Non-aqueous electrolyte secondary cell

• US 6,022,641 A
• Filed: 12/22/1997
• Issued: 02/08/2000
• Est. Priority Date: 12/27/1996
• Status: Expired due to Term

• Current Assignee: Murata Manufacturing Co Limited
• Original Assignee: Sony Corporation (Sony Group Corp.)
• Inventors: Endo, Takuya, Takahashi, Kimio
• Primary Examiner(s): Nuzzolillo, Maria
• Assistant Examiner(s): CHANEY, CAROL DIANE
• Application Number:
  US08/996,320
• Time in Patent Office: 778 Days
• Field of Search: 429/224, 429/231.1, 429/232
• US Class Current: 429/232
• CPC Class Codes: H01M 10/052 Li-accumulators
• CPC Class Codes: H01M 10/0525 Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
• CPC Class Codes: H01M 4/505 of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
• CPC Class Codes: H01M 4/587 for inserting or intercalating light metals
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

Disclosed is a non-aqueous electrolyte secondary cell comprising a cathode made from a cathode compound that comprises a manganese oxide or a lithium-manganese composite oxide, a lithium metal anode or an anode comprising lithium or capable of doping and dedoping lithium ions, and a non-aqueous electrolyte, which is characterized in that the cathode compound contains an alkali metal carbonate of being from 0.5 to 20% by weight of the dry cathode compound. Even when used at high temperatures over room temperature for a long period of time, the cell is deteriorated little.

Claims

1. A non-aqueous electrolyte secondary cell comprising:

a cathode comprising an active cathode material comprising a manganese oxide or a lithium manganese composite oxide, and from about 0.5 to about 20% by weight, based on dry weight of the active cathode material, of sodium carbonate;

an anode comprising lithium or lithium metal; and

a non-aqueous electrolyte.

3. A non-aqueous electrolyte secondary cell as defined in claim 1, wherein said non-aqueous electrolyte comprises a solution of a lithium salt in a mixed solvent system including at least one high dielectric constant solvent selected from the group consisting of ethylene carbonate, propylene carbonate, butylene carbonate, vinylene carbonate, sulfolanic acid, butyrolactonic acid and valerolactonic acid and at least one low viscosity solvent selected from the group consisting of diethyl carbonate, dimethyl carbonate, methyl ethyl carbonate, methyl propyl carbonate, methyl propionate, ethyl propionate, trimethyl phosphate and triethyl phosphate.

5. A non-aqueous electrolyte secondary cell as defined in claim 1, wherein said active cathode material consists essentially of:

(i) a manganese oxide or a lithium manganese composite oxide;

(ii) a conductive material;

(iii) a binder; and

(iv) from about 0.5 to about 20% by weight based on dry weight of the active cathode material, of sodium carbonate.

7. The non-aqueous electrolyte secondary cell as claimed in claim 1, in which the lithium-manganese composite oxide has a spinel-type crystal structure.

8. The non-aqueous electrolyte secondary cell as claimed in claim 1, of which the discharge voltage is 3 V or higher.

2. A non-aqueous electrolyte secondary cell comprising a cathode comprising an active cathode material comprising a manganese oxide or a lithium-manganese composite oxide and from about 0.5 to about 20% by weight, based on dry weight of the active cathode material, of sodium carbonate;

an anode capable of doping and dedoping lithium ions; and

a non-aqueous electrolyte.

4. A non-aqueous electrolyte secondary cell as defined in claim 2, wherein said non-aqueous electrolyte comprises a solution of a lithium salt in a mixed solvent system including at least one high dielectric constant solvent selected from the group consisting of ethylene carbonate, propylene carbonate, butylene carbonate, vinylene carbonate, sulfolanic acid, butyrolactonic acid and valerolactonic acid and at least one low viscosity solvent selected from the group consisting, of diethyl carbonate, dimethyl carbonate, methyl ethyl carbonate, methyl propyl carbonate, methyl propionate, ethyl propionate, trimethyl phosphate and triethyl phosphate.

6. A non-aqueous electrolyte secondary cell as defined in claim 2, wherein said active cathode material consists essentially of:

(i) a manganese oxide or a lithium manganese composite oxide;

(ii) a conductive material;

(iii) a binder; and

(iv) from about 0.5 to about 20% by weight based on dry weight of the active cathode material, of sodium carbonate.

9. The non-aqueous electrolyte secondary cell as claimed in claim 2, in which the anode is made from a carbon material.

10. The non-aqueous electrolyte secondary cell as claimed in claim 9, in which the carbon material is a graphite material or a hardly-graphitizable carbon material.

11. The non-aqueous electrolyte secondary cell as claimed in claim 10, in which the graphite material has a true density of not smaller than 2.1 g/cm³, a spacing for (002) of from 0.335 nm to 0.337 nm, and a C-axis crystal lattice thickness for (002) of not smaller than 14.0 nm.

12. The non-aqueous electrolyte secondary cell as claimed in claim 10, in which the hardly-graphitizable carbon material has a spacing for (002) of not smaller than 0.37 nm, and a true density of smaller than 1.70 g/cm³, and gives no exothermic peak at 700°

C. or higher in differential thermal analysis in air.

13. The non-aqueous electrolyte secondary cell as claimed in claim 2, in which the lithium-manganese composite oxide has a spinel-type crystal structure.

14. The non-aqueous electrolyte secondary cell as claimed in claim 2, of which the discharge voltage is 3 V or higher.