Liquid crystal element having composite layer

• US 6,015,507 A
• Filed: 11/08/1995
• Issued: 01/18/2000
• Est. Priority Date: 11/08/1994
• Status: Expired due to Term

• Current Assignee: Minolta Corporation Limited (Konica Minolta Inc.)
• Original Assignee: Minolta Corporation Limited (Konica Minolta Inc.)
• Inventors: Kobayashi, Nobuyuki, Hatano, Takuji, Hashimoto, Kiyofumi
• Primary Examiner(s): WU, SHEAN CHIU
• Application Number:
  US08/555,299
• Time in Patent Office: 1,532 Days
• Field of Search: 252/299.01, 252/299.66, 349/86, 349/88, 349/175, 349/184, 349/185, 349/186
• US Class Current: 252/299.01
• CPC Class Codes: C09K 19/544 as dispersing or encapsulating medium around the liquid crystal

Abstract

A liquid crystal element includes a pair of plates at least one of which is transparent, and a composite layer retained between the plates and including a liquid crystal material in a transparent resin substrate. In the liquid crystal element, (A) the liquid crystal material in the composite layer contains aromatic rings and exhibits a cholesteric phase, the substrate in the composite layer is made of resin and contains aromatic rings, and a ratio of the number of aromatic rings to that of carbon atoms in the main chain of monomer is in a range from 1:5 to 1:12; (B) the liquid crystal material in the composite layer is formed of a mixture of a liquid crystal material exhibiting a nematic phase and a liquid crystal material exhibiting a smectic phase, and exhibits a cholesteric phase as a whole; or (C) the liquid crystal material in the composite layer is formed of a mixture of a tolane liquid crystal material, a biphenyl liquid crystal material and a chiral ingredient, and exhibits a cholesteric phase as a whole.

Claims

1. A liquid crystal element comprising a pair of plates at least one of which is transparent, and a composite layer retained between said plates, said composite layer including a transparent resin substrate and a liquid crystal material which has a cholesteric characteristic, wherein said liquid crystal material contains aromatic rings, said transparent resin substrate contains aromatic rings, and ratio of the number of aromatic rings to that of carbon atoms in the main chain of monomer of the transparent resin substrate is in a range from 1:

5 to 1;

12, the number of said carbon atoms being the number of carbon atoms of groups in the main chain of the monomer represented by --CH₂ --, --CH-- or the like except for aromatic rings, --CO-- groups, and --COOH-- groups.

2. A liquid crystal element according to claim 1, wherein said liquid crystal material is formed of nematic liquid crystal material and chiral ingredient added thereto.

3. A liquid crystal element according to claim 2, wherein both of said nematic liquid crystal material and said chiral ingredient contain aromatic rings.

4. A liquid crystal element according to claim 3, wherein a molecule of said chiral ingredient contains a cyano group.

5. A liquid crystal element according to claim 3, wherein a molecule of said chiral ingredient contains a --COO-- group.

6. A liquid crystal element according to claim 2, wherein a molecule of said nematic liquid crystal contains a fluorine atom.

7. A liquid crystal element according to claim 1, wherein said transparent resin is photo-curing resin.

8. A liquid crystal element according to claim 7, wherein said photo-curing resin is monofunctional or bifunctional acrylate which has a molecular structure containing one or two aromatic rings in the main chain of monomer.

9. A liquid crystal element according to claim 7, wherein said composite layer is prepared by phase separation caused by irradiating light beams to a mixture of said photo-curing resin material and said liquid crystal material to form the photo-curing resin substrate containing the liquid crystal material.

10. A liquid crystal element according to claim 1, wherein said transparent resin substrate has a three-dimensionally continuous mesh structure.

11. A liquid crystal element according to claim 1, wherein the weight ratio of said liquid crystal material to said transparent resin substrate is in a range from 5:

5 to 9;

1.

12. A liquid crystal element comprising a pair of plates at least one of which is transparent, and a composite layer retained between said plates, said composite layer including a transparent matrix material and a liquid crystal material which has a cholesteric characteristic, wherein said liquid crystal material is formed of mixture of (a) a first compound of a liquid crystal material having a nematic characteristic, (b) a second compound of a liquid crystal material having a smectic characteristic, and (c) a third compound having a chiral ingredient.

13. A liquid crystal element according to claim 12, wherein said transparent matrix is made of resin.

25. A liquid crystal element according to claim 12 wherein said transparent matrix material is made of photo-curing resin.

26. A liquid crystal element according to claim 25 wherein said composite layer is prepared by phase separation caused by radiating light beams to a mixture of said photo-curing resin material and said liquid crystal material to form the photo-curing resin substrate containing the liquid crystal material.

27. A liquid crystal element according to claim 12 wherein said transparent matrix material has a three-dimensionally continuous mesh structure.

14. A liquid crystal element comprising a pair of plates at least one of which is transparent, and a composite layer retained between said plates, said composite layer including a transparent matrix material and a liquid crystal material which has a cholesteric characteristic wherein said liquid crystal material is formed of mixture of a liquid crystal material having a nematic characteristic, a liquid crystal having a smectic characteristic, and a chiral ingredient wherein said transparent matrix material is made of photo-curing resin.

15. A liquid crystal element according to claim 14, wherein said composite layer is prepared by phase separation caused by irradiating light beams to a mixture of said photo-curing resin material and said liquid crystal material to form the photo-curing resin matrix containing the liquid crystal material.

16. A liquid crystal element comprising a pair of plates at least one of which is transparent, and a composite layer retained between said plates, said composite layer including a transparent matrix material and a liquid crystal material which has a cholesteric characteristic, wherein said liquid crystal material is formed of mixture of a liquid crystal material having a nematic characteristic, a liquid crystal having a smectic characteristic, and a chiral ingredient wherein said transparent matrix material has a three-dimensionally continuous mesh structure.

17. A liquid crystal element comprising a pair of plates at least one of which is transparent, and a composite layer retained between said plates and including a transparent matrix material and a liquid crystal material which has a cholesteric characteristic, wherein said liquid crystal material is formed of a mixture of a first compound having a tolane portion, a second compound containing a biphenyl component and a chiral ingredient.

18. A liquid crystal element according to claim 17, wherein said transparent substrate is made of resin.

19. A liquid crystal element according to claim 17, wherein said transparent substrate is made of photo-curing resin.

20. A liquid crystal element according to claim 19, wherein said composite layer is prepared by phase separation caused by irradiating light beams to a mixture of said photo-curing resin material and said liquid crystal material to form the photo-curing resin substrate containing the liquid crystal material.

21. A liquid crystal element according to claim 17, wherein said transparent substrate has a three-dimensionally continuous mesh structure.

22. A liquid crystal material having a cholesteric characteristic, said liquid crystal material being formed from a mixture of (a) a first compound of a liquid crystal material having a nematic characteristic, (b) a second compound of a liquid crystal material having a smectic characteristic, and (c) a third compound having a chiral ingredient.

23. A liquid crystal material having a cholesteric characteristic, said liquid crystal material being formed of a mixture of a first compound having a tolane portion, a second compound containing a biphenyl component and a chiral ingredient, wherein the amount of said second compound is about 30 wt % or less of the amount of said first compound.

24. A liquid crystal material having a cholesteric characteristic, said liquid crystal material being formed from a mixture of (a) a first compound of a liquid crystal material having a nematic characteristic said nematic material containing fluorine atoms, (b) a second compound of a liquid crystal material having a smectic characteristic, and (c) a third compound having a chiral ingredient.