Polymer films having a printed self-assembling monolayer

• US 6,020,047 A
• Filed: 09/04/1996
• Issued: 02/01/2000
• Est. Priority Date: 09/04/1996
• Status: Expired due to Term

• Current Assignee: Kimberly-Clark Worldwide Incorporated (Kimberly-Clark Corporation)
• Original Assignee: Kimberly-Clark Worldwide Incorporated (Kimberly-Clark Corporation)
• Inventors: Everhart, Dennis S.
• Primary Examiner(s): DIXON, MERRICK L
• Application Number:
  US08/707,456
• Time in Patent Office: 1,245 Days
• Field of Search: 428/403, 428/204, 428/212, 428/704, 428/901, 428/469, 428/476.1, 428/441, 252/512, 252/518, 252/521
• US Class Current: 428/209
• CPC Class Codes: B41M 3/003 on optical devices, e.g. lens elements; for the production of optical devices production by thermal imaging means B41M5/265
• CPC Class Codes: B82Y 10/00 Nanotechnology for information processing, storage or transmission, e.g. quantum computing or single electron logic
• CPC Class Codes: B82Y 40/00 Manufacture or treatment of nanostructures
• CPC Class Codes: G03F 7/0002 Lithographic processes using patterning methods other than those involving the exposure to radiation, e.g. by stamping
• CPC Class Codes: Y10S 428/901 Printed circuit
• CPC Class Codes: Y10T 428/24917 including metal layer
• CPC Class Codes: Y10T 428/24942 including components having same physical characteristic in differing degree
• CPC Class Codes: Y10T 428/2991 Coated

Abstract

The present invention comprises methods of contact printing of patterned, self-assembling monolayers of alkanethiolates, carboxylic acids, hydroxamic acids, and phosphonic acids on thermoplastic films metallized with an alloy such as nickel/gold, the compositions produced thereby, and the use of these compositions. Patterned self-assembling monolayers allow for the controlled placement of fluids thereon which contain a chemically reactive, indicator functionality. The optical sensing devices produced thereby when the film is exposed to an analyte and light, can produce optical diffraction patterns which differ depending on the reaction of the self-assembling monolayer with the analyte of interest. The light can be in the visible spectrum, and be either reflected from the film, or transmitted through it, and the analyte can be any compound reacting with the fluid on the self-assembling monolayer. The present invention also provides a flexible support for a self-assembling monolayer on a metal alloy.

Claims

1. A film with patterned self-assembling monolayers thereon comprising:

a polymer film coated with a metal alloy; and

a self-assembling monolayer printed onto the polymer film.

2. The film of claim 1, wherein the metals to be alloyed are selected from the group consisting essentially of gold, silver, nickel, platinum, aluminum, iron, copper, and zirconium.

3. The film of claim 1, wherein the alloy coating is between approximately 1 nanometer and 1000 nanometers in thickness.

4. The film of claim 1, wherein the polymer film is selected from the group consisting of polyethylene-terephthalate, acrylonitnile-butadiene-styrene, acrylonitrile-methyl acetate copolymer, cellophane, cellulosic polymers such as ethyl cellulose, cellulose acetate, cellulose acetate butyrate, cellulose propionate, cellulose triacetate, polyethylene, polyethylene-vinyl acetate compolymers, ionomers (ethylene polymers) polyethylene-nylon copolymers, polypropylene, methyl pentene polymers, polyvinyl fluoride, and aromatic polysulfones.

5. The film of claim 4, wherein the polymer film is polyethylene-terephthalate.

6. The film of claim 1, wherein the polymer film is optically transparent.

7. The film of claim 1, wherein the polymer film has an optical transparency between 5% and 95%.

8. The film of claim 1, wherein the polymer film has an optical transparency between 20% and 80%.

9. The film of claim 1, wherein the self-assembling monolayer comprises compounds with the following general formula:

space="preserve" listing-type="equation">X--R--Y

wherein;

X is reactive with the metal or metal oxide on the polymer film;

R is a hydrocarbon chain; and

Y is a compound with any property of interest;

wherein the self-assembling monolayer compound is attached to the polymer film through reaction of X with the metal or metal oxide on the polymer film.

10. The film of claim 9, wherein:

X is selected from the group consisting of an asymmetrical or symmetrical disulfide (--SSY'"'"', --SSY), sulfide (--"SY'"'"', SY), diselenide (--'"'"'Se--SeY'"'"'), selenide (--SeY'"'"', --SeY), thiol (--SH), nitrile (--CN), isonitrile, nitro (--NO₂), selenol (--SeH), trivalent phosphorous compounds, isothiocyanate, xanthate, thiocarbamate, phosphine, thioacid, dithioacid, carboxylic acids, hydroxylic acids, and hydroxamic acids;

R and R'"'"' are selected from hydrocarbon chains hydrocarbon chains interrupted by hetero atoms, hydrocarbon chains which are perfluorinated, or hydrocarbons which are non-branched; and

Y and Y'"'"' are selected from hydroxy, carboxyl, amino, aldehyde, hydrazide, carbonyl, epoxy, or vinyl groups.

11. The film of claim 9, wherein R is greater than 7 carbon atoms in length.

12. The film of claim 9, wherein R is a compound of the form (CH₂)_a --Z--(CH₂)_b, wherein a≧

0, b≧

7, and Z is any chemical functionality of interest.

13. The film of claim 12, wherein Z is selected from the group consisting of sulfones, lactams, and urea.

14. The film of claim 1, wherein the polymer film comprises a first self-assembling monolayer stamped on the polymer film and a second self-assembling monolayer located in unstamped areas of the polymer film, further wherein each self-assembling monolayer has different chemical properties.

15. The film of claim 14, wherein the first self-assembling monolayer is hydrophobic, and the second self-assembling monolayer is hydrophilic.

16. A film with patterned self-assembling monolayers thereon comprising:

a polymer film coated with a metal alloy; and

a self-assembling monolayer printed onto the polymer film;

wherein the metal alloy has surface enrichment of a metal reacting with the self-assembling monolayer.

17. The film of claim 16 wherein the metal alloy is selected from the group consisting of Ni/Au, Pt/Au, and Cu/Au.