Electrically conductive silicone compositions

• US 6,017,587 A
• Filed: 07/09/1998
• Issued: 01/25/2000
• Est. Priority Date: 07/09/1998
• Status: Expired due to Fees

• Current Assignee: Dow, Inc.
• Original Assignee: Dow Corning Toray Company Limited (Dow, Inc.), Dow, Inc.
• Inventors: Vanwert, Bernard, Nakayoshi, Kazumi, Mitani, Osamu, Kleyer, Don Lee, Mine, Katsutoshi, Lutz, Michael Andrew
• Primary Examiner(s): Marquis, Melvyn I.
• Application Number:
  US09/112,392
• Time in Patent Office: 565 Days
• Field of Search: 525/478, 525/479, 524/440, 524/46, 524/100, 524/267, 524/315, 524/306, 524/484, 427/387, 428/447
• US Class Current: 427/387
• CPC Class Codes: C08G 77/12 containing silicon bound to hydrogen C08G77/045 takes precedence
• CPC Class Codes: C08G 77/20 containing silicon bound to unsaturated aliphatic groups C08G77/045 takes precedence
• CPC Class Codes: C08G 77/44 containing only polysiloxane sequences
• CPC Class Codes: C08G 77/60 in which all the silicon atoms are connected by linkages other than oxygen atoms
• CPC Class Codes: C08G 77/70 Siloxanes defined by use of the MDTQ nomenclature
• CPC Class Codes: C08G 77/80 Siloxanes having aromatic substituents, e.g. phenyl side groups
• CPC Class Codes: C08L 2666/54 Inorganic substances
• CPC Class Codes: C08L 83/00 Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 83/04 Polysiloxanes
• CPC Class Codes: H01B 1/22 the conductive material comprising metals or alloys
• CPC Class Codes: Y10T 428/31663 As siloxane, silicone or silane

Abstract

The present invention relates to electrically conductive silicone compositions comprising an organopolysiloxane containing at least two alkenyl groups per molecule, an organohydrogenpolysiloxane having at least two silicon-bonded hydrogen atoms per molecule, a platinum group metal containing catalyst, a conductive metal particulate, a precrosslinked elastomeric silicone particle, and a non-reactive volatile diluent. The electrically conductive silicone compositions of this invention are useful as electrically conductive adhesives and coatings for electrical and electronic devices. The cured electrically conductive silicone compositions of this invention have high electroconductivity and rubbery elasticity.

Claims

1. An electrically conductive silicone composition comprising:

(A) at least one organopolysiloxane containing at least two alkenyl groups per molecule;

(B) at least one organohydrogenpolysiloxane having at least two silicon-bonded hydrogen atoms per molecule;

(C) a platinum group metal-containing catalyst;

(D) at least one electrically conductive metal particulate;

(E) precrosslinked elastomeric silicone particles; and

(F) at least one non-reactive volatile compatible diluent.

2. A composition according to claim 1, wherein (A) is selected from the group consisting of trimethylsiloxy-terminated dimethylpolysiloxane-methylvinylpolysiloxane copolymers, vinyldimethylsiloxy-terminated dimethylpolysiloxanes, vinyldimethylsiloxy-terminated dimethylpolysiloxane-methylvinylpolysiloxane copolymers, trimethylsiloxy-terminated dimethylpolysiloxane-methylhexenylpolysiloxane copolymers, hexenyldimethylsiloxy-terminated dimethylpolysiloxanes, hexenyldimethylsiloxy-terminated dimethylpolysiloxane-methylhexenylpolysiloxane copolymers, trimethylsiloxy-terminated dimethylsiloxane-methylvinylsiloxane-methylphenylsiloxane copolymers, vinyldimethylsiloxy-terminated dimethylsiloxane-methylvinylsiloxane-methylphenylsiloxane copolymers, vinyldimethylsiloxy-terminated dimethylsiloxane-methylphenylsiloxane copolymers, vinyldimethylsiloxy-terminated dimethylsiloxane-diphenylsiloxane copolymers, trimethylsiloxy-terminated dimethylsiloxane-methylvinylsiloxane-diphenylsiloxane copolymers, trimethylsiloxy-terminated dimethylsiloxane-methylhexenylsiloxane-methylphenylsiloxane copolymers, hexenyldimethylsiloxy-terminated dimethylsiloxane-methylhexenylsiloxane-methylphenylsiloxane copolymers, hexenyldimethylsiloxy-terminated dimethylsiloxane-methylphenylsiloxane copolymers, hexenyldimethylsiloxy-terminated dimethylsiloxane-diphenylsiloxane copolymers, trimethylsiloxy-terminated dimethylsiloxane-methylhexenylsiloxane-diphenylsiloxane copolymers, and combinations thereof.

3. A composition according to claim 1, wherein (B) is selected from the group consisting of dimethylhydrogensiloxy-terminated dimethylpolysiloxanes, dimethylhydrogensiloxy-terminated methylhydrogenpolysiloxanes, dimethylhydrogensiloxy-terminated dimethylpolysiloxane-methylhydrogenpolysiloxane copolymers, trimethylsiloxy-terminated dimethylpolysiloxane-methylhydrogenpolysiloxane copolymers, trimethylsiloxy-terminated methylhydrogenpolysiloxanes, PrSi(OSiMe₂ H)₃ Pr denotes propyl and me denotes methyl, cyclic methylhydrogensiloxanes, and siloxane resin copolymers consisting essentially of Me₂ HSiO_1/2 units and SiO₂ units.

4. A composition according to claim 1, wherein (C) is selected from the group consisting of chloroplatinic acid, alcohol modified chloroplatinic acids, and olefin complexes of platinum.

5. A composition according to claim 1, wherein (C) is a microencapsulated platinum-containing catalyst comprising microparticles of a thermoplastic resin containing an encapsulated hydrosilylation reaction catalyst obtained by a method comprising:

(i) dissolving a hydrosilylation catalyst and a thermoplastic resin in a quantity of a volatilizable liquid sufficient to achieve a solution exhibiting a viscosity suitable for spraying, where the softening point or glass-transition temperature of the resin is from 40 to 200°

C.;

(ii) blending the solution in the form of a spray into a current of a heated inert gas, whereby the liquid is volatilized from the individual droplets that constitute the spray concurrently with solidification of the resin to form discrete microparticles during entrainment of the droplets in the current; and

(iii) recovering the microparticles.

6. A composition according to claim 5, wherein the hydrosilylation catalyst is selected from the group consisting of chloroplatinic acid, alcohol-modified chloroplatinic acids, and olefin complexes of platinum.

7. A composition according to claim 5, wherein the thermoplastic resin is selected from the group consisting of silicone resins, polysilane resins, acrylic resins, polystyrene resins, and methyl cellulose.

8. A composition according to claim 1, wherein (D) is selected from the group consisting of silver powders, silver flakes, and a mixture of silver powders and silver flakes.

9. A composition according to claim 1, wherein (E) comprises spherical particles of precrosslinked silicone elastomer.

10. A composition according to claim 1, wherein (E) comprises irregular shaped particles of precrosslinked silicone elastomer.

11. A composition according to claim 1, wherein (F) is selected from the group consisting of cyclic saturated hydrocarbons, straight-chain saturated hydrocarbons, isoparaffins, mineral oils, aromatic hydrocarbons, alkyl substituted aromatic hydrocarbons, ethers, esters, low molecular weight polysiloxanes, and cyclic low molecular weight polysiloxanes.

12. A composition according to claim 1, wherein (F) is selected from the group consisting of hexadecane, mineral oil, isoparaffins, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, xylene, pentylbenzene, cyclohexylbenzene, diethyl phthalate, decane, pentadecane, and a mixture of decamethylcyclopentasiloxane and dodecamethylcyclohexasiloxane.

13. A composition according to claim 1, wherein the composition further comprises a siloxane resin consisting essentially of at least one R₃ SiO_1/2 (M) unit and at least one SiO_4/2 (Q) unit wherein R is independently selected from the group consisting of a monovalent hydrocarbon group free of aliphatic unsaturation having from 1 to 10 carbon atoms and an alkenyl group having from 2 to 10 carbon atoms.

14. A composition according to claim 1, wherein the composition fturther comprises an inhibitor.

15. A composition according to claim 13, wherein the composition further comprises an inhibitor.

16. A composition according to claim 1, wherein the composition further comprises an adhesion promoter.

17. A composition according to claim 13, wherein the composition further comprises an adhesion promoter.

18. A composition according to claim 14, wherein the composition further comprises an adhesion promoter.

19. A composition according to claim 15, wherein the composition further comprises an adhesion promoter.

20. An electrically conductive silicone composition obtained by a method comprising reacting a mixture comprising:

(A) at least one organopolysiloxane containing at least two alkenyl groups per molecule;

(B) at least one organohydrogenpolysiloxane having at least two silicon-bonded hydrogen atoms per molecule;

(C) a platinum group metal-containing catalyst;

(D) an electrically conductive metal particulate;

(E) a precrosslinked elastomeric silicone particle; and

(F) a non-reactive volatile compatible diluent.

21. A composition according to claim 20, wherein the mixture further comprises a siloxane resin consisting essentially of at least one R₃ SiO_1/2 (M) unit and at least one SiO_4/2 (Q) unit wherein R is independently selected from the group consisting of a monovalent hydrocarbon group free of aliphatic unsaturation having from 1 to 10 carbon atoms and an alkenyl group having from 2 to 10 carbon atoms.

22. A composition according to claim 20, wherein the mixture further comprises an inhibitor.

23. A composition according to claim 21, wherein the mixture further comprises an inhibitor.

24. A composition according to claim 20, wherein the mixture further comprises an adhesion promoter.

25. A composition according to claim 21, wherein the mixture further comprises an adhesion promoter.

26. A composition according to claim 22, wherein the mixture further comprises an adhesion promoter.

27. A composition according to claim 23, wherein the mixture further comprises an adhesion promoter.

28. An article of manufacture obtained by a method comprising

(I) applying an electrically conductive silicone composition on the surface of a substrate wherein the electrically conductive silicone composition comprises:

(A) at least one organopolysiloxane containing at least two alkenyl groups per molecule;

(B) at least one organohydrogenpolysiloxane having at least two silicon-bonded hydrogen atoms per molecule;

(C) a platinum group metal-containing catalyst;

(D) an electrically conductive metal particulate;

(E) a precrosslinked elastomeric silicone particle; and

(F) a none-reactive volatile compatible diluent.

29. An article of manufacture according to claim 28, wherein the method further comprises (II) exposing the coating and the substrate to heat in an amount sufficient to cure the coating.