Transparent substrate provided with a thin-film stack with properties in the infrared

• US 6,020,077 A
• Filed: 02/07/1997
• Issued: 02/01/2000
• Est. Priority Date: 02/09/1996
• Status: Expired due to Fees

• Current Assignee: Saint-Gobain Vitrage
• Original Assignee: Saint-Gobain Vitrage
• Inventors: Haussler, Wulf, Ditzel, Gerhard, Schicht, Heinz, Schmidt, Uwe, Schindler, Herbert, Kaiser, Wilfried
• Primary Examiner(s): Thibodeau, Paul
• Assistant Examiner(s): Rickman, Holly C.
• Application Number:
  US08/796,185
• Time in Patent Office: 1,089 Days
• Field of Search: 428/622, 428/632, 428/673, 428/432, 428/433, 428/469, 428/426
• US Class Current: 428/622
• CPC Class Codes: C03C 17/36 at least one coating being a metal
• CPC Class Codes: C03C 17/3618 Coatings of type glass/inorganic compound/other inorganic layers, at least one layer being metallic
• CPC Class Codes: C03C 17/3639 Multilayers containing at least two functional metal layers
• CPC Class Codes: C03C 17/3644 the metal being silver
• CPC Class Codes: C03C 17/3652 the coating stack containing at least one sacrificial layer to protect the metal from oxidation
• CPC Class Codes: C03C 17/366 Low-emissivity or solar control coatings
• CPC Class Codes: C03C 17/3681 the multilayer coating being used in glazing, e.g. windows or windscreens
• CPC Class Codes: Y10T 428/12542 More than one such component
• CPC Class Codes: Y10T 428/12611 Oxide-containing component
• CPC Class Codes: Y10T 428/12896 Ag-base component
• CPC Class Codes: Y10T 428/31627 Next to aldehyde or ketone condensation product

Abstract

The invention relates to a transparent substrate, in particular glass substrate, provided with a thin-film stack including at least one metal film with properties in the infrared, in particular a low-emissivity one, arranged between two coatings which each include at least one anti-reflection film based on dielectric material, and at least one protective film based on a sacrificial metal or a partially or fully oxidized sacrificial metal or a sacrificial metal alloy placed between the said metal film and one of the said coatings. According to the invention, the film placed directly below and/or above the said metal film contains at least one of the noble metals Pd, Au, Ir, Pt and Rh. The low-level addition of one or more of these metals to the others, namely the film placed below and/or above the metal film, leads to an increase in the chemical stability and the hardness of the thin-film stack.

Claims

1. Transparent coated substrate provided with a thin-film stack, said thin film stack comprising:

at least one lower anti-reflection film made of a dielectric material;

at least one upper anti-reflection film made of a dielectric material;

at least one metal film having low emissivity in the infrared disposed between said lower anti-reflection film and said upper anti-reflection film;

at least one protective film made of a sacrificial metal, a partially or fully oxidized sacrificial metal, or a sacrificial metal alloy disposed between said metal film and said upper anti-reflection film; and

an anti-reflection film containing a noble metal component comprising Pd, Au, Ir, Pt, Rh or mixtures thereof in an amount of between about 0.05% and 10% by weight which is disposed directly below said metal film.

2. The coated substrate according to claim 1 wherein said at least one protective film contains a noble metal component comprising Pd, Au, Ir, Pt, Rh or mixtures thereof.

3. The coated substrate according to claim 1 wherein the metal film is silver.

4. The coated substrate according to claim 1 wherein the substrate is glass.

5. The coated substrate according to claim 1 wherein the protective film contains one or more metals selected from the group consisting of Ni, Fe, Co, Ge, Pb, Cr, W, Bi, As, Sb, Be, Zn, Ti, Sn, Zr, V, Ta, Mn, Cu, Nb and Al.

6. The coated substrate according to claim 2 wherein the protective film contains 70 to 90% by weight of Ni, 5 to 25% by weight of Cr and 0.05 to 5% by weight of the noble metal component.

7. The coated substrate according to claim 1 wherein the anti-reflection film disposed directly below the metal film has a thickness of about 0.5 to 2 nm.

8. The coated substrate according to claim 1 wherein the protective film has a thickness of about 1 to 10 nm.

9. The coated substrate according to claim 1 wherein the protective film has a thickness of about 1 to 5 nm.

10. The coated substrate according to claim 1 wherein the at least one metal film comprises two or more metal films.

22. A low-emissivity monolithic or laminated window comprising the coated substrate according to claim 1.

11. Transparent coated substrate provided with a thin-film stack, said thin film stack comprising:

at least one lower anti-reflection film made of a dielectric material;

at least one upper anti-reflection film made of a dielectric material;

at least one metal film having low emissivity in the infrared disposed between said lower anti-reflection film and said upper anti-reflection film;

at least one lower protective film made of a sacrificial metal, a partially or fully oxidized sacrificial metal, or a sacrificial metal alloy, which is disposed between said metal film and said lower anti-reflection film directly below said metal film and which contains at least on noble metal selected from the group consisting of Pd, Au, Ir, Pt, and Rh in an amount of between about 0.05% and 10% by weight; and

at least one upper protective film made of a sacrificial metal, a partially or fully oxidized sacrificial metal, or a sacrificial metal alloy disposed between said metal film and said upper anti-reflection film.

12. The coated substrate according to claim 11 wherein said at least one upper protective film contains a noble metal component comprising Pd, Au, Ir, Pt, Rh or mixtures thereof.

13. The coated substrate according to claim 11 wherein the metal film is silver.

14. The coated substrate according to claim 11 wherein the substrate is glass.

15. The coated substrate according to claim 11 wherein the upper protective film and the lower protective film contain one or more metals selected from the group consisting of Ni, Fe, Co, Ge, Pb, Cr, W, Bi, As, Sb, Be, Zn, Ti, Sn, Zr, V, Ta, Mn, Cu, Nb and Al.

16. The coated substrate according to claim 11 wherein the lower protective film contains 70 to 90% by weight of Ni, 5 to 25% by weight of Cr and 0.05 to 5% by weight of the noble metal component.

17. The coated substrate according to claim 12 wherein the upper protective film contains 70 to 90% by weight of Ni, 5 to 25% by weight of Cr and 0.05 to 5% by weight of the noble metal component.

18. The coated substrate according to claim 11 wherein the film disposed directly below the metal film has a thickness of about 0.5 to 2 nm.

19. The coated substrate according to claim 11 wherein the upper and lower protective films each have a thickness of about 1 to 10 nm.

20. The coated substrate according to claim 19 wherein the upper and lower protective films each have a thickness of about 1 to 5 nm.

21. The coated substrate according to claim 11 wherein the at least one metal film comprises two or more metal films.

23. A low-emissivity monolithic or laminated window comprising the coated substrate according to claim 11.

24. Transparent coated substrate provided with a thin-film stack, said thin film stack comprising:

at least one lower anti-reflection film made of a dielectric material;

at least one upper anti-reflection film made of a dielectric material;

at least one metal film having low emissivity in the infrared disposed between said lower anti-reflection film and said upper anti-reflection film;

at least one protective film made of a sacrificial metal, a partially or fully oxidized sacrificial metal, or a sacrificial metal alloy disposed between said metal film and said upper anti-reflection film; and

an anti-reflection film containing a noble metal component comprising Au, Ir, Rh or mixtures thereof which is disposed directly below said metal film.

25. Transparent coated substrate provided with a thin-film stack, said thin film stack comprising:

at least one lower anti-reflection film made of a dielectric material;

at least one upper anti-reflection film made of a dielectric material;

at least one metal film having low emissivity in the infrared disposed between said lower anti-reflection film and said upper anti-reflection film;

at least one lower protective film made of a sacrificial metal, a partially or fully oxidized sacrificial metal, or a sacrificial metal alloy, which is disposed between said metal film and said lower anti-reflection film directly below said metal film and which contains at least on noble metal selected from the group consisting of Au, Ir, and Rh; and

at least one upper protective film made of a sacrificial metal, a partially or fully oxidized sacrificial metal, or a sacrificial metal alloy disposed between said metal film and said upper anti-reflection film.