Antimicrobial cleaning composition

• US 6,017,561 A
• Filed: 04/04/1997
• Issued: 01/25/2000
• Est. Priority Date: 04/04/1997
• Status: Expired due to Term

• Current Assignee: Clorox Company
• Original Assignee: Clorox Company
• Inventors: Zhou, Boli, Ochomogo, Maria
• Primary Examiner(s): Dees, Jose' G.
• Assistant Examiner(s): Shelborne, Kathryne E.
• Application Number:
  US08/833,276
• Time in Patent Office: 1,026 Days
• Field of Search: 424/76.1, 424/486
• US Class Current: 424/486
• CPC Class Codes: A01N 2300/00 Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48
• CPC Class Codes: A01N 25/04 Dispersions, emulsions, suspoemulsions, suspension concentrates or gels foams A01N25/16
• CPC Class Codes: A01N 25/10 Macromolecular compounds
• CPC Class Codes: A01N 25/24 containing ingredients to enhance the sticking of the active ingredients
• CPC Class Codes: A01N 25/34 Shaped forms, e.g. sheets, not provided for in any other sub-group of this main group
• CPC Class Codes: A01N 33/12 Quaternary ammonium compounds
• CPC Class Codes: C11D 3/3746 Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
• CPC Class Codes: C11D 3/48 Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions

Abstract

A novel antibacterial cleaning composition which exhibits exceptional germicidal activity for sustained periods of time is provided. The antibacterial cleaning composition that includes: (a) a quaternary ammonium compound; (b) an anionic polymer having an acid number greater than 10 wherein the anionic polymer is partially or completely neutralized by the quaternary ammonium compound to form a polymer complex and wherein the polymer complex is greater than about 15% by weight of the solids in the composition; (c) a dispersing agent and/or solvent; and (d) water. The composition can be incorporated into the matrix of sponges. Alternatively, the quaternary ammonium compound can be complexed directly to cellulosic sponges that have been functionalized with anionic groups.

Claims

1. An antibacterial cleaning composition comprising:

a) a quaternary ammonium compound;

b) an anionic polymer having an acid number greater than 10 wherein the anionic polymer is partially or completely neutralized by quaternary ammonium compound to form a polymer complex and wherein the polymer complex and wherein the polymer complex is greater than about 15% by weight of the solids in the composition;

c) a dispersing agent, which comprises a surfactant that is selected from the group consisting of nonionic surfactant, amphoteric surfactant, and mixtures thereof and;

d) optionally, a solvent.

2. The cleaning composition of claim 1 wherein the cleaning composition is an aqueous composition which comprises a dispersing agent that comprises a nonionic polymer that is selected from the group consisting of polyvinyl alcohol, polyvinyl pyrrolidone, polyacrylamide, polyethylene oxide, polypropylene oxide, polyvinyl acetate, and mixtures thereof.

3. The cleaning composition of claim 1 further comprises an adhesion promoter.

4. A sponge device having antibacterial activity that comprises:

(a) a sponge; and

(b) a polymer complex comprising a quaternary ammonium compound and an anionic polymer having an acid number of greater than 10 wherein the anionic polymer is partially or completely neutralized by the quaternary ammonium compound to form the polymer complex which is attached to a surface of the sponge.

5. A cellulose sponge material comprising anionic groups on a surface of the sponge and quaternary ammonium compounds that are complexed to said anionic groups.

6. An absorbent or adsorbent matrix having antibacterial activity, said matrix comprising;

(a) the absorbent or adsorbent matrix, and;

(b) a polymer complex comprising a quaternary ammonium compound and an anionic polymer having an acid number of greater than 10 wherein the anionic polymer is partially or completely neutralized by the quaternary ammonium compound to form the polymer complex which associates with said matrix.

7. The matrix of claim 6 wherein said matrix comprises a sponge.

8. The matrix of claim 7 wherein said polymer complex is impregnated within said sponge.

9. The matrix of claim 7 wherein said polymer complex is provided in a layer adhered to said sponge.

10. The matrix of claim 7 wherein said polymer complex comprises a component of said sponge.

11. A method of fabricating an absorbent or adsorbent matrix having antimicrobial activity which comprises the steps of:

(a) providing an absorbent or adsorbent matrix;

(b) contacting said matrix with an aqueous mixture comprising an antibacterial cleaning composition comprising;

(i) a quaternary ammonium compound;

(ii) an anionic polymer having an acid number greater than 10 wherein the anionic polymer is partially or completely neutralized by the quaternary ammonium compound to form a polymer complex and wherein the polymer complex is greater than about 15% by weight of the solids in the composition;

(iii) optionally a dispensing agent; and

(iv) optionally, a solvent;

wherein the polymer complex is associated with a surface of the matrix.

12. The method of claim 11 wherein the matrix comprises cellulose.

13. The method of claim 12 wherein said polymer complex is prefabricated and thereafter incorporated into said matrix.

14. A method of fabricating an absorbent or adsorbent matrix having antimicrobial activity which comprises the steps of:

(a) providing an absorbent or adsorbent matrix;

(b) impregnating an anionic polymer into the matrix to form an impregnated matrix; and

(c) contacting the impregnated matrix with an aqueous solution of quaternary ammonium compound whereby the anionic polymer is partially or completely neutralized by the quaternary ammonium compound to form a polymer complex which associates with said matrix.

15. The method of claim 14 wherein the matrix is regenerated cellulose.