes: Y10T 428/249931 Free metal or alloy fiber
• CPC Class Codes: Y10T 428/31678 Of metal
• CPC Class Codes: Y10T 428/31681 Next to polyester, polyamide or polyimide [e.g., alkyd, glue, or nylon, etc.]

Abstract

A shaped article having EMI shielding properties, having been shaped by thermoforming of a planar sheet, and having a shape requiring the planar sheet to exhibit a stretch ratio of at least about 300%, and up to about 500%. The article consists essentially of a fibrous metal mat substantially surrounded by a fiber-coat and a polymeric carrier for support of the mat. The fiber mat may also be embedded into the carrier material. The fiber-coat may be sprayed onto the mat or, as a thermoplastic material, may be forced together with the metal fiber mat to surround it, and such procedure may take place before or after attachment to the carrier material.

Claims

1. A shaped article shaped by thermoforming of a planar sheet, said shaped article having a shape requiring said planar sheet to exhibit a stretch ratio of at least about 300%, said article comprising:

a shield for electromagnetic interference consisting essentially of a unitary fibrous metal mat, including fused metal fiber-to-fiber contacts, said mat comprising a low melting metal or metal alloy having a melting point in the range from about 70°

C. to about 370°

C., said metal mat being substantially surrounded by a thermoplastic coating, said metal mat further being supported by a non-porous carrier sheet, said shaped article being substantially free from metal bumps and metal mat gaps.

2. A shaped article according to claim 1 wherein said metal mat is formed from a metal or metal alloy having a melting point lower than the softening points of either said non-porous sheet or said thermoplastic coating.

3. A shaped article according to claim 1 wherein said thermoplastic coating and said carrier sheet are formed of different materials.

4. A shaped article according to claim 1 wherein said shape requires said planar sheet to exhibit a stretch ratio of about 500%.

5. A shaped article according to claim 1 wherein said thermoplastic coating was applied to said fibrous metal mat prior to attachment to said carrier sheet.

6. A shaped article according to claim 5 wherein said thermoplastic coating was applied by spraying.

7. A shaped article according to claim 1 wherein said thermoplastic coating is a thermoplastic resin selected from the group consisting of ethylene-butyl acrylate copolymers, ethylene-vinyl acetate copolymers and dispersions thereof, ethylene-methacrylic acid copolymers;

thermoplastic polyesters, polyamides, acrylic adhesives, hot melt adhesives, block copolymers, polyurethanes, polyethylenes, polypropylenes, grafted polymers and copolymers, functionalized copolymers, maleic anhydrides, acrylic acid modified copolymers, polyesters, copolyesters, latex binders, polyurethane dispersions, styrene-ethylene butylene-styrene copolymers, and paraffin wax.

8. A shaped article according to claim 7 wherein said thermoplastic coating is ethylene vinyl acetate.

9. A shaped article according to claim 1 wherein said fibrous metal mat was attached to said carrier sheet prior to the application of said thermoplastic coating.

10. A shaped article according to claim 9 wherein said carrier sheet is attached to said fibrous metal mat by means of pressure or heat.

11. A shaped article according to claim 1 wherein said carrier sheet is selected from the group consisting of acrylonitrile, butadiene styrene, polycarbonate, cellulosic materials, ethylene-butyl acrylate copolymers, ethylene-vinyl acetate copolymers and dispersions thereof, ethylene-methacrylic acid copolymers;

thermoplastic polyesters, polyamides, acrylic adhesives, hot melt adhesives, block copolymers, polyurethanes, polyethylenes, polypropylenes, grafted polymers and copolymers, functionalized copolymers, maleic anhydrides, acrylic acid modified copolymers, polyesters, copolyesters, latex binders, polyurethane dispersions, styrene-ethylene butylene-styrene copolymers, and paraffin wax.

12. A shaped article according to claim 11 wherein said thermoplastic coating is an acrylic adhesive.

13. A shaped article according to claim 12 wherein said acrylic adhesive contains microspheres.

14. A shaped article according to claim 1 wherein said thermoplastic coating and said carrier sheet are an acrylic adhesive.

15. A composite thermoformable planar sheet consisting essentially of a non-porous carrier sheet with a metal fiber mat of randomly oriented, low melting metal fibers, as a shield for electromagnetic interference, said metal fiber mat being substantially surrounded by a thermoplastic fiber-coat material, said fiber-coat material being attached prior to or after attachment of said low melting metal fibers to the non-porous carrier sheet, said composite thermoformable planar sheet being capable of being formed into a shaped article having fused metal fiber-to-fiber contacts.

16. A shaped article having been formed by insert injection molding, said shaped article having as an integral portion an EMI shield, consisting of a composite, sheet consisting essentially of a non-porous carrier sheet with a mat of randomly oriented, low melting metal fibers, said mat of randomly oriented, low melting metal fibers being substantially surrounded by a thermoplastic coating material, said thermoplastic coating material being attached prior to or after attachment of the metal fibers to said non-porous sheet, said EMI shield including fused metal fiber-to-fiber contacts said composite sheet fashioned from a planar sheet into said integral portion of said shaped article by inserting said planar sheet into the injection molding mold before infecting resin therein.