Liquid crystal optical element, liquid crystal display element and a projection type liquid crystal display apparatus

• US 6,017,466 A
• Filed: 06/28/1996
• Issued: 01/25/2000
• Est. Priority Date: 06/30/1995
• Status: Expired due to Term

• Current Assignee: Asahi Glass Company, Limited (AGC, Inc.)
• Original Assignee: AG Technology Co., Ltd.
• Inventors: Fujino, Yohsuke, Niiyama, Satoshi, Hirai, Yoshinori
• Primary Examiner(s): WU, SHEAN CHIU
• Application Number:
  US08/673,313
• Time in Patent Office: 1,306 Days
• Field of Search: 428/1.1, 252/299.01, 349/86, 349/93, 349/5, 348/761, 348/790
• US Class Current: 252/299.01
• CPC Class Codes: C09K 19/544 as dispersing or encapsulating medium around the liquid crystal
• CPC Class Codes: G02F 1/1334 based on polymer dispersed liquid crystals, e.g. microencapsulated liquid crystals

Abstract

A liquid crystal optical element comprising a pair of substrates with electrodes and a liquid crystal/polymer composite material interposed between the pair of substrates wherein polymer which constitutes a polymer phase has a maximum value of 20° C. or less in the temperature dependence of the loss dielectric constant (a frequency for measurement=100 Hz).

Claims

1. A liquid crystal optical element comprising a pair of substrates with electrodes and a liquid crystal/polymer composite material interposed between the pair of substrates wherein polymer which constitutes a polymer phase in said liquid crystal/polymer composite material has a maximum loss dielectric constant at a temperature of 20°

C. or less when measured at 100 Hz and said polymer is obtained from photocurable compounds comprising photocurable monomers, wherein the photocurable monomers have molecular weights of 144 to 500.

2. A liquid crystal optical element according to claim 1, wherein the polymer is swelled by 5-20 wt % in the presence of liquid crystal.

3. A liquid crystal optical element according to claim 1, wherein the polymer is a cured product of a mixture of at least two different photocurable vinyl compounds having different molecular weights, and the ratio of the higher molecular weight to the lower molecular weight of photocurable vinyl compounds is at least 1.5.

4. A liquid crystal optical element according to claim 1, wherein the refractive index of the polymer at the time of application of a voltage or at the time of application of non-voltage substantially coincide with the ordinary refractive index (n_o) or the extraordinary refractive index (n_e).

5. A liquid crystal optical element according to claim 1, wherein an outer signal is applied across substrate electrodes to cause a change in an electric field passing through the liquid crystal/polymer composite material and to produce a non-saturated voltage value whereby a half tone display is effected.

6. A liquid crystal display element comprising an active matrix substrate, an opposing electrode substrate and a liquid crystal/polymer composite material for the liquid crystal optical element defined in claim 1, the liquid crystal/polymer composite material being interposed between the active matrix substrate and the opposing electrode substrate.

7. A projection liquid crystal display apparatus comprising the liquid crystal display element defined in claim 6, a light source for projection and an optical system for projection.

8. A projection liquid crystal display apparatus according to claim 7, wherein light from the light source for projection is split into color lights of R, G and B;

the liquid crystal display element is arranged for each of the color lights;

the color lights modified by the liquid crystal display elements are synthesized, and a full-color light of picture image is projected through the optical system for projection.

9. A liquid crystal optical element according to claim 2, wherein the polymer is a cured product of a mixture of at least two different photocurable vinyl compounds having different molecular weights, and the ratio of the higher molecular weight to the lower molecular weight of photocurable vinyl compounds is at least 1.5.

10. The liquid crystal optical element as claimed in claim 1, wherein said photocurable compounds further comprise a photocurable oligomer having a molecular weight that is at least 1.5 times higher than said photocurable monomers molecular weight.

11. The liquid crystal optical element as claimed in claim 1, wherein at least one of said photocurable monomers has a chemical structure containing a hexamethylene group with no side chains, a hexamethylene group with one or more side chains or a polysiloxane group.

12. The liquid crystal optical element as claimed in claim 1, wherein said photocurable monomers are one or more members selected from the group consisting of alkyl acrylates, hydroxyalkyl acrylates and alkylene glycol diacrylates.

13. The liquid crystal optical element as claimed in claim 10, wherein said photocurable oligomer is a bifunctional acrylurethane.